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Chemical Structure| 1112-49-8 Chemical Structure| 1112-49-8

Structure of 1112-49-8

Chemical Structure| 1112-49-8

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Product Details of [ 1112-49-8 ]

CAS No. :1112-49-8
Formula : C6H15ISi
M.W : 242.17
SMILES Code : I[Si](CC)(CC)CC
MDL No. :MFCD09910019

Safety of [ 1112-49-8 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H226-H301-H314
Precautionary Statements:P280-P301+P310-P305+P351+P338-P310
Class:8(3)
UN#:2920
Packing Group:

Application In Synthesis of [ 1112-49-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1112-49-8 ]

[ 1112-49-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1034287-04-1 ]
  • [ 1112-49-8 ]
  • [ 1528700-15-3 ]
YieldReaction ConditionsOperation in experiment
69%Chromat. With [{Ir(mu-Cl)(CO)2}2]; N-ethyl-N,N-diisopropylamine; In toluene; at 80℃; for 24h;Schlenk technique; Inert atmosphere; General procedure: A glass Schlenk reactor (10 mL) equipped with a magnetic stirbar was evacuated and flushed with argon. The calculated amountof [{Ir(l-Cl)(CO)2}2] complex (0.005 or 0.0025 mmol) was placed inthe reactor under the flow of argon, then 3 mL of solvent and amine (1.8 mmol) were added. The obtained mixture was stirred forabout 10 min. In the next step, the terminal alkyne (1 mmol) andR3SiI (1.6 mmol) were added, and the reaction was conducted atthe given temperature. The mixture was analyzed by GC and GC/MS at the beginning and after 24 or 48 h. The conversions andyields were calculated using the internal standard calculationmethod.
 

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