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Chemical Structure| 110391-10-1 Chemical Structure| 110391-10-1

Structure of 110391-10-1

Chemical Structure| 110391-10-1

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Product Details of [ 110391-10-1 ]

CAS No. :110391-10-1
Formula : C35H34O5
M.W : 534.64
SMILES Code : O=C1C=C(COCC2=CC=CC=C2)[C@@H](OCC3=CC=CC=C3)[C@H](OCC4=CC=CC=C4)[C@H]1OCC5=CC=CC=C5
MDL No. :N/A

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Application In Synthesis of [ 110391-10-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 110391-10-1 ]

[ 110391-10-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1030825-20-7 ]
  • [ 110391-10-1 ]
  • [ 1413373-77-9 ]
YieldReaction ConditionsOperation in experiment
Synthesis of compound 45C53H49F05S M = 817.02 g.mol"1 19FNMR (CDCh, 282.5MHz): -115.2 (m, IF, Ar-F)+; 855.4 [M+K]+ ft-Butyllithium (1.4M in hexanes, 0.30mL, 0.412mmol, l . l eq) was slowly added to a cooled solution (-70°C) of 44 (149mg, 0.412mmol, l . l eq) in anhydrous THF-toluene (1:1, v/v, 4.8mL) under inert atmosphere. The resultant dark blue solution was stirred for 5 min at the same temperature before a cooled solution (-70°C) of cyclohexenone 8 was slowly added. The reaction mixture was stirred for 15 min at -70°C before being poured into water. The organic layer was then dried over sodium sulphate, filtered and concentrated to afford crude 45 (300mg, 98percent yield) as yellow oil which was used in the next step without further purification.
 

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