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Chemical Structure| 1089687-06-8 Chemical Structure| 1089687-06-8

Structure of 1089687-06-8

Chemical Structure| 1089687-06-8

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Product Details of [ 1089687-06-8 ]

CAS No. :1089687-06-8
Formula : C30H54S2SiSn2
M.W : 744.39
SMILES Code : C([Si]1(C2C=C(SC=2C2SC(=CC1=2)[Sn](C)(C)C)[Sn](C)(C)C)CC(CC)CCCC)C(CC)CCCC
InChI Key :KJEMHVQXPBRUNL-UHFFFAOYSA-N
Pubchem ID :58991605

Safety of [ 1089687-06-8 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H300+H310+H330-H410
Precautionary Statements:P501-P273-P260-P270-P262-P271-P264-P280-P284-P391-P361+P364-P301+P310+P330-P302+P352+P310-P304+P340+P310-P403+P233-P405
Class:6.1
UN#:3146
Packing Group:

Application In Synthesis of [ 1089687-06-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1089687-06-8 ]

[ 1089687-06-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1089687-06-8 ]
  • [ 1347736-74-6 ]
  • [ 1589072-33-2 ]
YieldReaction ConditionsOperation in experiment
26% The 30 mL microwave tube was charged with 4,4-bis(2-ethylhexyl)-2,6-bis(trimethylstannyl)-4H-silolo[3,2-b:4,5-b']dithiophene(Me3Sn-DTSi-SnMe3, 1.40 g, 1.88 mmol), <strong>[1347736-74-6]4,7-dibromo-5-fluorobenzo[c][1,2,5]-thiadiazole</strong> (FBTBr2, 1.47 g, 4.70 mmol), Pd(PPh3)4(0.108 g, 0.094 mmol) and toluene (10 mL). Then, microwave-assistedStille coupling were carried out using a Biotage microwave reactor.After cooling, the material was loaded onto silica and purified by flashchromatography using hexanes/chloroform gradient. Solvent was removedafter collection. The solid in 3:1 mixture of methanol and hexaneswas sonicated for 1 h and stirred during the overnight. The suspensionwas filtered and recrystallized with dichloromethane andhexane. Finally, red solid was obtained (0.42 g, yield: 26%). 1H NMR(400 MHz, CDCl3): delta 8.17 (t, J=8.0 Hz, 2H), 7.68 (d, J=4.0 Hz, 2H),1.51 (m, 2H), 1.43-1.16 (m, 16H), 1.09 (m, 4H), 0.82 (m, 12H). 13CNMR (100 MHz, CDCl3): delta 151.3, 148.8, 145.6, 132.1, 132.1, 132.0,127.7, 127.6, 115.4, 115.0, 36.0, 35.7, 30.9, 28.9, 23.0, 17.6, 14.1,10.8. Elemental analysis calc. For C36H38Br2F2N4S4Si: C 49.09 H 4.35 N6.36 S 14.56; Found: C 49.34 H 4.50 N 6.55 S 14.82. MALDI-TOF:Calcld. For 880.86; Found: 880.00.
 

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