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Chemical Structure| 108865-84-5 Chemical Structure| 108865-84-5

Structure of 108865-84-5

Chemical Structure| 108865-84-5

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Product Details of [ 108865-84-5 ]

CAS No. :108865-84-5
Formula : C7H12O4
M.W : 160.17
SMILES Code : O=C(C1OC(C)(C)OC1)OC
MDL No. :MFCD00010078
InChI Key :DOWWCCDWPKGNGX-UHFFFAOYSA-N
Pubchem ID :539745

Safety of [ 108865-84-5 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H227
Precautionary Statements:P210-P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362

Application In Synthesis of [ 108865-84-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 108865-84-5 ]

[ 108865-84-5 ] Synthesis Path-Downstream   1~6

  • 1
  • [ 108865-84-5 ]
  • [ 5736-06-1 ]
YieldReaction ConditionsOperation in experiment
90.5% With methanol; potassium hydroxide; at 0 - 20℃; for 0.75h; To a solution of methyl-2,2-dimethyl-1,3-dioxalane-4-carboxylate 5 (2.057 g, 12.8 mmol) in 5 mL MeOH, kept in an ice-water bath was added drop-wise 15 mL 1 M potassium hydroxide in methanol. After addition of KOH, the ice-bath was removed and the mixture was stirred at room temperature for 45 min. To this solution were added 15 mL of MeOH and 30 mL of Dowex-H+ ion exchange resin, and then the mixture was stirred for 3 min. The mixture was then filtered and the resin was washed with MeOH (40 mL). The solvent was evaporated, the residue was dispersed in benzene and freeze-dried to give compound 6 (1.695 g, 90.5%) as colorless oil. IR (neat): 3180br m, 1736vs, 1220s, 1104s, 1069s, 837m cm-1; 1H NMR (CDCl3, 200 MHz) delta 1.32 (s, 3H), 1.42 (s, 3H), 4.04-4.12 (dd, 1H, J=8.7, 5.1 Hz), 4.16-4.24 (dd, 1H, J=7.3, 8.7 Hz), 4.51-4.57 (dd, 1H, J=5.1, 7.3 Hz), 9.45 (s, 1H); 13C NMR (CDCl3, 50 MHz) delta 25.2, 25.7, 67.1, 73.5, 111.7, 175.8. [alpha]D20 -25.2 (c 1.1, CHCl3), known compound.
  • 2
  • [ 77-78-1 ]
  • [ 5736-06-1 ]
  • [ 108865-84-5 ]
  • 3
  • [ 108865-84-5 ]
  • [ 60456-21-5 ]
  • [ 5736-06-1 ]
  • 4
  • [ 186581-53-3 ]
  • [ 5736-06-1 ]
  • [ 108865-84-5 ]
  • 5
  • (trimethylsilyl)diazomethane [ No CAS ]
  • [ 5736-06-1 ]
  • [ 108865-84-5 ]
  • 6
  • [ 5736-06-1 ]
  • [ 18107-18-1 ]
  • [ 108865-84-5 ]
 

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[ 108865-84-5 ]

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Related Parent Nucleus of
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