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Chemical Structure| 1088-00-2 Chemical Structure| 1088-00-2

Structure of 1088-00-2

Chemical Structure| 1088-00-2

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Product Details of [ 1088-00-2 ]

CAS No. :1088-00-2
Formula : C18H13P
M.W : 260.27
SMILES Code : P1(C2=CC=CC=C2)C3=CC=CC=C3C4=C1C=CC=C4
MDL No. :MFCD00046900
InChI Key :DNPJAMMRVRYLOB-UHFFFAOYSA-N
Pubchem ID :258370

Safety of [ 1088-00-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313

Application In Synthesis of [ 1088-00-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1088-00-2 ]

[ 1088-00-2 ] Synthesis Path-Downstream   1~35

  • 7
  • [ 13029-09-9 ]
  • [ 644-97-3 ]
  • [ 1088-00-2 ]
YieldReaction ConditionsOperation in experiment
82% General procedure for the synthesis of dibenzophosphole ligands At -78 C, a solution of n-butyllithium (2.0 mmol, 2 equiv) in hexanes (1.1 mL) was added slowly to a solution of the 2,2'-dihalobiaryl (1.0 mmol) in tetrahydrofuran (2 mL). After 30 min, a solution of dichlorophenylphosphine (0.18 g, 0.14 mL, 1.0 mmol, 1 equiv) in toluene (1 mL) was added slowly. After 15 min, the reaction mixture was allowed to reach 25 C and was treated with a saturated aqueous solution of ammonium chloride (15 mL). The mixture was extracted with ethyl acetate (3*15 mL), and the combined organic layers were dried over sodium sulfate. Evaporation of the solvent followed by column chromatography on silica gel using cyclohexane as the eluent gave the corresponding dibenzophosphole. All analytical data were identical to those previously reported. 17
  • 9
  • [ 1088-00-2 ]
  • [ 75-03-6 ]
  • [ 113686-87-6 ]
  • 10
  • [ 1088-00-2 ]
  • [ 105-36-2 ]
  • 9-phenyl-9-carbethoxymethylphosphafluorinium bromide [ No CAS ]
  • 14
  • [ 1088-00-2 ]
  • Dinatrium-5-(3-sulfonatophenyl)-5H-dibenzophosphol-3-sulfonat [ No CAS ]
  • 15
  • [ 13029-09-9 ]
  • [ 1079-66-9 ]
  • [ 1088-00-2 ]
  • [ 603-35-0 ]
  • 16
  • [ 1088-00-2 ]
  • [ 112-29-8 ]
  • P-Decyldibenzophosphole [ No CAS ]
  • 19
  • [ 506-68-3 ]
  • [ 1088-00-2 ]
  • [ 955374-96-6 ]
  • 20
  • (+)-(2R,4S,5R)-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazaphospholidine-2-borane [ No CAS ]
  • [ 13029-09-9 ]
  • bis[(1R,2S)-(N-ephedrino)](phenyl)phosphine-P-borane [ No CAS ]
  • [ 1088-00-2 ]
  • 21
  • (+)-(2R,4S,5R)-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazaphospholidine-2-borane [ No CAS ]
  • [ 92-52-4 ]
  • bis[(1R,2S)-(N-ephedrino)](phenyl)phosphine-P-borane [ No CAS ]
  • [ 1088-00-2 ]
  • 22
  • [ 1088-00-2 ]
  • [ 852921-66-5 ]
  • 35
  • [ 1088-00-2 ]
  • [ 19190-38-6 ]
 

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