1082-19-5|1,10-Phenanthroline-2-carbonitrile| Ambeed

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Structure of 1082-19-5

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Quality Control of [ 1082-19-5 ] Purity: 98% SDS Specification

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Product Details of [ 1082-19-5 ]

CAS No. :	1082-19-5
Formula :	C₁₃H₇N₃
M.W :	205.22
SMILES Code :	N#CC1=CC=C2C=CC3=CC=CN=C3C2=N1
MDL No. :	MFCD18431788
InChI Key :	LSMQCFPLQFCYAW-UHFFFAOYSA-N
Pubchem ID :	680341

Safety of [ 1082-19-5 ]

GHS Pictogram:
Signal Word:	Danger
Hazard Statements:	H302-H318
Precautionary Statements:	P280-P305+P351+P338
Class:	8
UN#:	1759
Packing Group:	Ⅲ

Application In Synthesis of [ 1082-19-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1082-19-5 ]

[ 1082-19-5 ] Synthesis Path-Downstream 1~35

1
[ 1891-19-6 ]
[ 151-50-8 ]
[ 1082-19-5 ]

Yield	Reaction Conditions	Operation in experiment
24.0%	With benzoyl chloride; In water; at 20℃;	Step 2; 23 g [1,10]phenanthroline-N-oxide and 37.5 g KCN were dissolved in 2.5 L water to form a mixture, and 65 g benzoyl chloride was added into the mixture drop by drop. Then, the mixture was stirred at room temperature overnight. After completion of reaction, solids were collected, purified by silica gel column (Hexane/CH2Cl2=1/2) and dried to obtain solids [1,10]phenanthroline-2-carbonitrile 6 g (yield 24.0%).

References: [1]Journal of Heterocyclic Chemistry,1986,vol. 23,p. 989 - 900.
[2]Patent: US7282586,2007,B1 .Location in patent: Page/Page column 20.
[3]Journal of Organic Chemistry,2008,vol. 73,p. 7444 - 7450.

2
[ 67-56-1 ]
[ 1082-19-5 ]
[ 37067-12-2 ]

References: [1]European Journal of Inorganic Chemistry,2013,p. 6137 - 6146.
[2]Journal of Organometallic Chemistry,2006,vol. 691,p. 4114 - 4123.
[3]Journal of the Chemical Society. Perkin transactions II,1991,p. 1121 - 1126.

3
[ 1082-19-5 ]
[ 111622-25-4 ]

References: [1]Journal of Heterocyclic Chemistry,1986,vol. 23,p. 989 - 900.

4
[ 1082-19-5 ]
[ 60-34-4 ]
[ 180518-31-4 ]

References: [1]Australian Journal of Chemistry,1996,vol. 49,p. 505 - 515.

5
[ 1082-19-5 ]
[ 1025-07-6 ]

References: [1]Australian Journal of Chemistry,1996,vol. 49,p. 505 - 515.

8
[ 1082-19-5 ]
[ 1025-07-6 ]

References: [1]Journal of the Chemical Society, Dalton Transactions,2001,p. 1326 - 1331.

9
[ 1082-19-5 ]
[ 16332-24-4 ]

References: [1]Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry,2001,vol. 40,p. 625 - 627.

10
[ 1082-19-5 ]
[ 422268-60-8 ]

References: [1]Organic Letters,2002,vol. 4,p. 1253 - 1256.

11
[ 1082-19-5 ]
[ 1891-17-4 ]

Yield	Reaction Conditions	Operation in experiment
60%	With sodium hydroxide; In ethanol; water;Reflux;	To a solution of8.3 g (208 mmol) of sodium hydroxide in 50 mL of waterwas added a solution of 10 g (49 mmol) of <strong>[1082-19-5]2-cyano-1,10-phenanthroline</strong> in 100 mL of 95% ethanol. The mixturewas heated to reflux under magnetic stirring. The disappearanceof <strong>[1082-19-5]2-cyano-1,10-phenanthroline</strong> was followedby TLC with dichloromethane/methanol (95/5 v/v) as eluent.The reaction was stopped when complete disappearance of <strong>[1082-19-5]2-cyano-1,10-phenanthroline</strong>was achieved (ca. 1.5 h). The ethanol was removed under reduced pressure, andthe mixture was acidified with 37% hydrochloric acid to pH≈2 in an ice-water bath. A palebrown solid precipitated, was collected by suction filtration, washed with 10% hydrochloricacid solution and dried over vacuum to yield a pale brown solid (7.7 g, 60% yield). Theproduct was used without further purification.

References: [1]Advanced Synthesis and Catalysis,2003,vol. 345,p. 1341 - 1352.
[2]Dalton Transactions,2013,vol. 42,p. 11047 - 11055.
[3]European Journal of Inorganic Chemistry,2013,p. 6137 - 6146.
[4]Molecules,2021,vol. 26.
[5]Journal of Organic Chemistry,2008,vol. 73,p. 7444 - 7450.
[6]Chemistry - A European Journal,2009,vol. 15,p. 9147 - 9159.
[7]Inorganic Chemistry,2020,vol. 59,p. 14564 - 14576.

12
[ 75-24-1 ]
[ 1082-19-5 ]
[ 72404-92-3 ]