There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
*Storage: Sealed in dry,Room Temperature.
*Shipping: Normal
4.5
*For Research Use Only !
Change View
Size | Price | USA Stock *0-1 Day | Global Stock *5-7 Days | In Stock |
10g | łÇʶÊÊ | Inquiry | Inquiry | Login |
25g | łÇò¶ÊÊ | Inquiry | Inquiry | Login |
100g | ł§Í¶ÊÊ | Inquiry | Inquiry | Login |
500g | łÇÊʶÊÊ | Inquiry | Inquiry | Login |
Please Login or Create an Account to: See VIP prices and availability
łÇʶÊÊ
łÇò¶ÊÊ
ł§Í¶ÊÊ
łÇÊʶÊÊ
In Stock
- +
Please Login or Create an Account to: See VIP prices and availability
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
CAS No. : | 1073-06-9 |
Formula : | C6H4BrF |
M.W : | 175.00 |
SMILES Code : | FC1=CC=CC(Br)=C1 |
MDL No. : | MFCD00000326 |
Boiling Point : | No data available |
InChI Key : | QDFKKJYEIFBEFC-UHFFFAOYSA-N |
Pubchem ID : | 14082 |
GHS Pictogram: | ![]() ![]() |
Signal Word: | Danger |
Hazard Statements: | H225-H315-H319-H335 |
Precautionary Statements: | P261-P305+P351+P338 |
Class: | 3 |
UN#: | 1993 |
Packing Group: | Ⅲ |
Num. heavy atoms | 8 |
Num. arom. heavy atoms | 6 |
Fraction Csp3 | 0.0 |
Num. rotatable bonds | 0 |
Num. H-bond acceptors | 1.0 |
Num. H-bond donors | 0.0 |
Molar Refractivity | 34.1 |
TPSA ? Topological Polar Surface Area: Calculated from | 0.0 Ų |
Log Po/w (iLOGP)? iLOGP: in-house physics-based method implemented from | 2.08 |
Log Po/w (XLOGP3)? XLOGP3: Atomistic and knowledge-based method calculated by | 2.92 |
Log Po/w (WLOGP)? WLOGP: Atomistic method implemented from | 3.01 |
Log Po/w (MLOGP)? MLOGP: Topological method implemented from | 3.48 |
Log Po/w (SILICOS-IT)? SILICOS-IT: Hybrid fragmental/topological method calculated by | 3.0 |
Consensus Log Po/w? Consensus Log Po/w: Average of all five predictions | 2.9 |
Log S (ESOL):? ESOL: Topological method implemented from | -3.32 |
Solubility | 0.0838 mg/ml ; 0.000479 mol/l |
Class? Solubility class: Log S scale | Soluble |
Log S (Ali)? Ali: Topological method implemented from | -2.58 |
Solubility | 0.459 mg/ml ; 0.00262 mol/l |
Class? Solubility class: Log S scale | Soluble |
Log S (SILICOS-IT)? SILICOS-IT: Fragmental method calculated by | -3.52 |
Solubility | 0.0522 mg/ml ; 0.000299 mol/l |
Class? Solubility class: Log S scale | Soluble |
GI absorption? Gatrointestinal absorption: according to the white of the BOILED-Egg | Low |
BBB permeant? BBB permeation: according to the yolk of the BOILED-Egg | Yes |
P-gp substrate? P-glycoprotein substrate: SVM model built on 1033 molecules (training set) | No |
CYP1A2 inhibitor? Cytochrome P450 1A2 inhibitor: SVM model built on 9145 molecules (training set) | Yes |
CYP2C19 inhibitor? Cytochrome P450 2C19 inhibitor: SVM model built on 9272 molecules (training set) | No |
CYP2C9 inhibitor? Cytochrome P450 2C9 inhibitor: SVM model built on 5940 molecules (training set) | No |
CYP2D6 inhibitor? Cytochrome P450 2D6 inhibitor: SVM model built on 3664 molecules (training set) | No |
CYP3A4 inhibitor? Cytochrome P450 3A4 inhibitor: SVM model built on 7518 molecules (training set) | No |
Log Kp (skin permeation)? Skin permeation: QSPR model implemented from | -5.29 cm/s |
Lipinski? Lipinski (Pfizer) filter: implemented from | 0.0 |
Ghose? Ghose filter: implemented from | None |
Veber? Veber (GSK) filter: implemented from | 0.0 |
Egan? Egan (Pharmacia) filter: implemented from | 0.0 |
Muegge? Muegge (Bayer) filter: implemented from | 2.0 |
Bioavailability Score? Abbott Bioavailability Score: Probability of F > 10% in rat | 0.55 |
PAINS? Pan Assay Interference Structures: implemented from | 0.0 alert |
Brenk? Structural Alert: implemented from | 0.0 alert: heavy_metal |
Leadlikeness? Leadlikeness: implemented from | No; 1 violation:MW<1.0 |
Synthetic accessibility? Synthetic accessibility score: from 1 (very easy) to 10 (very difficult) | 1.24 |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 7 h; | To a solution of 1-bromo-3-fluorobenzene (250 mg, 1.429 mmol) in DMF (Volume: 5 mL) was added pyrrolidine (122 mg, 1.714 mmol) followed by K2C03 (395 mg, 2.86 mmol) and heated to 100 °C for 7 h. The reaction was diluted with 50 mL DCM and 50 mL water. The organic layer was separated, washed with water (2x20 mL), dried (MgSO4) and concentrated under reduced pressure. The crude product was purified by silica gel chromatography eluting with 10-50percent ethyl acetate:hexanes to afford the desired product 62 (226 mg, 1.000 mmol, 70percent yield). 1H NMR (500 MHz, CD3OD) : 7.02 (t, J= 8.0 Hz, 1H), 6.68 (dd, J= 8.0 Hz, J= 1.0 Hz, 1H), 6.65 (t, J= 2.0 Hz, 1H), 6.48 (dd, J= 8.5 Hz, J= 2.5 Hz, 1H), 3.23 (t, J= 6.5 Hz, 4H), 2.01 (quintet, J=3.5 Hz, 4H) |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
18% | 4'-Bromo-2'-fluoropropiophenone A mixture of 3-fluorobromobenzene (5.0 g, 29 mmol) and aluminium (III) chloride (11.6 g, 87 mmol) was heated under argon until a slurry formed. Propionyl chloride (3.2 g, 35 mmol) was added over 15 min and the mixture was heated at 90 C. for 1 h. The reaction was poured onto ice-water (100 mL) and the resultant mixture was extracted with dichloromethane (3*50 mL). The combined organic extracts were dried (magnesium sulfate), concentrated in vacuo and purified by column chromatography (SiO2; heptane) to give the product (1.2 g, 18%) as a colourless oil: NMR deltaH (400 MHz, CDCl3) 1.18 (3H, t, J 7.5), 2.95 (2H, m), 7.29-7.38 (2H, m) and 7.75 (1H, t, J 8 Hz). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With ammonium chloride; magnesium; In tetrahydrofuran; | a) A solution of 109 g of 1-bromo-3-fluorobenzene in 270 ml of dry tetrahydrofuran was slowly added dropwise to 14.4 g (0.623 mol) of magnesium shavings and a spatula tip of iodine crystals in such a manner that the reaction mixture was held at the reflux temperature. The reaction mixture was left at 73°-75° C. until the magnesium had been consumed completely, then cooled to 5° C. and treated within 20 minutes with a solution of 117.2 g of <strong>[56309-94-5]4-(1,4-dioxaspiro[4,5]dec-8-yl)cyclohexanone</strong> in 460 ml of anhydrous tetrahydrofuran at 5°-15° C. Thereafter, the reaction solution was warmed to room temperature -and stirred for 90 minutes. Subsequently, 800 ml of 10 percent ammonium chloride solution were added dropwise in such a manner that the temperature did not exceed 35° C. The reaction mixture was thereupon extracted with ether, the organic phase was dried over sodium sulfate, filtered and the filtrate was evaporated. This gave 174.3 g of crude 4-(1,4-dioxaspiro[4,5]dec-8-yl)-1-(3-fluorophenyl)cyclohexanol as brownish crystals which were used in the next reaction without further purification. (cis/trans: 47.5:49.5). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
94% | With caesium carbonate;palladium diacetate; triphenylphosphine; In 1,4-dioxane; at 150℃; for 0.5h;Inert atmosphere; Microwaves; | A solution of ethyl 6-chloroimidazo[l,2-a]pyridine-2-carboxylate (0.8 g, 3.6 mmol), cesium carbonate (1.3 g, 3.9 mmol), palladium acetate (64 mg, 0.29 mmol), andtriphenylphosphine (0.15 g, 0.57 mmol) in 1,4-dioxane (43 mL) was treated with l-bromo-3- fluorobenzene (0.54 mL, 4.8 mmol), degassed with nitrogen, and heated in the microwave at 150 C for 30 min. The reaction mixture was filtered over celite and the filtrate was concentrated to give a crude residue. This material was purified by flash column chromatography to give the desired product (1.2 g, 94%). LCMS for C16H13C1FN202 (M+H)+: m/z = 319.1. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
13% | With aluminum (III) chloride; at 90℃; for 1.0h;Inert atmosphere; | A mixture of 3-bromofluorobenzene (5.0 g, 28.57 mmol) and aluminum (III) chloride (11.6 g, 86.99 mmol) was heated under nitrogen until a slurry formed. Propionyl chloride (3.2 g, 34.59 mmol) was added over 15 min and the mixture was heated at 90 C for 1 h. The reaction was poured onto ice-water (100 mL) and the resulting mixture was extracted with dichloromethane (3 x 50 mL). The combined organic extract was dried over magnesium sulfate, was filtered, was concentrated and was purified by column chromatography (eluted with hexanes:ethyl acetate = 10: 1) to give l-(4-bromo-2-fluorophenyl)propan-l-one as a colorless solid (854 mg, 3.696 mmol, 13% yield). XH NMR (400 MHz, CDC13): delta 7.75 (t, 1H), 7.38-7.29 (m, 2H), 3.00-2.94 (m, 2H), 1.18 (t, 3H). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With potassium phosphate; copper(l) iodide; hydrazine hydrate; at 120℃; for 10h;Sealed tube; Inert atmosphere; | General procedure: A mixture of aryl halide (1.0 mmol), CuI (0.1 mmol), Na3PO4 (2.0 mmol), 85% aqueous hydrazine (1 mL), and PEG-400 (2 mL) were added to a sealed tube. The reaction mixture was stirred under argon atmosphere at 120 C for the desired time until complete consumption of starting material as monitored by TLC. Then cooled to room temperature and extracted with diethyl ether (three times). Without dry, the solvent was removed under reduced pressure. The crude product was added to p-toluenesulfonyl chloride in water solution and stirred at room temperature until the reaction was completed at room temperature (monitored by TLC). Then, extracted with diethyl ether (three times). The combined organic phase was then dried with anhydrous Na2SO4 and the solvent was removed under reduced pressure. The remaining residue was purified by column chromatography (petroleum ether/ethyl acetate) on silica gel to provide the desired aryl hydrazines derivatives. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
50% | With copper(l) iodide; potassium carbonate; (1S,2S)-N,N'-dimethyl-1,2-diaminocyclohexane; at 140℃; for 3h; | A 50 mL of flask was charged with 2.62 g of 3-fluorobenzenebromide (15 mmol), 1.40 g of ethyl 1-H-pyrazole-3-carboxylate (10 mmol), 400 mg of CuI (2.0 mmol), 4.5 g of K2CO3 (3.3 mmol) and 0.9 mL of trans-N,N'-dimethylcyclohexayldiamine (2.0 mmol). The resulting mixture was stirred at 140° C. for 3 h. After the mixture was cooled down to room temperature, it was diluted with 200 mL EtOAc and then was washed with water (2*50 mL), and brine (2*50 mL). The organics were dried over MgSO4 and concentrated under reduced pressure. The residue was purified via flash column chromatography on silica gel (0-25percent EtOAc in hexanes) to give the desired product (1.17 g, 50percent). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Equipped with a dropping funnel,thermometer,Magnetic stir the 500ml of the four bottles,200 ml of anhydrous tetrahydrofuran was added,3.75 g (154 mmol) of metallic magnesium.To the dropping funnel was added 24.5 g (140 mmol) of 3-fluorobromobenzene.The reaction flask was charged with trace iodine and a small amount of 3-fluorobromobenzene,The reaction mixture is then heated to about 50 C to initiate a Grignard reaction.After the Grignard reaction,3-fluorobromobenzene in the dropping funnel was slowly dropped into the reaction solution to control the internal temperature to 45 C to 52 C.After completion of the reaction, the reaction solution was stirred for 3 hours until the reaction was complete.In another four-necked flask equipped with a thermometer, a dropping funnel and a magnetic stirrer, 84 ml of dry tetrahydrofuran(83.8 mmol) of 1,2-dichloroethane, and 0.7 g (4.3 mmol) of 3 mol% FeCl3.The Grignard solution prepared as described above was placed in a dropping funnel,And slowly added dropwise to the stirred 1,2-dichloroethane / FeCl3 / THF reaction mixture for about 1.5 hours. After the drop, the reaction temperature was 49 . The reaction mixture was stirred at room temperature for an additional 2 hours. 19F NMR analysis reaction mixture,Fluorobenzene as the internal standard,The yield of product 3,3'-difluorobiphenyl was 96%.The post-treatment of the reaction mixture is as follows:The reaction mixture was acidified with dilute hydrochloric acid,Ethyl acetate extraction.Water ethyl acetate extraction,Combined organic layer,Saturated aqueous sodium chloride solution,Dried over magnesium sulfate, filtered and the filtrate evaporated to dryness. The remaining residue was distilled under reduced pressure, and GC-Mass and NMR analysis showed the crude productThe product contains a small amount of 1-bromo-4-acetylbutane and other impurities. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
66% | With potassium phosphate; In N,N-dimethyl acetamide; for 14h;Reflux; | Example 4a Synthesis of 10-(3-bromophenyl)-<strong>[1257220-47-5]12,12-dimethyl-10,12-dihydro-10-azaindeno[2,1-b]fluorene</strong> 150.0 g (526 mmol) of 12,12-dimethyl-10,12-dihydro-10-azaindeno[2,1-b]-fluorene [1257220-47-5], 184.0 g (1.05 mmol) of 1-bromo-3-fluorobenzene [1073-06-9] and 334.7 g (1.58 mol) of potassium phosphate are initially introduced in 2 l of dimethylacetamide and heated under reflux for 14 hours. After cooling to room temperature, the solvent is removed as far as possible in a rotary evaporator, leaving a dark-brown oil. After vigorous rubbing of the flask wall with a glass rod, the product can be precipitated by slowly stirring in about 750 ml of ethanol. The solid formed is filtered off with suction, washed four times with 250 ml of ethanol each time, dried in vacuo and finally subjected to fractional sublimation at a pressure of about 10-5 mbar and 220 C., leaving 152.2 g (347 mmol, 66% of theory) of the product as a yellow glass-like solid having a purity of about 99% according to 1H-NMR. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In tetrahydrofuran; water; at 60℃; for 4h;Inert atmosphere; | (3-1) Under dry nitrogen,3-fluorobromobenzene (20.6 g),Tetrakis (triphenylphosphine) palladium (0) (0.41 g),2 mol / L potassium carbonate aqueous solution (120 mL) and THF (80 mL) were mixed and heated to 60 C.At 60 C., a solution of <strong>[212386-71-5]4-ethoxy-2,3-difluorophenylboronic acid</strong> (25 g) in THF (75 mL) was slowly added.After further stirring at 60 C. for 4 hours,It was cooled to room temperature.Toluene (50 mL) was added and the layers were separated,The organic layer was washed with saturated brine (100 mL).Anhydrous sodium sulfate was added and dried,After removal of sodium sulfate by filtration,And concentrated under reduced pressure. The residue was dissolved in a mixed solvent of hexane and toluene,By purifying by silica gel column chromatography,Crude 1-ethoxy-2,3-difluoro-4- (3-fluorophenyl) benzene (29.5 g) was obtained as a yellow liquid. |
Tags: 1073-06-9 synthesis path| 1073-06-9 SDS| 1073-06-9 COA| 1073-06-9 purity| 1073-06-9 application| 1073-06-9 NMR| 1073-06-9 COA| 1073-06-9 structure
A109867 [64695-78-9]
1,2-Dibromo-4,5-difluorobenzene
Similarity: 0.89
A109867 [64695-78-9]
1,2-Dibromo-4,5-difluorobenzene
Similarity: 0.89
A109867 [64695-78-9]
1,2-Dibromo-4,5-difluorobenzene
Similarity: 0.89
Precautionary Statements-General | |
Code | Phrase |
P101 | If medical advice is needed,have product container or label at hand. |
P102 | Keep out of reach of children. |
P103 | Read label before use |
Prevention | |
Code | Phrase |
P201 | Obtain special instructions before use. |
P202 | Do not handle until all safety precautions have been read and understood. |
P210 | Keep away from heat/sparks/open flames/hot surfaces. - No smoking. |
P211 | Do not spray on an open flame or other ignition source. |
P220 | Keep/Store away from clothing/combustible materials. |
P221 | Take any precaution to avoid mixing with combustibles |
P222 | Do not allow contact with air. |
P223 | Keep away from any possible contact with water, because of violent reaction and possible flash fire. |
P230 | Keep wetted |
P231 | Handle under inert gas. |
P232 | Protect from moisture. |
P233 | Keep container tightly closed. |
P234 | Keep only in original container. |
P235 | Keep cool |
P240 | Ground/bond container and receiving equipment. |
P241 | Use explosion-proof electrical/ventilating/lighting/equipment. |
P242 | Use only non-sparking tools. |
P243 | Take precautionary measures against static discharge. |
P244 | Keep reduction valves free from grease and oil. |
P250 | Do not subject to grinding/shock/friction. |
P251 | Pressurized container: Do not pierce or burn, even after use. |
P260 | Do not breathe dust/fume/gas/mist/vapours/spray. |
P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. |
P262 | Do not get in eyes, on skin, or on clothing. |
P263 | Avoid contact during pregnancy/while nursing. |
P264 | Wash hands thoroughly after handling. |
P265 | Wash skin thouroughly after handling. |
P270 | Do not eat, drink or smoke when using this product. |
P271 | Use only outdoors or in a well-ventilated area. |
P272 | Contaminated work clothing should not be allowed out of the workplace. |
P273 | Avoid release to the environment. |
P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
P281 | Use personal protective equipment as required. |
P282 | Wear cold insulating gloves/face shield/eye protection. |
P283 | Wear fire/flame resistant/retardant clothing. |
P284 | Wear respiratory protection. |
P285 | In case of inadequate ventilation wear respiratory protection. |
P231 + P232 | Handle under inert gas. Protect from moisture. |
P235 + P410 | Keep cool. Protect from sunlight. |
Response | |
Code | Phrase |
P301 | IF SWALLOWED: |
P304 | IF INHALED: |
P305 | IF IN EYES: |
P306 | IF ON CLOTHING: |
P307 | IF exposed: |
P308 | IF exposed or concerned: |
P309 | IF exposed or if you feel unwell: |
P310 | Immediately call a POISON CENTER or doctor/physician. |
P311 | Call a POISON CENTER or doctor/physician. |
P312 | Call a POISON CENTER or doctor/physician if you feel unwell. |
P313 | Get medical advice/attention. |
P314 | Get medical advice/attention if you feel unwell. |
P315 | Get immediate medical advice/attention. |
P320 | |
P302 + P352 | IF ON SKIN: wash with plenty of soap and water. |
P321 | |
P322 | |
P330 | Rinse mouth. |
P331 | Do NOT induce vomiting. |
P332 | IF SKIN irritation occurs: |
P333 | If skin irritation or rash occurs: |
P334 | Immerse in cool water/wrap n wet bandages. |
P335 | Brush off loose particles from skin. |
P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. |
P337 | If eye irritation persists: |
P338 | Remove contact lenses, if present and easy to do. Continue rinsing. |
P340 | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P341 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | If experiencing respiratory symptoms: |
P350 | Gently wash with plenty of soap and water. |
P351 | Rinse cautiously with water for several minutes. |
P352 | Wash with plenty of soap and water. |
P353 | Rinse skin with water/shower. |
P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. |
P361 | Remove/Take off immediately all contaminated clothing. |
P362 | Take off contaminated clothing and wash before reuse. |
P363 | Wash contaminated clothing before reuse. |
P370 | In case of fire: |
P371 | In case of major fire and large quantities: |
P372 | Explosion risk in case of fire. |
P373 | DO NOT fight fire when fire reaches explosives. |
P374 | Fight fire with normal precautions from a reasonable distance. |
P376 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | |
P380 | Evacuate area. |
P381 | Eliminate all ignition sources if safe to do so. |
P390 | Absorb spillage to prevent material damage. |
P391 | Collect spillage. Hazardous to the aquatic environment |
P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
Home
* Country/Region
* Quantity Required :
* Cat. No.:
* CAS No :
* Product Name :
* Additional Information :
Total Compounds: mg
The concentration of the dissolution solution you need to prepare is mg/mL