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Structure of 1071125-59-1

Chemical Structure| 1071125-59-1

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Product Details of [ 1071125-59-1 ]

CAS No. :1071125-59-1
Formula : C27H18O9
M.W : 486.43
SMILES Code : O=C(O)C1=CC=C(OC2=CC(OC3=CC=C(C=C3)C(O)=O)=CC(OC4=CC=C(C=C4)C(O)=O)=C2)C=C1
MDL No. :MFCD30475486
InChI Key :PNPPEOGLIXXLAG-UHFFFAOYSA-N
Pubchem ID :91885097

Safety of [ 1071125-59-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 1071125-59-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1071125-59-1 ]

[ 1071125-59-1 ] Synthesis Path-Downstream   1~35

  • 1
  • [ 617-84-5 ]
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • 2C27H15O9(3-)*5C5H11NO*3Zn(2+) [ No CAS ]
  • 2
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • [Zn3(1,3,5-tri(4-carboxyphenoxy)benzene(-3H))2(H2O)2]*2H2O*4(dimethylformamide) [ No CAS ]
  • 3
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • [Zn3(1,3,5-tri(4-carboxyphenoxy)benzene)2(H2O)2]*4DMF*3H2O [ No CAS ]
  • 4
  • [ 109-99-9 ]
  • [ 1071125-59-1 ]
  • cadmium(II) nitrate [ No CAS ]
  • C27H15O9(3-)*1.5Cd(2+)*2C4H8O*H2O [ No CAS ]
  • 5
  • [ 10196-18-6 ]
  • [ 1071125-59-1 ]
  • [ 71-43-2 ]
  • [Zn1.5(4,4',4''-(benzene-1,3,5-triyltris(oxy))tribenzoate)(H2O)]·1.5benzene [ No CAS ]
  • 6
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • [Co3(4,4',4''-(benzene-1,3,5-triyl-tris(oxy))tribenzoic acid(-3H))2(H2O)2]·(DMF)4.5·(H2O)4 [ No CAS ]
  • 7
  • [ 123-91-1 ]
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • [Co3(4,4',4''-(benzene-1,3,5-triyl-tris(oxy))tribenzoic acid(-3H))2(H2O)2]·(DMF)3·(H2O)4·(dioxane)2.5 [ No CAS ]
  • 8
  • aluminum(III) nitrate nonahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 2C27H15O9(3-)*3Al(3+)*3HO(1-)*5.5C3H7NO*3H2O [ No CAS ]
  • 9
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • [Mg3/2(BTTB)(H2O)(N,N′-dimethylformamide)]n(N,N′-dimethylformamide)} [ No CAS ]
  • 10
  • [ 127-19-5 ]
  • [ 1071125-59-1 ]
  • [Mg3/2(BTTB)(N,N′-dimethylacetamide)2]n(N,N′-dimethylacetamide)0.5} [ No CAS ]
  • 11
  • manganese (II) sulfate monohydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • 3Mn(2+)*2C27H15O9(3-)*6H2O [ No CAS ]
  • 12
  • manganese (II) sulfate monohydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 3Mn(2+)*2C27H15O9(3-)*4C3H7NO [ No CAS ]
  • 13
  • manganese (II) nitrate tetrahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 3Mn(2+)*2C27H15O9(3-)*2H2O*4C3H7NO [ No CAS ]
  • 14
  • [ 67-56-1 ]
  • cobalt(II) nitrate hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 3Co(2+)*2C27H15O9(3-)*16CH4O*4C3H7NO [ No CAS ]
  • 15
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 3Cd(2+)*2C27H15O9(3-)*23H2O*3C3H7NO [ No CAS ]
  • 16
  • [ 123-91-1 ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • [ 7646-79-9 ]
  • [Co3(4,4',4''-(benzene-1,3,5-triyl-tris(oxy))tribenzoic acid(-3H))2(H2O)2]·(DMF)3·(H2O)4·(dioxane)2.5 [ No CAS ]
YieldReaction ConditionsOperation in experiment
40% at 120℃; for 72h; 4,4 ', 4' '- (1,3,5-triphenoxy) tribenzoic acid (0.1 mmol, 48.6 mg)And cobalt chloride (0.2 mmol, 47.6 mg) were dissolved in N, N'-dimethylformamide (2 mL)And 1,4-dioxane (2 mL) mixed solvent, sealed into 25 mL of hydrothermal reactor.The reaction mixture was then heated to 120 C at a temperature of 10 C per hour, maintained at this temperature for 3 days, and then allowed to cool to room temperature,To obtain purple columnar crystals in a yield of about 40%.
  • 17
  • [ 7784-27-2 ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • 2C27H15O9(3-)*3Al(3+)*3HO(1-)*5.5C3H7NO*3H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
76% at 10 - 120℃; for 72h;High pressure; A mixture of 4,4 ', 4 "- (1,3,5-triphenoxy) tribenzoic acid(0.65 mmol, 316.0 mg) was dissolved in N, N'-dimethylformamide (15 mL) with aluminum nitrate (0.5 mmol, 187.6 mg) and sealed into a 25 mL hydrothermal reactor.The reaction mixture was then heated at 10 C per hour to 120 C at constant temperature for 3 days and then dropped to room temperature to obtain colorless prismatic crystals available for single crystal X-ray diffraction analysis in a yield of about 76 %.
  • 18
  • [ 123-91-1 ]
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 25372-07-0 ]
  • [ 33513-42-7 ]
  • [Cd2(1,3,5-tris(4-carboxylatophenyloxy)benzene)(formate)(1,4-bis(imidazol-1-yl)benzene)(H2O)]·0.5dioxane}n [ No CAS ]
  • 19
  • manganese(II) chloride tetrahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 25372-07-0 ]
  • [ 33513-42-7 ]
  • [Mn1.5(1,3,5-tris(4-carboxylatophenyloxy)benzene)(1,4-bis(imidazol-1-yl)benzene)0.5(DMF)]n [ No CAS ]
  • 20
  • manganese(II) chloride tetrahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [Mn1.5(1,3,5-tris(4-carboxylatophenyloxy)benzene)(H2O)(μ2-OH2)]·H2O}n [ No CAS ]
  • 21
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [Cd3.5(1,3,5-tris(4-carboxylatophenyloxy)benzene)2(H2O)32-OH2)(μ3-OH)]·H2O}n [ No CAS ]
  • 22
  • [ 123-91-1 ]
  • [ 553-26-4 ]
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • C27H16O9(2-)*Co(2+)*C3H7NO*C10H8N2*0.5C4H8O2*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
56% In water; at 120℃; for 48h;Sealed tube; A mixture of H3tcpb (0.004 mmol, 1.9 mg), 4,40-bpy (0.08 mmol,1.2 mg) and CoCl2.6H2O (0.008 mmol, 1.9 mg) was dispersed in a1 mL DMF/1,4-dioxane/H2O (v/v/v = 1/1/2) mixed solution. Allreagents were sealed in a pressure-resistant glass tube, warmedto 120 C for 2 days, and then cooled to room temperature at acooling rate of 0.12 C/h. Red block crystals of 1 were obtained witha yield of 56% (based on Co). Anal. Calc. for C39H28CoN2O10: C,58.71; H, 3.51. Found: C, 59.14; H, 3.60%. IR (KBr pellet, cm1):3440 (w), 1703 (w), 1647 (w), 1548 (s), 1415 (s), 1228 (s), 1164(m), 1006 (m), 810 (w), 783 (m) (Fig. S1).
  • 23
  • [ 123-91-1 ]
  • [ 553-26-4 ]
  • cadmium(II) nitrate hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • C27H16O9(2-)*Cd(2+)*C3H7NO*C10H8N2*0.5C4H8O2*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
48% In water; at 120℃; for 48h;Sealed tube; General procedure: A mixture of H3tcpb (0.004 mmol, 1.9 mg), 4,40-bpy (0.08 mmol,1.2 mg) and CoCl2.6H2O (0.008 mmol, 1.9 mg) was dispersed in a1 mL DMF/1,4-dioxane/H2O (v/v/v = 1/1/2) mixed solution. Allreagents were sealed in a pressure-resistant glass tube, warmedto 120 C for 2 days, and then cooled to room temperature at acooling rate of 0.12 C/h. Red block crystals of 1 were obtained witha yield of 56% (based on Co).
  • 24
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • [Cd3(TCPB)2(H2O)2(DMF)2]*7H2O [ No CAS ]
  • 25
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • [ 7646-79-9 ]
  • [Co3(4,4',4''-(benzene-1,3,5-triyl-tris(oxy))tribenzoic acid(-3H))2(H2O)2]·(DMF)4.5·(H2O)4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
50% at 120℃; for 72h;Sealed tube; The 4, 4 ', 4" - (1, 3, 5 - triphenyl oxygen radical) three-benzoic acid (0.1 mmol, 48.6 mg) and cobalt chloride (0.2 mmol, 47.6 mg) is dissolved in N, N' - dimethyl formamide (3 ml) in, enclosed in and 25 ml of water hot reactor. Then the reaction mixture in order to every hour 10 C in heating to 120 C, to maintain this temperature 3 days, then cooled to the room temperature, to obtain the blue massive crystal, yield is about 50%.
  • 26
  • [ 123-91-1 ]
  • [ 51-17-2 ]
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • C27H15O9(3-)*2Zn(2+)*3C3H7NO*2C4H8O2*3H2O*C7H5N2(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
48% at 80℃; for 48h;Sealed tube; A mixture of H3tcpb (0.004 mmol, 1.9 mg), Hbim (0.008 mmol, 0.9 mg) and Zn(NO3)2·6H2O (0.008 mmol, 2.4 mg) was dissolved in a 1 mL DMF/1,4-dioxane/H2O (v/v/v = 1/1/2) mixed solution. All the reagents were sealed in a pressure-resistant glass tube, heated at 80 C for 2 days, and then cooled to room temperature at a descent rate of 0.08 C/h. Colorless block crystals of 3 were obtained with a yield of 48% (based on Zn). Anal. Calc. for C34H20N2O9Zn2: C, 55.79; H, 2.73. Found: C, 56.04; H, 2.80%. IR (KBr pellet, cm-1): 3382 (w), 1596 (s), 1460 (w), 1388 (s), 1220 (s), 1124 (m), 1016 (m), 780 (m) (Fig. S1).
  • 27
  • [ 123-91-1 ]
  • [ 855766-92-6 ]
  • cadmium(II) nitrate hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • 4C18H14N4*4C4H8O2*2.5H2O*C3H7NO*4C27H15O9(3-)*6Cd(2+) [ No CAS ]
  • 28
  • [ 123-91-1 ]
  • [ 855766-92-6 ]
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • 3Co(2+)*2C18H14N4*2.5C4H8O2*2H2O*C3H7NO*2C27H15O9(3-) [ No CAS ]
  • 29
  • [ 123-91-1 ]
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 56643-83-5 ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 3C4H8O2*C3H7NO*2C27H15O9(3-)*C14H14N4*1.5Zn(2+) [ No CAS ]
  • 30
  • [ 123-91-1 ]
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • [ 56643-83-5 ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 1.5Co(2+)*C4H8O2*C3H7NO*C27H15O9(3-)*0.5C14H14N4 [ No CAS ]
  • 31
  • [ 1071125-59-1 ]
  • [ 1135-32-6 ]
  • C27H18O9*C12H10N2 [ No CAS ]
  • 32
  • [ 4916-57-8 ]
  • [ 1071125-59-1 ]
  • C27H18O9*C12H12N2 [ No CAS ]
  • 33
  • [ 2645-22-9 ]
  • [ 1071125-59-1 ]
  • C27H18O9*C10H8N2S2 [ No CAS ]
  • 34
  • [ 123-91-1 ]
  • [ 855766-92-6 ]
  • nickel(II) nitrate hexahydrate [ No CAS ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 2C27H15O9(3-)*3Ni(2+)*4C4H8O2*C3H7NO*H2O*2C18H14N4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
48% In water; at 120℃; for 72h;Sealed tube; A mixture of H3TCPB (0.002 mmol, 0.9 mg), bibp (0.004 mmol, 1.2mg), Ni(NO3)2·6H2O (0.008 mmol, 2.3 mg) was dissolved in 1 mLmixed solution of DMF/1,4-dioxane/H2O (v/v/v =1/2/2), which was sealed in a near-vacuum glass tube and heated at 120 C for 72 h. The greenish petal-shaped crystals were achieved with a yield of 48% (basedon H3TCPB). Anal. (%) calcd. for C109H99Ni3N9O28: C, 60.63; H, 4.62;N, 5.83. Found (%): C, 60.64; H, 5.84; N, 5.85. IR (KBr pellet, cm-1):3426 (w), 1676 (m), 1591 (m), 1558 (s), 1398 (s), 1224 (s), 1155 (m),1006 (m), 962 (w), 781 (m) (Fig. S1).
  • 35
  • manganese(II) chloride tetrahydrate [ No CAS ]
  • [ 56643-83-5 ]
  • [ 1071125-59-1 ]
  • [ 33513-42-7 ]
  • 2C27H15O9(3-)*3Mn(2+)*2C3H7NO*C14H14N4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
35% In 1,4-dioxane; water; at 100℃; for 48h;Sealed tube; A mixture of H3TCPB (0.002 mmol, 0.9 mg), bimb (0.004 mmol,1.2 mg), MnCl2*4H2O (0.008 mmol, 1.6 mg) and 1 mL DMF/1,4-dioxane/H2O (v/v/v = 1/1/2) was transferred to hard glass tube, heated at 100 C for 48 h. After being cooled to room temperature with the falling rate of 2.5 C/h, the pale yellow lump crystals of 2 were obtained withthe yield of 35% (based on H3TCPB). Anal. (%) calcd. ForC74H58Mn3N6O20: C, 63.78; H, 5.66, N, 5.55. Found (%): C, 63.50;H, 5.42, N, 5.54. IR (KBr pellet, cm-1): 3429(w), 1683(s), 1589(w),1504(s), 1398(s), 1336(s), 1220(s), 1114(m), 1002(s), 860(w), 783(m)(Fig. S1).
 

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