Structure of 1071125-59-1
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CAS No. : | 1071125-59-1 |
Formula : | C27H18O9 |
M.W : | 486.43 |
SMILES Code : | O=C(O)C1=CC=C(OC2=CC(OC3=CC=C(C=C3)C(O)=O)=CC(OC4=CC=C(C=C4)C(O)=O)=C2)C=C1 |
MDL No. : | MFCD30475486 |
InChI Key : | PNPPEOGLIXXLAG-UHFFFAOYSA-N |
Pubchem ID : | 91885097 |
GHS Pictogram: |
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Signal Word: | Warning |
Hazard Statements: | H302-H315-H319-H335 |
Precautionary Statements: | P261-P280-P301+P312-P302+P352-P305+P351+P338 |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
40% | at 120℃; for 72h; | 4,4 ', 4' '- (1,3,5-triphenoxy) tribenzoic acid (0.1 mmol, 48.6 mg)And cobalt chloride (0.2 mmol, 47.6 mg) were dissolved in N, N'-dimethylformamide (2 mL)And 1,4-dioxane (2 mL) mixed solvent, sealed into 25 mL of hydrothermal reactor.The reaction mixture was then heated to 120 C at a temperature of 10 C per hour, maintained at this temperature for 3 days, and then allowed to cool to room temperature,To obtain purple columnar crystals in a yield of about 40%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
76% | at 10 - 120℃; for 72h;High pressure; | A mixture of 4,4 ', 4 "- (1,3,5-triphenoxy) tribenzoic acid(0.65 mmol, 316.0 mg) was dissolved in N, N'-dimethylformamide (15 mL) with aluminum nitrate (0.5 mmol, 187.6 mg) and sealed into a 25 mL hydrothermal reactor.The reaction mixture was then heated at 10 C per hour to 120 C at constant temperature for 3 days and then dropped to room temperature to obtain colorless prismatic crystals available for single crystal X-ray diffraction analysis in a yield of about 76 %. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | In water; at 120℃; for 48h;Sealed tube; | A mixture of H3tcpb (0.004 mmol, 1.9 mg), 4,40-bpy (0.08 mmol,1.2 mg) and CoCl2.6H2O (0.008 mmol, 1.9 mg) was dispersed in a1 mL DMF/1,4-dioxane/H2O (v/v/v = 1/1/2) mixed solution. Allreagents were sealed in a pressure-resistant glass tube, warmedto 120 C for 2 days, and then cooled to room temperature at acooling rate of 0.12 C/h. Red block crystals of 1 were obtained witha yield of 56% (based on Co). Anal. Calc. for C39H28CoN2O10: C,58.71; H, 3.51. Found: C, 59.14; H, 3.60%. IR (KBr pellet, cm1):3440 (w), 1703 (w), 1647 (w), 1548 (s), 1415 (s), 1228 (s), 1164(m), 1006 (m), 810 (w), 783 (m) (Fig. S1). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
48% | In water; at 120℃; for 48h;Sealed tube; | General procedure: A mixture of H3tcpb (0.004 mmol, 1.9 mg), 4,40-bpy (0.08 mmol,1.2 mg) and CoCl2.6H2O (0.008 mmol, 1.9 mg) was dispersed in a1 mL DMF/1,4-dioxane/H2O (v/v/v = 1/1/2) mixed solution. Allreagents were sealed in a pressure-resistant glass tube, warmedto 120 C for 2 days, and then cooled to room temperature at acooling rate of 0.12 C/h. Red block crystals of 1 were obtained witha yield of 56% (based on Co). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
50% | at 120℃; for 72h;Sealed tube; | The 4, 4 ', 4" - (1, 3, 5 - triphenyl oxygen radical) three-benzoic acid (0.1 mmol, 48.6 mg) and cobalt chloride (0.2 mmol, 47.6 mg) is dissolved in N, N' - dimethyl formamide (3 ml) in, enclosed in and 25 ml of water hot reactor. Then the reaction mixture in order to every hour 10 C in heating to 120 C, to maintain this temperature 3 days, then cooled to the room temperature, to obtain the blue massive crystal, yield is about 50%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
48% | at 80℃; for 48h;Sealed tube; | A mixture of H3tcpb (0.004 mmol, 1.9 mg), Hbim (0.008 mmol, 0.9 mg) and Zn(NO3)2·6H2O (0.008 mmol, 2.4 mg) was dissolved in a 1 mL DMF/1,4-dioxane/H2O (v/v/v = 1/1/2) mixed solution. All the reagents were sealed in a pressure-resistant glass tube, heated at 80 C for 2 days, and then cooled to room temperature at a descent rate of 0.08 C/h. Colorless block crystals of 3 were obtained with a yield of 48% (based on Zn). Anal. Calc. for C34H20N2O9Zn2: C, 55.79; H, 2.73. Found: C, 56.04; H, 2.80%. IR (KBr pellet, cm-1): 3382 (w), 1596 (s), 1460 (w), 1388 (s), 1220 (s), 1124 (m), 1016 (m), 780 (m) (Fig. S1). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
48% | In water; at 120℃; for 72h;Sealed tube; | A mixture of H3TCPB (0.002 mmol, 0.9 mg), bibp (0.004 mmol, 1.2mg), Ni(NO3)2·6H2O (0.008 mmol, 2.3 mg) was dissolved in 1 mLmixed solution of DMF/1,4-dioxane/H2O (v/v/v =1/2/2), which was sealed in a near-vacuum glass tube and heated at 120 C for 72 h. The greenish petal-shaped crystals were achieved with a yield of 48% (basedon H3TCPB). Anal. (%) calcd. for C109H99Ni3N9O28: C, 60.63; H, 4.62;N, 5.83. Found (%): C, 60.64; H, 5.84; N, 5.85. IR (KBr pellet, cm-1):3426 (w), 1676 (m), 1591 (m), 1558 (s), 1398 (s), 1224 (s), 1155 (m),1006 (m), 962 (w), 781 (m) (Fig. S1). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
35% | In 1,4-dioxane; water; at 100℃; for 48h;Sealed tube; | A mixture of H3TCPB (0.002 mmol, 0.9 mg), bimb (0.004 mmol,1.2 mg), MnCl2*4H2O (0.008 mmol, 1.6 mg) and 1 mL DMF/1,4-dioxane/H2O (v/v/v = 1/1/2) was transferred to hard glass tube, heated at 100 C for 48 h. After being cooled to room temperature with the falling rate of 2.5 C/h, the pale yellow lump crystals of 2 were obtained withthe yield of 35% (based on H3TCPB). Anal. (%) calcd. ForC74H58Mn3N6O20: C, 63.78; H, 5.66, N, 5.55. Found (%): C, 63.50;H, 5.42, N, 5.54. IR (KBr pellet, cm-1): 3429(w), 1683(s), 1589(w),1504(s), 1398(s), 1336(s), 1220(s), 1114(m), 1002(s), 860(w), 783(m)(Fig. S1). |
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