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Chemical Structure| 102074-60-2 Chemical Structure| 102074-60-2

Structure of 102074-60-2

Chemical Structure| 102074-60-2

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Product Details of [ 102074-60-2 ]

CAS No. :102074-60-2
Formula : C7H9NO2
M.W : 139.15
SMILES Code : OCC1=C(OC)C=NC=C1
MDL No. :MFCD16606979
InChI Key :BAHUOCIALOMKRJ-UHFFFAOYSA-N
Pubchem ID :19805479

Safety of [ 102074-60-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of [ 102074-60-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 102074-60-2 ]

[ 102074-60-2 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 102074-60-2 ]
  • [ 1849-52-1 ]
YieldReaction ConditionsOperation in experiment
190 mg With manganese(IV) oxide In ethyl acetate for 3 h; Reflux Manganese dioxide (843 mg) was added to a solution of (3-methoxypyridin-4-yl)methanol (270 mg) in ethyl acetate (10 mL), followed by refluxing for 2 hours. Manganese dioxide (167 mg) was added thereto, followed by refluxing for 1 hour. The reaction mixture was cooled to room temperature, the insoluble materials were filtered off, and the solvent was distilled off under reduced pressure. The obtained residues were purified by silica gel column chromatography (hexane:ethyl acetate=1:1→0:1), whereby 3-methoxyisonicotinic aldehyde (190 mg) was obtained as a white solid.
References: [1] Patent: WO2007/67511, 2007, A2, . Location in patent: Page/Page column 35.
[2] Patent: US2016/168139, 2016, A1, . Location in patent: Paragraph 0944; 0949; 0950.
 

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