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Chemical Structure| 100-68-5 Chemical Structure| 100-68-5

Structure of Methylphenylsulfide
CAS No.: 100-68-5

Chemical Structure| 100-68-5

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Product Citations

Product Citations

Morningstar, John Tanner ;

Abstract: Molecular electronics is a continuously growing field which attempts to solve the problem that their solid-state counterparts encounter with continuing to grow smaller while maintaining the same functionality. Although successful molecular electronics have been created, their level of functionality does not yet match solid states. Furthering the field involves elucidating the mechanism of rectification and continuing to grow the library of compounds available. To accomplish this, we have successfully synthesized twenty new alkylsilanes which exhibit rectification behavior. We were able to draw several conclusions about promising scaffolds through examination of terminal groups with electron withdrawing and donating substituents, nitrogen heterocycles, and sterically hindered substituents. Additionally, our compounds were subjected to doping of the selfassembled monolayer devices which we found to benefit rectification. It was hypothesized that adding electron withdrawing groups, large and soft atoms, and groups with non-bonding electrons would also boost rectification. We obtained compounds with R ratios as high as 8500. This value is the highest our group has achieved to date. Biopolymers are commonly used as drug delivery scaffolds due to their safety and resistance to environmental stimuli. Alginate is one such polymer which has garnered increased attention as of late. To improve the properties of alginate for this purpose, we have developed a method to quantitatively modify the backbone of alginate with small molecules via sodium periodate oxidation and reductive amination of the corresponding oxidized product. Examining the difference in modified alginate with a small unsubstituted aromatic ring as well as an aromatic ketone, ester, and carboxylic acid allowed us to determine which molecules are beneficial to environmental pH sensitivity. xiv We successfully synthesized three new quantitatively modified alginates and examined their pH sensitivity using hydrogel beading studies. Each new compound shows distinct pH response; however, our expectations were met as our original benzoic acid modified product still holds the most desirable degradation profile.

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Product Details of [ 100-68-5 ]

CAS No. :100-68-5
Formula : C7H8S
M.W : 124.20
SMILES Code : CSC1=CC=CC=C1
MDL No. :MFCD00008559
InChI Key :HNKJADCVZUBCPG-UHFFFAOYSA-N
Pubchem ID :7520

Safety of [ 100-68-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H227-H315-H318-H335-H410
Precautionary Statements:P210-P261-P264-P271-P273-P280-P302+P352-P304+P340-P305+P351+P338-P310-P321-P332+P313-P362-P370+P378-P391-P403+P233-P403+P235-P405-P501
Class:9
UN#:3334
Packing Group:

Application In Synthesis of [ 100-68-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 100-68-5 ]

[ 100-68-5 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 3652-92-4 ]
  • [ 882-33-7 ]
  • [ 2622-63-1 ]
  • [ 100-68-5 ]
  • [ 108-98-5 ]
  • 1,3-Dimethyl-2-phenylbenzenediazolium phenylthiolate [ No CAS ]
  • 2
  • [ 100-68-5 ]
  • [ 459-04-1 ]
  • [ 87483-29-2 ]
YieldReaction ConditionsOperation in experiment
48% In carbon disulfide; Step 1 Preparation of 1-(4-methylthiophenyl)-2-(4-fluorophenyl)ethanone; To a stirred solution of thioanisole (380 mL, 3.2 mol) and 4-fluorophenylacetyl chloride (300 g, 1.6 mol) in carbon disulfide (1.2 L), cooled to 5 C., was added anhydrous aluminum chloride portionwise at such a rate that the internal temperature did not rise above 15 C. The reaction was stirred at room temperature for 16 hours. The solution was cautiously poured into 2 L of ice and water. The aqueous solution was extracted with methylene chloride (6*150 mL), the combined extracts were dried over anhydrous MgSO4, filtered and concentrated in vacuo. The residue was dissolved in 800 mL of ether and cooled to 0 C. whereupon crystals of pure product formed which were isolated by filtration on a Buchner funnel and air dried to provide the ketone (199.6 g, 48%): mp 135-138 C. 1 H NMR (CDCl3 /TMS) 300 MHz 8.00 (d, J=8.7 Hz, 2H), 7.40-7.30 (m, 4H), 7.13-7.03 (m, 2H), 4.34 (s, 2H), 2.56 (s, 3H). Mass spectrum M+ =260.
  • 3
  • [ 100-68-5 ]
  • [ 122135-83-5 ]
  • 2-[(1E)-2-(phenylthio)-1-[(phenylthio)methyl]ethenyl]-phenol [ No CAS ]
 

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