Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 579-07-7 Chemical Structure| 579-07-7
Chemical Structure| 579-07-7

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

1-Phenyl-1,2-propanedione is an eukaryotic metabolite produced during a metabolic reaction in plants.

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of 1-Phenylpropane-1,2-dione

CAS No. :579-07-7
Formula : C9H8O2
M.W : 148.16
SMILES Code : CC(C(C1=CC=CC=C1)=O)=O
MDL No. :MFCD00008755
InChI Key :BVQVLAIMHVDZEL-UHFFFAOYSA-N
Pubchem ID :11363

Safety of 1-Phenylpropane-1,2-dione

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225
Precautionary Statements:P501-P240-P210-P233-P243-P241-P242-P280-P370+P378-P303+P361+P353-P403+P235
Class:3
UN#:1224
Packing Group:

Application In Synthesis of 1-Phenylpropane-1,2-dione

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 579-07-7 ]

[ 579-07-7 ] Synthesis Path-Downstream   1~26

  • 1
  • [ 17019-26-0 ]
  • [ 579-07-7 ]
  • 3
  • [ 17019-18-0 ]
  • [ 579-07-7 ]
  • [ 17019-26-0 ]
  • 4
  • [ 579-07-7 ]
  • [ 90-63-1 ]
YieldReaction ConditionsOperation in experiment
78% With Thiamine hydrochloride; triethylamine; In PEG400; at 20℃; for 3h; Method A. To a vigorously stirred mixture of thiamine hydrochloride 2 (337 mg, 1.00 mmol), Et3N (279 muL, 2.00 mmol), and PEG400 (4 mL) alpha-diketone 1f (293 muL, 2.00 mmol) was added in one portion. The mixture was stirred at room temperature for 3 h and then diluted with Et2O (5 mL). The resulting mixture was vigorously stirred for 5 min, allowed to separate out and the ethereal solution was decanted. This process was repeated twice. The collected ethereal fractions were concentrated and the resulting residue was eluted from a column of silica gel with 4:1 cyclohexane/AcOEt to give 5frefPreviewPlaceHolder22 (234 mg, 78percent) as a white amorphous solid. ESI MS (150.1): 173.7 (M+Na+).CommentThe subsequent elution with AcOEt afforded a mixture of PEG-OBz and PEG-OAc. PEG-OBz: 1H NMR: delta=8.20-8.05, 7.60-7.50, and 7.48-7.40 (3m, Ph), 4.50-4.40 and 3.90-3.80 (2m, OCH2CH2OBz), 3.70-3.50 (m, OCH2CH2O-). PEG-OAc: 1H NMR: delta=4.30-4.20 and 3.60-3.50 (2m, OCH2CH2OAc), 3.70-3.50 (m, OCH2CH2O-), 2.08 (s, CH3).
  • 5
  • [ 673-32-5 ]
  • [ 67-56-1 ]
  • [ 21120-43-4 ]
  • [ 14320-36-6 ]
  • [ 703-17-3 ]
  • [ 29548-91-2 ]
  • [ 110097-47-7 ]
  • [ 579-07-7 ]
  • 6
  • [ 673-32-5 ]
  • [ 14320-36-6 ]
  • [ 703-17-3 ]
  • [ 29548-91-2 ]
  • [ 579-07-7 ]
  • 7
  • [ 75-07-0 ]
  • [ 579-07-7 ]
  • [ 90-63-1 ]
  • [ 122171-88-4 ]
  • [ 122171-88-4 ]
  • [ 122171-86-2 ]
  • 8
  • [ 75-07-0 ]
  • [ 579-07-7 ]
  • [ 90-63-1 ]
  • [ 122171-88-4 ]
  • [ 122171-86-2 ]
  • [ 122171-86-2 ]
  • 10
  • [ 579-07-7 ]
  • [ 5650-40-8 ]
  • [ 90-63-1 ]
  • [ 1075-04-3 ]
  • [ 1075-05-4 ]
  • 13
  • [ 579-07-7 ]
  • [ 90-63-1 ]
  • [ 5650-40-8 ]
  • [ 5650-40-8 ]
  • 14
  • [ 7664-93-9 ]
  • [ 17019-18-0 ]
  • [ 579-07-7 ]
  • [ 17019-26-0 ]
  • 15
  • [ 7664-93-9 ]
  • [ 579-07-7 ]
  • hydroxylamine sulfate [ No CAS ]
  • [ 17019-26-0 ]
  • 16
  • [ 4187-87-5 ]
  • [ 7732-18-5 ]
  • mercury(II) sulfate [ No CAS ]
  • [ 90-63-1 ]
  • [ 579-07-7 ]
  • 17
  • [ 90-63-1 ]
  • copper [ No CAS ]
  • [ 579-07-7 ]
  • 18
  • [ 579-07-7 ]
  • hydroxylamine sulfate [ No CAS ]
  • [ 17019-26-0 ]
  • 19
  • [ 64-17-5 ]
  • [ 7664-93-9 ]
  • [ 50353-41-8 ]
  • [ 90-63-1 ]
  • [ 579-07-7 ]
  • 20
  • (+-)-2-hydroxy-3-phenyl-propionaldehyde [ No CAS ]
  • [ 90-63-1 ]
  • [ 579-07-7 ]
  • 21
  • [ 579-07-7 ]
  • [ 90-63-1 ]
  • [ 5650-40-8 ]
  • 23
  • [ 579-07-7 ]
  • [ 5650-40-8 ]
  • [ 88196-06-9 ]
  • [ 40421-52-1 ]
  • [ 90-63-1 ]
  • 24
  • [ 6668-24-2 ]
  • [ 579-07-7 ]
  • 25
  • [ 6624-71-1 ]
  • [ 579-07-7 ]
  • dodecyl 3-hydroxy-2,2-dimethyl-4-oxo-3-phenylpentanoate [ No CAS ]
  • dodecyl 3-hydroxy-2,2,3-trimethyl-4-oxo-4-phenylbutyrate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In hexane; ethyl acetate; EXAMPLE IV Dodecyl 3-hydroxy-2,2-dimethyl-4-oxo-3-phenylpentanoate and Dodecyl 3-hydroxy-2,2,3-trimethyl-4-oxo-4-phenylbutyrate STR10 The reaction of <strong>[6624-71-1]dodecyl isobutyrate</strong> (6.4 g, 0.025 mole) with 1-phenyl-1,2-propanedione (3.7 g, 0.025 mole) is conducted in the manner described in Example I. Thin layer chromatography of the crude reaction mixture indicated the presence of two main reaction products. High pressure liquid chromatography on silica gel using 2% ethyl acetate in hexane as the eluant yields pure dodecyl 3-hydroxy-2,2-dimethyl-4-oxo-3-phenylpentanoate (IVa) (3.2 g, 32%), b.p. 148 C. (Kugelrohr air bath temperature) at 0.005 mm Hg. Also recovered is pure dodecyl 3-hydroxy-2,2,3-trimethyl-4-oxo-4-phenylbutyrate (IVb) (3.5 g, 35%), b.p. 145 C. (Kugelrohr air bath temperature) at 0.005 mm Hg. IR and NMR confirm the structure of the two products. Anal. calc. for C25 H40 O5 (IVa): C, 74.21; H, 9.97. Found: C, 74.45; H, 9.98. Anal. calc. for C25 H40 O5 (IVb): C, 74.21; H, 9.97. Found: C, 74.40; H, 9.85.
 

Historical Records

Technical Information

Categories