Oxazoline Ligands

Oxazoline Ligands

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Most Wished for in Oxazoline Ligands
Classical PyOx ligands Pyridine-based oxazoline ligands Aromatic heterooxazoline ligands Classical Bioxazoline ligands SaBOX Ligand Cyclic oxazoline ligands Other Bioxazoline ligands
Note:

R=i-Pr,t-Bu,Ph,Bn,etc.R'=H,PhR1=H,Me,Ph,CHPh2,etc.R2=H,OMe,etc.R3=H,Me,Et,etc.R4=H,Me,Et,CN,etc.R5=Me,Et,Bn,4-t-BuBn,4-AdBn,etc.R6=Bn,4-t-BuBn,4-AdBn,etc.X=H,CF3,Cl,Br,F,etc.X'=H,CF3Y=H,Nn=1,2,3,4...

Applications of Oxazoline Ligands in Asymmetric Catalysis

Oxazoline ligands currently dominate in asymmetric synthesis, they have been extensively applied in a series of important metal-catalyzed enantioselective reactions.

Technical Notes:

Nickel/Photo-Cocatalyzed Asymmetric Acyl-Carbamoylation of Alkenes.[1]

Asymmetric Ni-Catalyzed Radical Relayed Reductive Coupling.[2]

Modular access to substituted cyclohexanes with kinetic stereocontrol.[3]

Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes.[4]

Asymmetric Allylic C-H Alkylation via Palladium(II)/cis-ArSOX Catalysis.[5]

Reference:

[1] J. Am. Chem. Soc. 2020, 142, 2180.

[2] J. Am. Chem. Soc. 2020, 142, 13515.

[3] Science, 2022, 376, 749.

[4] J. Am. Chem. Soc. 2019, 141, 14480.

[5] J. Am. Chem. Soc. 2018, 140, 10658.

Available Ligands in Ambeed.

1. PyOX Series

2. BOX Series

3.PHOX Series

4.SOX Series