BIDIME & BIBOP Ligands

A6763061268693-24-8

4-(Anthracen-9-yl)-3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole

A8387071246888-90-3

3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole

A10059391373432-11-1

(2S,3S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole

A10059311884680-45-8

(2R,2'R,3R,3'R)-4,4'-Di(anthracen-9-yl)-3,3'-di-tert-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole

A11493711202033-19-9

(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-dimethoxy-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole

A11751242207601-10-1

(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-2,2'-dimethyl-2,2',3,3'-tetrahydro-4,4'-bibenzo[d][1,3]oxaphosphole

Technical Notes:

1.Ligand for highly enantioselective rhodium-catalyzed addition of arylboroxines to N-unprotected ketimines.

2.Ligand for palladium catalyzed α-arylation of sterically hindered substrates.

3.Ligand for highly enantioselective alkene aryloxyarylation led to the high-yielding formation of a series of 1,4-benzodioxanes and 1,4-benzooxazines.

4.Ligand for asymmetric Suzuki-Miyaura aryl−aryl cross-coupling.

5.Ligand for diastereoselective hydrogenation of β-aryl enamides.

6.Ligand for asymmetric hydroboration and diboration.

7.Ligand for asymmetric palladium-catalyzed intramolecular arylation.

8.Ligand for asymmetric Suzuki-Miyaura coupling of tetra-orthosubstituted biaryls.

Ligand for highly enantioselective rhodium-catalyzed addition of arylboroxines to N-unprotected ketimines.[1]

Ligand for palladium catalyzed α-arylation of sterically hindered substrates.[2]

Ligand for highly enantioselective alkene aryloxyarylation led to the high-yielding formation of a series of 1,4-benzodioxanes and 1,4-benzooxazines.[3]

Ligand for asymmetric aryl−aryl cross-coupling.[4]

Ligand for diastereoselective hydrogenation of β-aryl enamides.[5]

Ligand for asymmetric hydroboration and diboration.[6]

Ligand for asymmetric palladium-catalyzed intramolecular arylation.[7]

Ligand for asymmetric Suzuki-Miyaura coupling of tetra-orthosubstituted biaryls.[8]

Reference： [1] Angew. Chem., Int. Ed. 2019, 58, 16119. [2] Angew. Chem., Int. Ed. 2018, 57, 12328. [3] Angew. Chem., Int. Ed. 2016, 55, 5044. [4] J. Am. Chem. Soc. 2020, 142, 8036. [5] J. Am. Chem. Soc. 2014, 136, 570. [6] J. Am. Chem. Soc. 2015, 137, 6746. [7] J. Am. Chem. Soc. 2018, 140, 4508. [8] ACS Catal. 2018, 8, 10190.