Products Cited in Publications Worldwide Auxetic Liquid Crystal Elastomers: Overcoming Barriers to Scale-Up

Auxetic Liquid Crystal Elastomers: Overcoming Barriers to Scale-Up

Berrow, Stuart R; Raistrick, Thomas; Mandle, Richard J; Gleeson, Helen F

Abstract

The observation of auxetic behaviour (i.e. negative Poisson’s ratio) in liquid crystal elastomers (LCEs) presents an exciting opportunity to explore application areas previously inaccessible to LCEs. Since its initial discovery, research has focused on improving understanding of the underpinning physics that drives the auxetic response, the structure-property relationships that enable the response to be tuned, and LCE properties such as the refractive index. However, the auxetic LCE materials reported to date have made use of either mechanical strain during fabrication, or unreactive ‘templates’ to stabilize the nematic ordering in the precursors. The latter approach provides excellent monodomain films, but there is unavoidable anisotropic shrinkage of the LCE. Both processes previously employed create complications towards manufacturing and scale-up. In this article, we report the first example of an auxetic LCE synthesized through surface alignment without the use of a non-reactive ‘template’ and thus without the need for a washout. The LCE includes both terminally and laterally attached mesogens, presents an auxetic threshold of 76% strain, and displays a comparable dependence of auxetic behaviour on its glass transition temperature as that reported in the literature. This work presents an exciting milestone in the journey towards realizing applications for auxetic LCEs.

Keywords

Liquid crystal elastomer ; Auxetic ; Mechanical metamaterials ; Elastomer ; Network

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