Products Cited in Publications Worldwide From Donor-Acceptor Ligands to Smart Coordination Polymers: Cyanothiazole-Cu (I) Complexes for Multifunctional Electronic Devices

From Donor-Acceptor Ligands to Smart Coordination Polymers: Cyanothiazole-Cu (I) Complexes for Multifunctional Electronic Devices

Gutmańska, Karolina; Podborska, Agnieszka; Mazur, Tomasz; Sławek, Andrzej; Sivasamy, Ramesh; Maximenko, Alexey; Orzeł, Łukasz; Oszajca, Janusz; Stochel, Grażyna; Dev, Amarjith V

DOI: PMID:

Abstract

Cyanothiazoles, small and quite overlooked molecules, possess remarkable optical properties that can be fine-tuned through coordination with transition metals. In this study, we investigate a promising application of cyanothiazoles, where their combination with copper(I) iodide forms a new class of complexes exhibiting outstanding optical properties. X-ray crystallography of copper(I) iodide complexes with isomeric cyanothiazoles revealed key structural features, such as π-π stacking, hydrogen bonding, and rare halogen···chalcogen I···S interactions, enhancing stability and reactivity. Advanced spectroscopy and computational modeling allowed precise identification of spectral signatures in FTIR, NMR, and UV-Vis spectra. Fluorescence studies, along with XANES synchrotron analyses, highlighted their unique thermal and electronic properties, providing a solid foundation for further research in the field.

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A1070861452-16-098%

2-Cyanothiazole

13.0/250mg

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