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Chemical Structure| 939822-77-2 Chemical Structure| 939822-77-2

Structure of 939822-77-2

Chemical Structure| 939822-77-2

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Product Details of [ 939822-77-2 ]

CAS No. :939822-77-2
Formula : C28H27NO
M.W : 393.52
SMILES Code : N#CC1=CC=C2C=C(C3=CC=C(OC)C(C4(C5)CC6CC5CC(C6)C4)=C3)C=CC2=C1

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Application In Synthesis of [ 939822-77-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 939822-77-2 ]

[ 939822-77-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 939822-48-7 ]
  • [ 145369-29-5 ]
  • [ 939822-77-2 ]
YieldReaction ConditionsOperation in experiment
83% With potassium phosphate;tetrakis(triphenylphosphine) palladium(0); In tetrahydrofuran; water; for 17h;Heating / reflux;Product distribution / selectivity; Preparation of 6-[3-(1 -adamantyl)-4-methoxyphenyl1-2- cvanonaphthalene2,4,6-Tris[3-(1 -adamantyl)-4-methoxyphenyl]-1 ,3,5,2,4,6-trioxatriborinane (889 mg, 1.11 mmol), 6-cyanonaphthalenyl thfluoromethanesulfonate (500 mg, 1.66 mmol), K3PO4 (1 ,41 g, 6.64 mmol), THF (10 ml) and H2O (2 ml) were placed in a Schlenk flask and the reaction mixture was deoxygenated (3 freeze-thaw cycles). Immediately after, Pd(PPh3)4 (96 mg, 0.083 mmol) was added and the mixture was deoxygenated again (2 freeze-thaw cycles). After heating to reflux for 17 h, the reaction mixture was diluted, while still hot, in toluene (50 ml). The mixture was filtered through celite which was washed with hot toluene (2 x 50 ml). The combined organic phases were washed with hot H2O (2 x 50 ml). The organic phase was evaporated and a crude product (906 mg) was obtained that was recrystallized with a minimum volume of <n="24"/>toluene at reflux (6.2 ml), leading to the title compound (541 mg, 83%) as a gray powder. The spectroscopic data coincide with those of Example 11.
 

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