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Chemical Structure| 922528-07-2 Chemical Structure| 922528-07-2

Structure of 922528-07-2

Chemical Structure| 922528-07-2

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Product Details of [ 922528-07-2 ]

CAS No. :922528-07-2
Formula : C11H16O2
M.W : 180.24
SMILES Code : CC/C=C/C=C/C=C/C(OCC)=O

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Application In Synthesis of [ 922528-07-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 922528-07-2 ]

[ 922528-07-2 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 867-13-0 ]
  • [ 4313-03-5 ]
  • [ 922528-07-2 ]
  • 2
  • [ 4313-03-5 ]
  • [ 1099-45-2 ]
  • [ 922528-07-2 ]
YieldReaction ConditionsOperation in experiment
In chloroform;Inert atmosphere; A solution of 8 and 10 (1.5 eq.) in CHCl3 (50 mL) was heated to reflux. After TLC analysis indicated thatthe reaction was completed, the reaction mixture was concentrated under reduced pressure and purified bysilica gel chromatography (ethyl acetate/hexane = 10/90) to afford trienoate 11. Conversion of 11 toaldehyde 12 was performed as above for the synthesis of 8 using DIBAL-H and MnO2. Finally, 12 wasreacted with 9 as before to produce tetraenone 2p (18percent overall yield).
 

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