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Chemical Structure| 863027-98-9 Chemical Structure| 863027-98-9

Structure of 863027-98-9

Chemical Structure| 863027-98-9

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Product Details of [ 863027-98-9 ]

CAS No. :863027-98-9
Formula : C16H19Br2NO2
M.W : 417.14
SMILES Code : O=C1N(C(C2=C(C=CC(Br)=C21)Br)=O)CC(CC)CCCC
InChI Key :MFVRURWCDDILCC-UHFFFAOYSA-N
Pubchem ID :59523077

Safety of [ 863027-98-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of [ 863027-98-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 863027-98-9 ]

[ 863027-98-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 104-75-6 ]
  • [ 25834-16-6 ]
  • [ 863027-98-9 ]
YieldReaction ConditionsOperation in experiment
In acetic acid; Example 1 N-(2-ethylhexyl)-3,6-dibromophthalimide: <strong>[25834-16-6]3,6-Dibromo phthalic anhydride</strong> (1.53 g, 5 mmol), 2-ethylhexyl amine (0.84 g, 6.5 mmol) and glacial acetic acid (30 ml) were combined and refluxed under argon for two hours. After most of the acetic acid was removed under reduced pressure, N-(2-ethylhexyl)-3,6-dibromophthalimide was separated via column chromatography (silica gel, dichloromethane:hexanes 1:3). Colorless crystals were obtained after recrystallization from hexanes (1.88 g, 90%). 1H NMR (CDCl3, 400 MHz, ppm): delta 7.63 (s, 2H), 3.56 (d, 2H), 1.80 (m, 1H), 1.29 (m, 8H), 0.88 (m, 6H). 13C NMR (CDCl3, 100 MHz, ppm): delta 165.34, 139.71, 131.42, 117.71, 42.66, 38.46, 30.77, 28.76, 24.09, 23.16, 14.26, 10.59. mp: 65 C. GC-MS: m/z: 415 (C16H19Br2NO2+), 319 (100%). Anal. Calcd for C16H19Br2NO2(%): C, 46.07; H, 4.59; N, 3.36.
 

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