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Chemical Structure| 627909-24-4 Chemical Structure| 627909-24-4

Structure of 627909-24-4

Chemical Structure| 627909-24-4

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Product Details of [ 627909-24-4 ]

CAS No. :627909-24-4
Formula : C10H14F9O3P
M.W : 384.18
SMILES Code : FC(F)(F)C(F)(F)C(F)(F)C(F)(F)CCP(OCC)(OCC)=O
MDL No. :MFCD30063053

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Application In Synthesis of [ 627909-24-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 627909-24-4 ]

[ 627909-24-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 2043-55-2 ]
  • [ 122-52-1 ]
  • [ 627909-24-4 ]
  • ethyl 1H,1H,2H,2H-perfluorohexyl ethylphosphonate [ No CAS ]
  • [ 78-40-0 ]
YieldReaction ConditionsOperation in experiment
Preparation of [CF3 (CF213CH2CH2LO-3H2] A mixture of 37.4 g of [1-IODO-LH, LH,] 2H, [2H-PERFLUOROHEXANE] and 50.0 g of triethyl phosphite was heated at [150 °C.] After 16 hr, an additional 50.0 g of triethyl phosphite was added, and heating was continued. After 2 hr, an additional 50.0 g of triethyl phosphite was again added, and heating was continued for another 24 hr. Diethyl ethylphosphonate and other volatiles were removed by distillation through a 12-inch (30 cm) vacuum- jacketed packed column, b. p. [34-38 °C] at 0.05 torr (7 Pa). Distillation of the concentrate provided 22.3 g of [1-DIETHYLPHOSPHONO-LH, LH,] 2H, 2H-perfluorohexane as a 90: 2: 7 mixture with triethyl phosphate and ethyl 1H, lH, 2H, 2H-perfluorohexyl ethylphosphonate as a clear, colorless liquid, b. p. [47-51 °C] at 0.05 torr (7 Pa).
 

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