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Chemical Structure| 612-94-2 Chemical Structure| 612-94-2

Structure of 612-94-2

Chemical Structure| 612-94-2

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Product Details of [ 612-94-2 ]

CAS No. :612-94-2
Formula : C16H12
M.W : 204.27
SMILES Code : C1(C2=CC=CC=C2)=CC=C3C=CC=CC3=C1
MDL No. :MFCD00039601

Safety of [ 612-94-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501

Application In Synthesis of [ 612-94-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 612-94-2 ]

[ 612-94-2 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 59046-72-9 ]
  • [ 536-74-3 ]
  • [ 612-94-2 ]
YieldReaction ConditionsOperation in experiment
28% With toluene-4-sulfonic acid; In 1,2-dichloro-ethane; at 200℃; for 0.5h;Microwave irradiation; General procedure: A solution of <strong>[59046-72-9]2-(phenylethynyl)benzaldehyde</strong> (1) (0.60 mmol, 124 mg), alkyne 2 (0.30 mmol), and TsOH.H2O(0.90 mmol, 171 mg) in ClCH2CH2Cl (2.0 mL) was treated at 200 Cfor 30 min under microwave condition (Biotage INITIATOR; Allreactions were carried out under temperature-constant operation). Thereaction mixture was diluted with CHCl3 and washed with saturatedNaHCO3 (aq) and brine. The organic layer was dried over MgSO4.After removal of the solvent under reduced pressure, the residue waspurified by chromatography on SiO2 to give the naphthalene derivatives. Further purification was carried out a recyclable preparativeHPLC, if necessary. The structures of the products were assigned bytheir NMR spectra. The product was characterized by comparing itsspectral data with previous report.8a
  • 2
  • [ 91-20-3 ]
  • [ 3027-21-2 ]
  • [ 612-94-2 ]
  • [ 605-02-7 ]
  • 3
  • [ 2243-58-5 ]
  • potassium phenyltrifluoborate [ No CAS ]
  • [ 612-94-2 ]
  • 4
  • [ 1632-83-3 ]
  • [ 93-04-9 ]
  • [ 100-58-3 ]
  • [ 2622-63-1 ]
  • [ 612-94-2 ]
  • [ 612-78-2 ]
  • [ 3367-00-8 ]
 

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