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Chemical Structure| 58779-09-2 Chemical Structure| 58779-09-2

Structure of 58779-09-2

Chemical Structure| 58779-09-2

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Product Details of [ 58779-09-2 ]

CAS No. :58779-09-2
Formula : C29H24O6
M.W : 468.50
SMILES Code : O=C1C[C@@H](C2=CC=CC=C2)OC3=C(CC4=CC=CC=C4O)C(O)=C(CC5=CC=CC=C5O)C(O)=C13
MDL No. :N/A

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Application In Synthesis of [ 58779-09-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 58779-09-2 ]

[ 58779-09-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 90-01-7 ]
  • [ 480-39-7 ]
  • [ 58779-09-2 ]
YieldReaction ConditionsOperation in experiment
59% With zinc(II) chloride; In 1,4-dioxane; at 100℃; for 24h; (+/-)-Dichamanetm (2).; A solution of 4 (60 mg, 0.23 mmol, 1.0 equiv), <n="78"/>2-hydroxybenzyl alcohol 10 (61 mg, 0.48 mmol, 2.1 equiv), and anhydrous ZnCl2 (67 mg, 0.48 mmol, 2.1 equiv) in anhydrous dioxane (2 mL) was heated at 100 C for 24 h under an atmosphere of argon. After cooling, the solvent was removed in vacuo and the crude product was purified by flash column chromatography (0 to 30% EtOAc/Hexanes) to afford 2 (65 mg, 59%) as a light yellow solid, Rv 0.32 (30% EtOAc in Hexanes): 1H NMR (500 MHz5 CD3COCD3) delta 12.73 (s, IH), 9.15 (br s, 2H), 7.59 (d, J= 7.5 Hz, 2H),7.46-7.38 (m, 3H), 7.23-7.22 (m, IH), 7.09-7.07 (m, IH), 7.04-6.99 (m, 2H), 6.86 (t, J= 7.5 Hz, 2H), 6.77-6.69 (m, 2H), 5.64 (dd, J= 2.5, 10.0 Hz, 2H), 3.92-3.91 (two s, 4H), 3.23 (dd, J= 13.0, 4.0 Hz, IH), 2.90 (dd, J= 3.0, 14.0 Hz, IH); 13C NMR (125 MHz, CD3COCD3) delta 198.7, 163.6, 161.7, 160.6, 155.6, 141.2, 132.3, 132.1, 130.6, 130.5, 130.4, 129.03, 128.99, 128.7, 128.67, 128.3, 122.1, 122.0, 116.9, 116.8, 109.6, 108.7, 104.5, 81.0, 44.6, 24.4, 23.7; IR (CDCl3) 3427, 1631, 1489, 1457 cm"1; MS (ESI) m/z calcd for C29H24O6 (M + H)+ 469.17, found 469.98.
 

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• Appel Reaction • Baeyer-Villiger Oxidation • Barbier Coupling Reaction • Baylis-Hillman Reaction • Bucherer-Bergs Reaction • Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions • Chugaev Reaction • Clemmensen Reduction • Corey-Bakshi-Shibata (CBS) Reduction • Corey-Chaykovsky Reaction • Corey-Kim Oxidation • Dess-Martin Oxidation • Fischer Indole Synthesis • Grignard Reaction • Henry Nitroaldol Reaction • Horner-Wadsworth-Emmons Reaction • Hydride Reductions • Jones Oxidation • Lawesson's Reagent • Leuckart-Wallach Reaction • Martin's Sulfurane Dehydrating Reagent • McMurry Coupling • Meerwein-Ponndorf-Verley Reduction • Mitsunobu Reaction • Moffatt Oxidation • Oxidation of Alcohols by DMSO • Passerini Reaction • Paternò-Büchi Reaction • Petasis Reaction • Peterson Olefination • Pictet-Spengler Tetrahydroisoquinoline Synthesis • Preparation of Alcohols • Preparation of Aldehydes and Ketones • Preparation of Amines • Prins Reaction • Reactions of Alcohols • Reactions of Aldehydes and Ketones • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reactions with Organometallic Reagents • Reformatsky Reaction • Ritter Reaction • Robinson Annulation • Schlosser Modification of the Wittig Reaction • Schmidt Reaction • Sharpless Olefin Synthesis • Specialized Acylation Reagents-Ketenes • Stobbe Condensation • Swern Oxidation • Tebbe Olefination • Ugi Reaction • Wittig Reaction • Wolff-Kishner Reduction

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