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Chemical Structure| 482-89-3 Chemical Structure| 482-89-3
Chemical Structure| 482-89-3

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Product Citations

Shriver, James A. ; Kaller, Kaylie S. ; Kinsey, Ally L. ; Wang, Katelyn R. ; Sterrenberg, Summer R. ; Van Vors, Madison K. , et al.

Abstract: The spontaneous conversion of 3-indoxyl to indigo was a well-established process used to produce indigo dyes. It was recently shown that some indoles, when reacted with molybdenum hexacarbonyl and cumyl peroxide, proceed through an indoxyl intermediate to produce significant amounts of indirubin through a competing mechanism. Modulation of this system to lower temperatures allows for careful tuning, leading to selective production of indirubins in a general process. A systematic assay of indoles show that electron deficient indoles work well when substituted at the 5 and 7 positions. In contrast, 6-substituted electron rich indoles give the best results whereas halogeno indoles work well in all cases. This process shows broad functional group tolerance for generally reactive carbonyl-containing compounds such as aldehydes and carboxylic acids.

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Product Details of Indigo

CAS No. :482-89-3
Formula : C16H10N2O2
M.W : 262.26
SMILES Code : O=C1C(NC2=CC=CC=C12)=C3C(C4=CC=CC=C4N3)=O
MDL No. :MFCD00005722
InChI Key :QQILFGKZUJYXGS-UHFFFAOYSA-N
Pubchem ID :10215

Safety of Indigo

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
 

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