[ CAS No. 4371-28-2 ] {[proInfo.proName]}

Name: 4371-28-2|[1,1'-Biphenyl]-3,3',5,5'-tetracarboxylic acid|95%
Brand: Ambeed
SKU: A153483
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2D 3D

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Quality Control of [ 4371-28-2 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 4371-28-2 ]

SDS Specification

Alternatived Products of [ 4371-28-2 ]

Product Details of [ 4371-28-2 ]

CAS No. :	4371-28-2	MDL No. :	MFCD16621475
Formula :	C₁₆H₁₀O₈	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	QURGMSIQFRADOZ-UHFFFAOYSA-N
M.W :	330.25	Pubchem ID :	15840397
Synonyms :

Calculated chemistry of [ 4371-28-2 ]

Physicochemical Properties

Num. heavy atoms :	24
Num. arom. heavy atoms :	12
Fraction Csp3 :	0.0
Num. rotatable bonds :	5
Num. H-bond acceptors :	8.0
Num. H-bond donors :	4.0
Molar Refractivity :	79.72
TPSA :	149.2 Å²

Pharmacokinetics

GI absorption :	Low
BBB permeant :	No
P-gp substrate :	No
CYP1A2 inhibitor :	No
CYP2C19 inhibitor :	No
CYP2C9 inhibitor :	No
CYP2D6 inhibitor :	No
CYP3A4 inhibitor :	No
Log Kp (skin permeation) :	-7.14 cm/s

Lipophilicity

Log Po/w (iLOGP) :	0.48
Log Po/w (XLOGP3) :	1.65
Log Po/w (WLOGP) :	2.15
Log Po/w (MLOGP) :	1.97
Log Po/w (SILICOS-IT) :	1.22
Consensus Log Po/w :	1.49

Druglikeness

Lipinski :	0.0
Ghose :	None
Veber :	1.0
Egan :	1.0
Muegge :	0.0
Bioavailability Score :	0.56

Water Solubility

Log S (ESOL) :	-2.97
Solubility :	0.356 mg/ml ; 0.00108 mol/l
Class :	Soluble
Log S (Ali) :	-4.4
Solubility :	0.0133 mg/ml ; 0.0000401 mol/l
Class :	Moderately soluble
Log S (SILICOS-IT) :	-2.38
Solubility :	1.37 mg/ml ; 0.00414 mol/l
Class :	Soluble

Medicinal Chemistry

PAINS :	0.0 alert
Brenk :	0.0 alert
Leadlikeness :	0.0
Synthetic accessibility :	2.11

Safety of [ 4371-28-2 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P305+P351+P338	UN#:	N/A
Hazard Statements:	H315-H319	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 4371-28-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 4371-28-2 ]
Downstream synthetic route of [ 4371-28-2 ]

[ 4371-28-2 ] Synthesis Path-Upstream 1~6

1
[ 109936-20-1 ]
[ 4371-28-2 ]

Yield	Reaction Conditions	Operation in experiment
89%	Stage #1: With sodium hydroxide; water In tetrahydrofuran for 5 h; Heating / reflux Stage #2: With sulfuric acid In water	A mixture of 3,3',5,5'-tetrakis(methoxycarbonyl)biphenyl (12) (0.96 g, 2.5 mmol), THF (40 mL) and NaOH (1.6 g, 40 mmol) dissolved in water (40 mL) was refluxed for 1 h. Then, the organic solvent was removed under reduced pressure, and the aqueous solution was refluxed again for 4 h. The reaction mixture was cooled and acidified with 50 percent H₂SO₄. The precipitate was filtrated and dried to obtained 9 as a white powder. Yield 89percent. M.p. > 350 °C. ¹H-NMR (400 MHz, DMSO-d₆): δ= 8.44 (d, 4H, J =1.5 Hz), 8.53 (t, 2H, J =1.5 Hz,), 13.48 (bs, 4 H). ¹³C-NMR (100 MHz, DMSO-d₆): δ= 129.5, 131.4, 132.3, 139.2, 166.3. MS-EI, m/z (percent): 330 (100) [M⁺], 313 (40), 285 (15) 240 (5).

Reference： [1] Journal of Organic Chemistry, 2006, vol. 71, # 20, p. 7854 - 7857
[2] European Journal of Organic Chemistry, 2007, # 20, p. 3271 - 3276
[3] Patent: EP1972338, 2008, A1, . Location in patent: Page/Page column 14
[4] Journal of the Chemical Society, 1923, vol. 123, p. 1045

2
[ 25570-02-9 ]
[ 4371-28-2 ]

Reference： [1] Angewandte Chemie - International Edition, 2016, vol. 55, # 47, p. 14628 - 14632[2] Angew. Chem., 2016, vol. 128, # 47, p. 14848 - 14852,5
[3] Chemistry - A European Journal, 2014, vol. 20, # 26, p. 8024 - 8029
[4] Journal of the American Chemical Society, 2009, vol. 131, # 6, p. 2159 - 2171
[5] Chemical Communications, 2011, vol. 47, # 43, p. 11852 - 11854
[6] Angewandte Chemie - International Edition, 2006, vol. 45, # 44, p. 7358 - 7364
[7] ChemMedChem, 2018, vol. 13, # 18, p. 1957 - 1971

3
[ 51839-15-7 ]
[ 4371-28-2 ]

Reference： [1] European Journal of Organic Chemistry, 2007, # 20, p. 3271 - 3276
[2] Journal of Organic Chemistry, 2006, vol. 71, # 20, p. 7854 - 7857
[3] Journal of Organic Chemistry, 2006, vol. 71, # 20, p. 7854 - 7857
[4] Journal of the Chemical Society, 1923, vol. 123, p. 1045
[5] Patent: EP1972338, 2008, A1,
[6] Patent: EP1972338, 2008, A1,

4
[ 99-27-4 ]
[ 4371-28-2 ]

Reference： [1] European Journal of Organic Chemistry, 2007, # 20, p. 3271 - 3276
[2] Journal of Organic Chemistry, 2006, vol. 71, # 20, p. 7854 - 7857
[3] Journal of Organic Chemistry, 2006, vol. 71, # 20, p. 7854 - 7857
[4] Patent: EP1972338, 2008, A1,
[5] Patent: EP1972338, 2008, A1,

5
[ 944392-68-1 ]
[ 4371-28-2 ]

Reference： [1] European Journal of Organic Chemistry, 2007, # 20, p. 3271 - 3276
[2] Journal of Organic Chemistry, 2006, vol. 71, # 20, p. 7854 - 7857
[3] Patent: EP1972338, 2008, A1,

6
[ 51839-16-8 ]
[ 4371-28-2 ]

Reference： [1] Journal of the Chemical Society, 1923, vol. 123, p. 1045

[ 4371-28-2 ] Synthesis Path-Downstream 1~88

1
[ 4371-28-2 ]
[ 113797-72-1 ]

Yield	Reaction Conditions	Operation in experiment
	With thionyl chloride; In tetrahydrofuran; for 3h;Heating / reflux;	A mixture of biphenyl-3,3',5,5'- tetracarboxylic acid (13) (0.30 g, 0.90 mmol) and thionyl chloride (0.53 mL, 7.20 mmol) in THF (20 mL) was heated under reflux for 3 h. The solvent was removed in vacuum. Then, THF (4 x 20 mL) was added and again the solvent was removed in vacuum. The crude product was used directly for further reaction.

Reference： [1]Journal of Organic Chemistry,2006,vol. 71,p. 7854 - 7857
[2]European Journal of Organic Chemistry,2007,p. 3271 - 3276
[3]Patent: EP1972338,2008,A1 .Location in patent: Page/Page column 14

2
[ 25570-02-9 ]
[ 4371-28-2 ]

Yield	Reaction Conditions	Operation in experiment
82%	With potassium permanganate; water; sodium hydroxide; In tert-butyl alcohol; at 50 - 70℃; for 216h;	The synthesis of H4bptc was carried out according to reported procedure with slight modifications3. 3,3?5,5?-tetramethylbiphenyl (5.0 g, 0.023 mol), NaOH (2.0 g, 0.05 mol) were mixed in t-BuOH/H20 (100/100 mL) with stirring at 50 C. KMn04 (43.0 g, 0.27 mol) was added in portions over one week. The temperature was subsequently increased to 70 C and kept for 2 days. The mixture was filter when hot and the clear filtrate was added into 100 mL 6M HC1. White solid was obtained upon filtration. The crude product was recrystallized from DMF (-100 mL) to give pure H bptc with a yield 82%.
82%	With potassium permanganate; sodium hydroxide; In water; tert-butyl alcohol; at 50 - 70℃; for 216h;	3,3?5,5?-tetramethylbiphenyl (5.0 g, 0.023 mol), and NaOH (2.0 g, 0.05 mol) were mixed in t-BuOH/H20 (100 mL/lOO mL) with stirring at 50 C. KMn04 (43.0 g, 0.27 mol) was added in portions over one week. The temperature was subsequently increased to 70 C and kept for 2 days. The mixture was filtered when hot and the clear filtrate was added into 100 mL of 6M HC1. White solid was obtained upon filtration. The crude product was recrystallized from DMF (-100 mL) to give pure H4bptc with a yield of 82%. 'H NMR (400 MHz, DMSO-d6): 5= 13.50 (4H, COOH), 8.51 (2H, Ar-H), 8.42 (4H, Ar-H).

Reference： [1]Patent: WO2019/157013,2019,A1 .Location in patent: Page/Page column 38
[2]Patent: WO2020/60873,2020,A2 .Location in patent: Page/Page column 19
[3]Angewandte Chemie - International Edition,2016,vol. 55,p. 14628 - 14632
Angew. Chem.,2016,vol. 128,p. 14848 - 14852,5
[4]Chemistry - A European Journal,2014,vol. 20,p. 8024 - 8029
[5]Journal of the American Chemical Society,2009,vol. 131,p. 2159 - 2171
[6]Journal of the American Chemical Society,2020,vol. 142,p. 6907 - 6912
[7]Chemical Communications,2011,vol. 47,p. 11852 - 11854
[8]Angewandte Chemie - International Edition,2006,vol. 45,p. 7358 - 7364
[9]ChemMedChem,2018,vol. 13,p. 1957 - 1971

3
[ 944392-68-1 ]
[ 4371-28-2 ]

Reference： [1]European Journal of Organic Chemistry,2007,p. 3271 - 3276
[2]Journal of Organic Chemistry,2006,vol. 71,p. 7854 - 7857
[3]Patent: EP1972338,2008,A1

4
[ 51839-15-7 ]
[ 4371-28-2 ]

Reference： [1]European Journal of Organic Chemistry,2007,p. 3271 - 3276
[2]Journal of Organic Chemistry,2006,vol. 71,p. 7854 - 7857
[3]Journal of Organic Chemistry,2006,vol. 71,p. 7854 - 7857
[4]Journal of the Chemical Society,1923,vol. 123,p. 1045
[5]Patent: EP1972338,2008,A1
[6]Patent: EP1972338,2008,A1

5
[ 99-27-4 ]
[ 4371-28-2 ]

Reference： [1]European Journal of Organic Chemistry,2007,p. 3271 - 3276
[2]Journal of Organic Chemistry,2006,vol. 71,p. 7854 - 7857
[3]Journal of Organic Chemistry,2006,vol. 71,p. 7854 - 7857
[4]Patent: EP1972338,2008,A1
[5]Patent: EP1972338,2008,A1

6
[ 4371-28-2 ]
N,N',N'',N'''-tetrakis[(2-hydroxy-5-methyl-phenyl)]biphenyl-3,3',5,5'-tetracarboxamide [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2007,p. 3271 - 3276
[2]Patent: EP1972338,2008,A1

7
[ 4371-28-2 ]
N,N',N'',N'''-tetrakis(4,6-dimethylpyridin-2-yl)biphenyl-3,3',5,5'-tetracarboxamide [ No CAS ]

Reference： [1]Journal of Organic Chemistry,2006,vol. 71,p. 7854 - 7857
[2]Patent: EP1972338,2008,A1

8
[ 51839-16-8 ]
[ 4371-28-2 ]

Reference： [1]Journal of the Chemical Society,1923,vol. 123,p. 1045

9
[ 113797-72-1 ]
[ 4371-28-2 ]
[ 88797-22-2 ]
3,5,3',5'-biphenyltetracarbonyl tetrakis(3,5-dibromosalicylate) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With thionyl chloride;N,N-dimethyl-formamide; In tetrahydrofuran; water; trifluoroacetic acid;	EXAMPLE 1 Synthesis of 3,5,3',5'-Biphenyltetracarbonyl Tetrakis (3,5-dibromosalicylate), BTDS 1.41 g (4.0 mmol) of t-butyl 3,5-dibromosalicylate and 0.45 g (4.0 mmol) of potassium t-butoxide was stirred in 30 mL of anhydrous THF for 20 m. A solution of 0.40 g(1.0 mmol) of 3,5,3',5'-biphenyltetracarbonyl tetrachloride (prepared, from 3,5,3',5'-biphenyltetra-carboxylic acid, a known compound in the literature, synthesised from the commercially available 5-bromo-m-xylene, the tetracarbonyl tetrachloride being prepared by reaction with thionyl chloride and a catalytic amount of DMF) in 15 mL of anhydrous THF was added and stirring was continued overnight. Water was added to the mixture and the product was extracted with ether. The solution was dried over MgSO4, filtered, and the solvent was evaporated. The white solid was dissolved in 20 mL of anhydrous trifluoroacetic acid, for deprotection, and was allowed to stand at room temperature for 1 h. Then 20 mL of ether was added to the solution producing a white precipitate which was filtered and dried in vacuum (1.1 g, 76%). IR (KBr) 3079 (br s, nuOH), 1736 (S, nuC=O) 1202 (s, nuC--O) cm-1; 1 H NMR (dioxane-d8) delta 9.01 (2 H, t, J=1.6 Hz, ArH), 8.80 (4 H, d, J=1.6 Hz, ArH), 8.21 (8 H, dd, J=4.0 Hz, ArH), 2.57 (4 H, br s, CO2 H); 1 H nmr (DIOXANE-D8) delta 9.01 (2H, t,J=1.6 Hz), 8.80 (4H,d,J=1.6 Hz), 8.21(8H,dd,J=4.0 Hz), 2.57 (4H,brs); 13 C NMR (dioxane-d8) delta 163.56, 162.96, 148.26, 141.65, 140.29, 134.85, 134.72, 131.85, 131.48, 127.55, 120.01; MS (negative FAB): 1441 (M-1) UV (dioxane) lambdamax,1 =230 nm, epsilonmax,1 =133,000, lambdamax,2 =296 nm, epsilonmax,2 =14,000.

Reference： [1]Patent: US5811521,1998,A

10
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 68-12-2 ]
Co₂(3,3',5,5'-biphenyltetracarboxylate)(H₂O)(DMF)2*DMF*1.5(H₂O) [ No CAS ]

Reference： [1]Inorganic Chemistry,2005,vol. 44,p. 181 - 183

11
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 64-17-5 ]
[ 4371-28-2 ]
[ 68-12-2 ]
Co₂(3,3',5,5'-biphenyltetracarboxylate)(H₂O)(DMF)2*DMF*1.5(H₂O) [ No CAS ]
Co₂(3,3',5,5'-biphenyltetracarboxylate)(H₂O)5*3(DMF)*EtOH*4(H₂O) [ No CAS ]

Reference： [1]Inorganic Chemistry,2005,vol. 44,p. 181 - 183

12
copper nitrate hemi(pentahydrate) [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[ 68-12-2 ]
[Cu₂(bptc)(H₂O)2(dmf)3(H₂O)] [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2005,vol. 44,p. 4745 - 4749
[2]Journal of the American Chemical Society,2012,vol. 134,p. 17286 - 17290

13
copper nitrate hemi(pentahydrate) [ No CAS ]
[ 4371-28-2 ]
Cu₂(biphenyl-3,3',5,5'-tetracarboxylate)(H₂O)2 [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2006,vol. 45,p. 7358 - 7364

14
[ 4371-28-2 ]
indiun(III) nitrate [ No CAS ]
[ 68-12-2 ]
[ 75-05-8 ]
(CH₃)2NH₂⁽¹⁺⁾*In⁽³⁺⁾*(C₆H₃(C(O)O)2)2^(4-)*99CH₃CN=((CH₃)2NH₂)[In(C₆H₃(C(O)O)2)2]*99CH₃CN [ No CAS ]

Reference： [1]Chemical Communications,2008,p. 6108 - 6110

15
copper nitrate hemi(pentahydrate) [ No CAS ]
[ 4371-28-2 ]
[ 68-12-2 ]
2Cu⁽²⁺⁾*((OOC)2C₆H₃)2^(4-)*2.5HCON(CH₃)2*6H₂O=(Cu₂(C₁₆H₆O₈)(H₂O)2)*2.5HCON(CH₃)2*4H₂O [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2009,vol. 131,p. 2159 - 2171

16
[ 617-84-5 ]
{1,2-bis(1,4,6,8,11-pentaazacyclotetradecan-6-yl)ethane-dinickel(II,II)} perchlorate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[(nickel(II))2(CH₂)2(C₉N₅H₂₂)2(1,1'-biphenyl-3,3',5,5'-tetracarboxylate)]*6H₂O*3(N,N-diethylformamide) [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2009,vol. 48,p. 6865 - 6869

17
scandium trifluoromethanesulphonate hydrate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
([Sc₂(biphenyl-3,3',5,5'-tetracarboxylate)(OH)2]*1.25H₂O)n [ No CAS ]

Reference： [1]Chemical Communications,2011,vol. 47,p. 8304 - 8306

18
zinc(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[Zn₂(biphenyl-3,3',5,5'-tetracarboxylate)2(H₃NEt₃)4(H₂O)7] [ No CAS ]

Reference： [1]Chemical Communications,2011,vol. 47,p. 11852 - 11854
[2]Chemical Communications,2011,vol. 47,p. 11852 - 11854

19
magnesium(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[Mg2(μ2-H2O)2(biphenyl-3,3',5,5'-tetracarboxylate)] [ No CAS ]

Reference： [1]Chemical Communications,2011,vol. 47,p. 11852 - 11854

20
[ 4371-28-2 ]
Co₂(3,3',5,5'-biphenyltetracarboxylate)(H₂O)(DMF)2*DMF*1.5(H₂O) [ No CAS ]

Reference： [1]Inorganic Chemistry,2005,vol. 44,p. 181 - 183

21
[ 4371-28-2 ]
Co₂(3,3',5,5'-biphenyltetracarboxylate)(H₂O)5*(DMF)(acetonitrile)2(H₂O)5 [ No CAS ]

Reference： [1]Inorganic Chemistry,2005,vol. 44,p. 181 - 183

22
indium(III) nitrate pentahydrate [ No CAS ]
[ 4371-28-2 ]
[In₂(OH)2(biphenyl-3,3',5,5'-tetracarboxylate)]*6H₂O [ No CAS ]

Reference： [1]Chemical Communications,2012,vol. 48,p. 9696 - 9698

23
aluminum(III) nitrate nonahydrate [ No CAS ]
[ 4371-28-2 ]
MFM-300(Al) [ No CAS ]

Reference： [1]Nature Chemistry,2012,vol. 4,p. 887 - 894

24
calcium(II) nitrate tetrahydrate [ No CAS ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 127-19-5 ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[CdCa(biphenyl-3,3',5,5'-tetracarboxylicacid)(N,N'-dimethylacetamide)₂(H₂O)]_*(N,N'-dimethylacetamide) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
45%	at 100℃; for 72h;	A mixture of Cd(NO3)24H2O (0.060 g, 0.2 mmol), Ca(NO3)24H2O (0.048 g, 0.2 mmol), H4BPTC (0.032 g, 0.10 mmol), DMA(2 mL) and H2O (2 mL) was placed in a small vial. The resulting mixturewas kept at 100 C for 3 days. After being slowly cooled to theroom temperature, colorless block crystals of 1 were isolated. Yield:45% based on H4BPTC. Anal. calc. for C28H35N3O12CdCa (758.08): C,44.32; H, 4.62; N, 5.54%. Found: C, 44.33; H, 4.59; N, 5.56%.

Reference： [1]Journal of Molecular Structure,2014,vol. 1067,p. 239 - 242

25
[ 290-37-9 ]
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
Co(pyrazine)(3,3',5,5'-biphenyltetracarboxylate)<SUB>0.5</SUB> [ No CAS ]

Reference： [1]Chemical Communications,2014,vol. 50,p. 4911 - 4914

26
[ 553-26-4 ]
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
Co(4,4'-bipyridine)(3,3',5,5'-biphenyltetracarboxylate)<SUB>0.5</SUB> [ No CAS ]

Reference： [1]Chemical Communications,2014,vol. 50,p. 4911 - 4914

27
[ 100146-16-5 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 4371-28-2 ]
3C₁₈H₁₄N₄*C₁₆H₇O₈^(3-)*2Cd⁽²⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
32%	With sodium hydroxide; In water; at 180℃; for 72h;Sealed tube;	General procedure: A mixture of H2L (28.6mg, 0.1mmol), Cd(NO3)2·4H2O (30.8mg, 0.1mmol), H2BPDA (24.2mg, 0.1mmol) and NaOH (8.0mg, 0.2mmol) in 10mL of H2O was sealed in a 16mL Teflon lined stainless steel container and heated at 180C for 3d. After the reaction mixture was cooled to room temperature, block crystals of 1 were collected with a yield of 32% by filtration and washed with water several times.

Reference： [1]Polyhedron,2014,vol. 79,p. 239 - 249

28
[ 100146-16-5 ]
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
C₁₆H₆O₈^(4-)*2C₁₈H₁₄N₄*4H₂O*2Co⁽²⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
36%	With sodium hydroxide; at 180℃; for 72h;Sealed tube;	A mixture of H2L (28.6mg, 0.1mmol), Co(NO3)2·6H2O (29.1mg, 0.1mmol), H4BPTC (16.5mg, 0.05mmol) and NaOH (8.0mg, 0.2mmol) in 10mL of H2O was sealed in a 16mL Teflon lined stainless steel container and heated at 180C for 3d. After the reaction mixture was cooled to room temperature, block crystals of 5 were collected with a yield of 36%. Anal. Calc. for C26H21N4O6Co: C, 57.36; H, 3.89; N, 10.29. Found: C, 57.52; H, 3.92; N, 10.43%. IR (KBr pellet, cm-1, Fig. S8): 3479 (m), 3225-2856 (m), 1605 (s), 1579 (s), 1491 (w), 1423 (s), 1379 (s), 1358 (s), 1116 (s), 1072 (s), 818 (w), 787 (w), 737 (w), 647 (w), 648 (w), 557 (w), 514 (w).

Reference： [1]Polyhedron,2014,vol. 79,p. 239 - 249

29
[ 29604-34-0 ]
[ 52550-63-7 ]
[ 4371-28-2 ]
{Zn(biphenyl-3,3',5,5'-tetracarboxylic acid)0.5(1,4-bis(2-methylimidazol-1-yl)butane)}n [ No CAS ]

Reference： [1]Chemical Papers,2014,vol. 68,p. 1415 - 1420

30
manganese(II) chloride tetrahydrate [ No CAS ]
[ 4371-28-2 ]
[ 171565-44-9 ]
{Mn₂(biphenyl-3,3',5,5'-tetracarboxylic acid)(2-phenyl-1H-imidazo[4,5-f ][1,10]phenanthroline)(H₂O)}n [ No CAS ]

Reference： [1]Chemical Papers,2014,vol. 68,p. 1415 - 1420

31
bismuth (III) nitrate pentahydrate [ No CAS ]
[ 4371-28-2 ]
[Bi₂(L)_1.5(H₂O)₂]·(DMF)_3.5·(H₂O)₃ [ No CAS ]

Reference： [1]Chemistry - A European Journal,2014,vol. 20,p. 8024 - 8029

32
[ 553-26-4 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[Zn₂(biphenyl-3,3',5,5'-tetracarboxylic acid)(4,4'-bipyridine) (H₂O)₂]*2H₂O [ No CAS ]

Reference： [1]RSC Advances,2014,vol. 4,p. 32391 - 32397

33
zinc(II) nitrate hexahydrate [ No CAS ]
[ 357429-12-0 ]
[ 4371-28-2 ]
[Zn₂(biphenyl-3,3',5,5'-tetracarboxylic acid)(N,N'-bis-(4-pyridylmethyl)piperazine)₂]*2H₂O [ No CAS ]

Reference： [1]RSC Advances,2014,vol. 4,p. 32391 - 32397

34
[ 4916-57-8 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[Zn(biphenyl-3,3',5,5'-tetracarboxylic acid)(1,2-bis(4-pyridyl)ethane)]*2H₂O [ No CAS ]

Reference： [1]RSC Advances,2014,vol. 4,p. 32391 - 32397

35
zinc(II) nitrate hexahydrate [ No CAS ]
[ 69506-86-1 ]
[ 4371-28-2 ]
[Zn₂(biphenyl-3,3',5,5'-tetracarboxylic acid)(1,1'-(1,4-butanediyl)bis(imidazole))₂]*H₂O [ No CAS ]

Reference： [1]RSC Advances,2014,vol. 4,p. 32391 - 32397

36
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[ 25372-07-0 ]
2C₁₂H₁₀N₄*C₁₆H₆O₈^(4-)*2Co⁽²⁺⁾*4H₂O [ No CAS ]

Reference： [1]CrystEngComm,2014,vol. 16,p. 7990 - 7999

37
samarium(III) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[ 144-62-7 ]
[ 68-12-2 ]
2C₂H₇N*2Sm⁽³⁺⁾*C₁₆H₆O₈^(4-)*C₂H₂O₄*C₂O₄^(2-) [ No CAS ]

Reference： [1]CrystEngComm,2014,vol. 16,p. 9191 - 9197

38
[ 4371-28-2 ]
[ 7732-18-5 ]
[ 15280-57-6 ]
[ 144-62-7 ]
[ 68-12-2 ]
2C₂H₇N*2Er⁽³⁺⁾*C₁₆H₆O₈^(4-)*C₂H₂O₄*C₂O₄^(2-) [ No CAS ]

Reference： [1]CrystEngComm,2014,vol. 16,p. 9191 - 9197

39
ytterbium(III) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[ 144-62-7 ]
[ 68-12-2 ]
2C₂H₇N*2Yb⁽³⁺⁾*C₁₆H₆O₈^(4-)*C₂H₂O₄*C₂O₄^(2-) [ No CAS ]

Reference： [1]CrystEngComm,2014,vol. 16,p. 9191 - 9197

40
[ 120-93-4 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
2C₁₆H₇O₈^(3-)*3Zn⁽²⁺⁾*4C₃H₆N₂O [ No CAS ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2015,vol. 641,p. 596 - 600

41
copper nitrate hemi(pentahydrate) [ No CAS ]
[ 4371-28-2 ]
[Cu₂(3,3′,5,5′-biphenyltetracarboxylate)] [ No CAS ]

Reference： [1]Chemistry - A European Journal,2015,vol. 21,p. 2508 - 2518

42
[ 1455-77-2 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 68-12-2 ]
[(CH₃)₂NH₂]_2n[Zn₃(bptc)₂(datrz)₂]_n*n(H₂O) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
38%	In methanol; at 90℃; for 72h;	General procedure: A mixture of Zn(NO3)26H2O (0.030 g, 0.1 mmol), H3bpt (0.025 g,0.1 mmol), Hdatrz (0.01 g, 0.1 mmol), DMF (3 mL) and CH3OH(1 mL) was placed in a small vial at 90 C for 72 h and then cooledto room temperature slowly. Colorless block crystals were obtainedin 42% yield based on Zn(NO3)26H2O. Anal. calcd. forC36H29N11O12Zn3 (1004.88): C, 42.99; H, 2.89; N, 15.33%. Found: C,42.89; H, 2.85; N, 15.42%. IR (cm1): 3422(w), 1712(m), 1675(s),1587(m), 1509(m), 1389(m), 1378(m), 1109(w), 1025(w), 958(m),893(m), 826(m), 778(w), 690(w), 674(w), 589(w), 562(w).

Reference： [1]Journal of Molecular Structure,2016,vol. 1105,p. 112 - 117

43
zinc(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 68-12-2 ]
2Zn⁽²⁺⁾*C₁₆H₆O₈^(4-)*2C₃H₇NO*H₂O [ No CAS ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2015,vol. 641,p. 2380 - 2383

44
zinc(II) nitrate hexahydrate [ No CAS ]
[ 127-19-5 ]
[ 4371-28-2 ]
Zn⁽²⁺⁾*0.5C₁₆H₆O₈^(4-)*C₄H₉NO [ No CAS ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2015,vol. 641,p. 2380 - 2383

45
[ 280-57-9 ]
[ 617-84-5 ]
[ 4371-28-2 ]
indiun(III) nitrate [ No CAS ]
In⁽³⁺⁾*C₁₆H₆O₈^(4-)*3H₂O*C₆H₁₂N₂*0.33C₅H₁₁NO*H⁽¹⁺⁾ [ No CAS ]

Reference： [1]CrystEngComm,2015,vol. 17,p. 8512 - 8518

46
indium(III) chloride [ No CAS ]
[ 64-17-5 ]
[ 127-19-5 ]
[ 4371-28-2 ]
C₂H₇N*In⁽³⁺⁾*C₁₆H₆O₈^(4-)*1.33C₂H₆O*3H₂O*0.67C₄H₉NO*H⁽¹⁺⁾ [ No CAS ]

Reference： [1]CrystEngComm,2015,vol. 17,p. 8512 - 8518

47
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 127-19-5 ]
[ 4371-28-2 ]
2C₁₆H₆O₈^(4-)*4Cd⁽²⁺⁾*4C₄H₉NO*2H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In ethanol; at 120℃; for 50h;Sealed tube; High pressure;	A mixture of Cd(NO3)2·4H2O (30.8mg, 0.1mmol), H4bta (33.0mg, 0.1mmol) and 5mL DMA-EtOH (v:v=1:1) was sealed in a 25mL Teflon-lined reaction vessel, then heated to 120C in 10h and kept at 120C for 50h, then slowly cooled to 30C in 13h. Colorless block crystals of 1 was isolated by filtration, washed with H2O, and dried in air. Elemental analysis calcd (%) for 1 (C52H61Cd4N5O23): C 39.68, H 3.90, N 4.45; found: C 39.98, H 4.65, N 4.42. Selected IR peaks (cm-1): 1578(s), 1403(s), 1343(s), 1017(w), 782(s), 653(s), 584(w).

Reference： [1]Journal of Molecular Structure,2016,vol. 1107,p. 1 - 6

48
europium(III) nitrate hexahydrate [ No CAS ]
[ 127-19-5 ]
[ 4371-28-2 ]
2C₁₆H₇O₈^(3-)*3Eu⁽³⁺⁾*3H₂O*C₁₆H₆O₈^(4-)*H⁽¹⁺⁾*4C₄H₉NO [ No CAS ]

Reference： [1]Journal of Materials Chemistry A,2015,vol. 3,p. 24016 - 24021

49
[ 553-26-4 ]
copper(II) choride dihydrate [ No CAS ]
[ 4371-28-2 ]
[Cu₂(cis-H₂bpta)₂(4,4'-bipy)₂]_n*nH₄bpta*2nH₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
Ca. 47%	With sodium hydroxide; at 129.84℃; for 72h;pH 6.5;Autoclave;	A mixture of H4bpta (33.3 mg, 0.1 mmol), 4,40-bipy (31.2 mg,0.2 mmol), CuCl22H2O (34.2 mg, 0.2 mmol) and 8 mL of H2O wasadjusted to approximately pH 6.5 with dilute NaOH solution, andthen transferred to 13 mL Teflon-lined stainless steel and heatedunder autogenous pressure at 403 K for 72 h and then cooled toroom temperature naturally. Blue block-shaped crystals werecollected by filtration, washed with H2O, and dried in air (yield~47%, based on H4bpta). Analysis calculated for C40H32Cd2N8O11 (I):C 55.86, H 3.17, N 3.83%; found: C 56.23, H 3.41, N 3.15%. IR (KBr, n,cm1): 3436m, 1629s, 1608s, 1543s, 1488w, 1419s, 1307s, 1369s,1217w, 1085w, 897w, 814m, 781m, 722m, 711m, 656m, 631m,461w (see Fig. S1, ESIy).

Reference： [1]Journal of Molecular Structure,2016,vol. 1108,p. 451 - 457

50
gallium(III) nitrate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[ 68-12-2 ]
C₁₆H₆O₈^(4-)*1.6C₃H₇NO*4H₂O*2HO^(1-)*2Ga⁽³⁺⁾ [ No CAS ]

Reference： [1]Inorganic Chemistry,2016,vol. 55,p. 1076 - 1088

51
Iron(III) nitrate nonahydrate [ No CAS ]
gallium(III) nitrate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
C₁₆H₆O₈^(4-)*2HO^(1-)*1.87Ga⁽³⁺⁾*0.13Fe⁽³⁺⁾*1.5H₂O [ No CAS ]

Reference： [1]Inorganic Chemistry,2016,vol. 55,p. 1076 - 1088

52
Iron(III) nitrate nonahydrate [ No CAS ]
[ 4371-28-2 ]
C₁₆H₇O₈^(3-)*0.5C₁₆H₆O₈^(4-)*3.5H₂O*HO^(1-)*3Fe⁽³⁺⁾*1.5O^(2-) [ No CAS ]

Reference： [1]Inorganic Chemistry,2016,vol. 55,p. 1076 - 1088

53
3C₄H₆N₂*C₈H₄O₄^(2-)*Cu⁽²⁺⁾ [ No CAS ]
[ 4371-28-2 ]
C₁₆H₆O₈^(4-)*2Cu⁽²⁺⁾ [ No CAS ]

Reference： [1]Chemistry - A European Journal,2015,vol. 21,p. 13894 - 13899

54
1,3,5-tris(1-imidazolyl)benzene [ No CAS ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 563-83-7 ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[Zn₆(1,3,5-tris(1-imidazolyl)benzene)₄(3,3',5,5'-biphenyltetracarboxylate)₃](DMA)₄(H₂O)₁₀} [ No CAS ]

Reference： [1]Chinese Journal of Chemistry,2014,vol. 32,p. 1029 - 1032

55
terbium(III) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 68-12-2 ]
[(CH₃)₂NH₂][Tb(bptc)] [ No CAS ]

Reference： [1]Dalton Transactions,2019,vol. 48,p. 3723 - 3729
[2]Dalton Transactions,2016,vol. 45,p. 1040 - 1046

56
copper(II) nitrate trihydrate [ No CAS ]
[ 4371-28-2 ]
[Cu₂(3,3′,5,5′-biphenyltetracarboxylate)] [ No CAS ]

Reference： [1]Dalton Transactions,2016,vol. 45,p. 8753 - 8759

57
[ 4371-28-2 ]
[ 7697-37-2 ]
indiun(III) nitrate [ No CAS ]
[In₂(OH)₂(biphenyl-3,3′,5,5′-tetracarboxylate)] [ No CAS ]

Reference： [1]Chemical Communications,2016,vol. 52,p. 10273 - 10276

58
copper (II) nitrate tetrahydrate [ No CAS ]
[ 4371-28-2 ]
C₁₆H₆O₈^(4-)*2Cu⁽²⁺⁾ [ No CAS ]

Reference： [1]Inorganic Chemistry,2016,vol. 55,p. 12110 - 12113

59
zinc(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 68-12-2 ]
{Zn₄(H₂BPTC)₂(HCOO)₄}_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	In water; at 90℃; for 120h;Autoclave; High pressure;	Solvothermal reactions of Zn(NO3)2·6H2O (0.015g, 0.05mmol) with H4BPTC (0.016g, 0.05mmol) in the mixture of DMF/DMP/H2O (v/v/v=1:1:1) in a sealed Teflon-lined autoclave (25mL) and heated at 90C for 5 d under autogenous pressure. Light yellow square plate crystals were obtained and then filtered, washed with water and DMF, and dried in air. Yield: 0.16g, 58%. Anal. Calcd. for Zn4(C16H8O8)2(HCOO)4: C, 39.61; H, 1.82. Found: C, 39.58; H, 1.85.

Reference： [1]Journal of Solid State Chemistry,2017,vol. 247,p. 39 - 42

60
[ 4371-28-2 ]
indiun(III) nitrate [ No CAS ]
[In₂(OH)₂(biphenyl-3,3′,5,5′-tetracarboxylate)] [ No CAS ]

Reference： [1]Advanced Materials,2016,vol. 28,p. 8705 - 8711

61
[ 4371-28-2 ]
biphenyl-3,3’,5,5’-tetracarboxylic acid-d₄ [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2016,vol. 55,p. 14628 - 14632
Angew. Chem.,2016,vol. 128,p. 14848 - 14852,5

62
[ 2632-99-7 ]
[ 4371-28-2 ]
[(biphenyl-3,3’,5,5’-tetracarboxylic acid)·(4,4'-azopyridine)₂] [ No CAS ]

Reference： [1]Angewandte Chemie - International Edition,2016,vol. 55,p. 14628 - 14632
Angew. Chem.,2016,vol. 128,p. 14848 - 14852,5

63
iron(III) chloride [ No CAS ]
[ 127-19-5 ]
[ 4371-28-2 ]
[Fe₂(BPDC)(DMAC)₃]_n [ No CAS ]

Reference： [1]Chemical Communications,2017,vol. 53,p. 2394 - 2397

64
[ 127-19-5 ]
iron(III) chloride hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 1310-73-2 ]
[H₂N(CH₃)₂][Fe₂Na₃(BPDC)₂(DMAC)₂(H₂O)]*DMAC}_n [ No CAS ]

Reference： [1]Chemical Communications,2017,vol. 53,p. 2394 - 2397

65
zinc(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 68-12-2 ]
3C₁₆H₆O₈^(4-)*2C₂H₇N*5Zn⁽²⁺⁾*5.5C₃H₇NO*3.5H₂O*2H⁽¹⁺⁾ [ No CAS ]

Reference： [1]Inorganic Chemistry,2017,vol. 56,p. 4263 - 4266

66
[ 1455-77-2 ]
[ 4371-28-2 ]
[ 5970-45-6 ]
[ 68-12-2 ]
C₂H₇N*2Zn⁽²⁺⁾*C₁₆H₆O₈^(4-)*C₂H₄N₅^(1-)*2H₂O*H⁽¹⁺⁾ [ No CAS ]

Reference： [1]Inorganic Chemistry,2017,vol. 56,p. 5069 - 5075

67
iron(II) chloride tetrahydrate [ No CAS ]
[ 127-19-5 ]
[ 4371-28-2 ]
[ 67-68-5 ]
[(CH₃)2NH₂][Fe^II₃(OH)(3,3’,5,5’-biphenyltetracarboxylic acid)_1.5(DMSO)₃] [ No CAS ]

Reference： [1]Chemistry - A European Journal,2017,vol. 23,p. 6693 - 6700

68
[ 4371-28-2 ]
indiun(III) nitrate [ No CAS ]
[ 68-12-2 ]
In₂(OH)₂(biphenyl-3,3′,5,5′-tetracarboxylate)*N,N-dimethylformamide [ No CAS ]

Reference： [1]Inorganic Chemistry,2017,vol. 56,p. 5863 - 5872

69
[ 4371-28-2 ]
[ 25372-07-0 ]
cobalt(II) nitrate [ No CAS ]
C₁₆H₆O₈^(4-)*2C₁₂H₁₀N₄*2Co⁽²⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
57.4%	In water; N,N-dimethyl-formamide; at 160℃; for 72h;Autoclave; High pressure;	A mixture of 0.5 mmol of 3,5,3',5'-biphenyltetracarboxylic acid, 1 mmol of 1,4-bisimidazole benzene and 1 mmol of cobalt nitrate was dissolved in 10 mL of distilled water and 5 mL of DMF and stirred at room temperature for 20 min and transferred to a polytetrafluoroethylene autoclave high pressure reaction and allowed to stand in an oven at 160 C for 72 hours and then reduced to 4 C / hour to room temperature to obtain the three-dimensional coordination polymer with a double-core structure C40H34Co2N8O3 in a yield of 57.4% (based on Co).

Reference： [1]Patent: CN104130292,2017,B .Location in patent: Paragraph 0019; 0020; 0026; 0027

70
[ 4371-28-2 ]
[ 25372-07-0 ]
[ 7646-79-9 ]
C₁₆H₆O₈^(4-)*2C₁₂H₁₀N₄*2Co⁽²⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
38.5%	In water; N,N-dimethyl-formamide; at 140℃; for 70h;Autoclave; High pressure;	A mixture of 0.5 mmol of 3,5,3',5'-biphenyltetracarboxylic acid, 1 mmol of 1,4-bisimidazole benzene and 0.9 mmol of cobalt chloride was dissolved in 12 mL of distilled water and 5 mL of DMF and stirred at room temperature for 20 min and transferred to a polytetrafluoroethylene autoclave high pressure reaction and allowed to stand in an oven at 140 C for 70 hours and then reduced to 5 C / hour to room temperature to obtain the three-dimensional coordination polymer with a double-core structure C40H34Co2N8O3 in a yield of 38.5% (based on Co).

Reference： [1]Patent: CN104130292,2017,B .Location in patent: Paragraph 0028; 0029; 0030; 0031

71
[ 553-26-4 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 4371-28-2 ]
[Cd₂(bptc)(4,4′-bipyridine)(H₂O)₂]*4H₂O [ No CAS ]

Reference： [1]Inorganic Chemistry,2017,vol. 56,p. 11768 - 11778

72
[ 366-18-7 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 4371-28-2 ]
[Cd₂(bptc)(2,2′-bipyridine)₂(H₂O)₂] [ No CAS ]

Reference： [1]Inorganic Chemistry,2017,vol. 56,p. 11768 - 11778

73
[ 66-71-7 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 4371-28-2 ]
[Cd₂(bptc)(1,10-phenanthroline)₂]*4H₂O [ No CAS ]

Reference： [1]Inorganic Chemistry,2017,vol. 56,p. 11768 - 11778

74
zinc(II) sulfate heptahydrate [ No CAS ]
[ 4371-28-2 ]
[ 68-12-2 ]
1,3-bis(diimidazol-2-ylhydroxymethyl)benzene [ No CAS ]
Zn(1,3-bis(diimidazol-2-ylhydroxymethyl)benzene)_0.5(BPTC)_0.5*3(dimethylformamide) [ No CAS ]

Reference： [1]Chemical Communications,2017,vol. 53,p. 11302 - 11305

75
[ 4371-28-2 ]
[ 7732-18-5 ]
scandium tris(trifluoromethanesulfonate) [ No CAS ]
C₁₆H₆O₈^(4-)*2Sc⁽³⁺⁾*2HO^(1-) [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2017,vol. 139,p. 16289 - 16296

76
aluminum(III) nitrate nonahydrate [ No CAS ]
[ 4371-28-2 ]
[Al₂(OH)₂(biphenyl-3,3',5,5'-tetracarboxylate)] [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2017,vol. 139,p. 16289 - 16296

77
indium(III) nitrate trihydrate [ No CAS ]
[ 4371-28-2 ]
[In₂(OH)₂(biphenyl-3,3′,5,5′-tetracarboxylate)] [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2017,vol. 139,p. 16289 - 16296

78
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
2C₁₆H₆O₈^(4-)*4Co⁽²⁺⁾*19H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
36%	With tetrafluoroboric acid; In N,N-dimethyl-formamide; at 85℃; for 72h;pH 4;Autoclave; High pressure;	A mixture of Co(NO3)2·6H2O (29.1mg, 0.1mmol) and H4bptc (33.0mg, 0.1mmol) was dissolved in distilled water and N, N-Dimethylformamide (DMF), adjusting the pH value to 4 with HBF4. The final mixture was sealed in a 15ml Parr Teflon-lined stainless-steel vessel and heated at 85C for 3days, and then the reaction system was cooled to room temperature. Red block crystals of 1 were obtained, washed with water, and dried under ambient conditions. (Yields: 36% for 1 based on H4bptc). Elemental analysis (%) calcd for (C32H50Co4O35): C, 31.24; H, 4.10. Found: C, 31.11; H, 4.06.

Reference： [1]Inorganic Chemistry Communications,2017,vol. 85,p. 89 - 91

79
nickel(II) nitrate hexahydrate [ No CAS ]
[ 794485-43-1 ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[Ni(1,3-di(1H-imidazol-4-yl)benzene)(biphenyl-3,3′,5,5′-tetracarboxylate)0.5(H2O)2] [ No CAS ]

Reference： [1]Crystal Growth and Design,2018,vol. 18,p. 1136 - 1146

80
nickel(II) nitrate hexahydrate [ No CAS ]
4,4′-di(1H-imidazol-4-yl)biphenyl [ No CAS ]
[ 4371-28-2 ]
[ 7732-18-5 ]
[Ni2(4,4′-di(1H-imidazol-4-yl)biphenyl)3(biphenyl-3,3′,5,5′-tetracarboxylate)(H2O)2]·6H2O [ No CAS ]

Reference： [1]Crystal Growth and Design,2018,vol. 18,p. 1136 - 1146

81
terbium(III) nitrate hexahydrate [ No CAS ]
samarium(III) nitrate hexahydrate [ No CAS ]
gadolinium(III) nitrate hexahydrate [ No CAS ]
[ 4371-28-2 ]
3C₁₆H₇O₈^(3-)*0.018Sm⁽³⁺⁾*9H₂O*3C₃H₇NO*2.976Gd⁽³⁺⁾*0.006Tb⁽³⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With nitric acid; In water; at 110℃; for 24h;Autoclave; High pressure;	General procedure: The preparation of solid-state samples of LnL (Ln=Eu, Tb, Sm and Dy) were carried out according the literature [27]. Taking EuL as an example, Eu(NO3)3·6H2O (0.4 mmol in 5mL H2O) and H4BPTC (0.0660g, 0.2mmol) were dispersed in DMF (8 mL) and 6M HNO3 (2.5mL, pH=2.0) in a 23 mL Teflon-lined autoclave and then heated under autogenous pressure at 110C for one day, then cooled to room temperature under ambient conditions. Colorless sheet crystals was recovered by filtration, washed with distilled water, and dried in air. Other crystals were synthesized similar to EuL using compounds Ln(NO3)3·6H2O. GdL was obtained by employing the same synthetic method, but the poor crystallization make it not suitable for X-ray Crystallographic Determination. We combined XRD, TGA, elemental analyses and electron count to confirm that Gd compound is isomorphous to LnL (Ln=Eu, Tb, Sm and Dy). Yield: 82% (based on H4BPTC ligand). Element analysis (%) calcd for: C 37.31, H 3.30, N 2.29; found: C 37.25, H 3.25, N 2.28. Selected IR data (KBr pellet cm-1): 3423 (s), 1645 (s), 1542 (s), 1354 (m), 1078 (m), 775 (w), 618 (w).