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Chemical Structure| 36400-98-3 Chemical Structure| 36400-98-3

Structure of 36400-98-3

Chemical Structure| 36400-98-3

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Product Details of [ 36400-98-3 ]

CAS No. :36400-98-3
Formula : C18H38O
M.W : 270.49
SMILES Code : CC(C)(C)CC(C)CCC(C(C)CC(C)(C)C)CO
MDL No. :N/A

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Application In Synthesis of [ 36400-98-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 36400-98-3 ]

[ 36400-98-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 3452-97-9 ]
  • [ 36400-98-3 ]
YieldReaction ConditionsOperation in experiment
100% With 3,5,5-trimethyl hexanal; hydrogen; zinc(II) oxide; at 230℃; for 5h;Catalytic behavior; A 100 mL flask equipped with a condenser packed at the bottom with MS4A was charged with 25.7 g of TMHOL as the starting material, 1.00 g (10 mol percent with respect to the starting material) of potassium hydroxide (KOH) (granular; guaranteed reagent from Wako Pure Chemical Industries, Ltd.; purity, ?85percent) as the base, and 2.5 g (9.9 mol percent with respect to the starting material) of TMHAL as the catalyst. Next, the mixture was reacted for 5 hours in an oil bath set to 230° C. while blowing (bubbling) 0.1 L/min of hydrogen gas (compressed hydrogen gas, from Toho Sakata Suiso KK) into the mixture under stirring. The mixture was then cooled to room temperature (about 23° C.), and the blowing of hydrogen gas was stopped. The product peak retention time was confirmed by GC to agree with the retention time for the reference material. The peak portion was then analyzed by GC-MS, and the molecular weight and degradation product pattern were confirmed to agree with those for the reference material. The reaction product obtained was the target substance 2-(4,4-dimethylpentan-2-yl)-5,7,7-trimethyl-1-octanol, and the yield was 90.5percent. As used herein, the ?yield? means the ratio of the amount of target product actually obtained to the amount of target product that can be obtained from the entire charged amount of the starting material, and is a value determined by the following formula. Yield (percent)=amount of target product (mol)/amount of starting material charged (mol)×2×100
 

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