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Chemical Structure| 32864-11-2 Chemical Structure| 32864-11-2

Structure of 32864-11-2

Chemical Structure| 32864-11-2

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Product Details of [ 32864-11-2 ]

CAS No. :32864-11-2
Formula : C7H5ClO3
M.W : 172.57
SMILES Code : O=CC1=CC=C(O)C(O)=C1Cl

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Application In Synthesis of [ 32864-11-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 32864-11-2 ]

[ 32864-11-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 5417-17-4 ]
  • [ 32864-11-2 ]
YieldReaction ConditionsOperation in experiment
48.1% With boron tribromide; In dichloromethane; at 0 - 25℃; for 4h; <strong>[5417-17-4]2-chloroveratraldehyde</strong> (3 g, 15.0 mmol) wasdissolved in DCM (30 mL). BBr3 (4.61 mL, 48mmol) was added dropwise at 0°C. After addition,the reaction mixture was warmed to room temperature and stirred for 4 h. The reaction mixture wasextracted with EA and the organic phase was washed with water and brine, dried over anhydrousNa2SO4, filtered and then the filtrate was concentrated in vacuo. The residue was purified bychromatography on silica gel with DCM/MeOH (50:1) to give 73a-2 (1.24 g, 48.1percent) as a whitesolid.
 

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