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Chemical Structure| 320337-16-4 Chemical Structure| 320337-16-4

Structure of 320337-16-4

Chemical Structure| 320337-16-4

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Product Details of [ 320337-16-4 ]

CAS No. :320337-16-4
Formula : C5H13NO2S
M.W : 151.23
SMILES Code : O=S(CCN)(C(C)C)=O
MDL No. :MFCD06213263

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Application In Synthesis of [ 320337-16-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 320337-16-4 ]

[ 320337-16-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 120069-21-8 ]
  • [ 320337-16-4 ]
YieldReaction ConditionsOperation in experiment
With dimethylsulfide borane complex; In tetrahydrofuran; for 0.666667h;Heating / reflux; Iso-Propylsulfonylethylamine Prepared according to Procedure K. 2-iso-Propylsulfonylacetonitrile (0.50 g, 3.39 mmol) was dissolved in THF and warmed to reflux under N2. Borane dimethylsulfide (2M, 1.7 mL, 3.39 mmol) was added dropwise and the reaction was stirred for an additional 40 minutes at reflux. After cooling the reaction to rt, HCl (2 M in MeOH) was added to the reaction slowly due to gas evolution. The volatiles were removed and frexh methanol was added to the resulting residue. Again, the volatiles were removed and the resulting residue was taken up in CH2Cl2 (25 mL) and washed with saturated potassium carbonate (aqueous). The organic layer was dried over sodium sulfate and the volatiles were removed to afford the title compound. GC-MS m/z 152 (MH+).
 

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