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Chemical Structure| 3009-88-9 Chemical Structure| 3009-88-9

Structure of 3009-88-9

Chemical Structure| 3009-88-9

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Product Details of [ 3009-88-9 ]

CAS No. :3009-88-9
Formula : C7H11NO2
M.W : 141.17
SMILES Code : O=C(OC)CCCCC#N

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Application In Synthesis of [ 3009-88-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3009-88-9 ]

[ 3009-88-9 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 126-33-0 ]
  • [ 25899-50-7 ]
  • [ 26294-98-4 ]
  • [ 3009-88-9 ]
YieldReaction ConditionsOperation in experiment
92% In methanol; EXAMPLE 1 Approximately 4.4 parts of dicobalt octacarbonyl, 26.4 parts cis-2-pentenenitrile, 142 parts of tetramethylene sulfone, and 20 parts of methanol were charged to a magnetically stirred stainless steel autoclave. After the charge was complete the autoclave was sealed and heated with stirring to 180 C. under 31 MPa carbon monoxide pressure. After approximately 4 hours at these conditions, the autoclave was cooled to ambient temperature and the contents analyzed. It was found that the conversion of pentenenitrile was 92% and the yield of methyl 5-cyanovalerate was 92%.
  • 2
  • [ 126-33-0 ]
  • [ 26294-98-4 ]
  • [ 16529-66-1 ]
  • [ 3009-88-9 ]
YieldReaction ConditionsOperation in experiment
55% In methanol; EXAMPLE 2 Approximately 4 parts of dicobaltoctacarbonyl, 21 parts of 3-pentenenitrile, 150 parts of tetramethylenesulfone, and 20 parts of methanol were charged to a magnetically stirred stainless steel autoclave. After the charge was complete, the autoclave was sealed, heated with stirring to 160 C. and pressurized to 21 MPa with carbon monoxide. After approximately four hours at these conditions, the autoclave was cooled to ambient temperature and the contents analyzed. It was found that the conversion of pentenenitrile was 55%, and the yield of methyl 5-cyanovalerate was 93%.
  • 3
  • [ 126-33-0 ]
  • [ 26294-98-4 ]
  • [ 3009-88-9 ]
YieldReaction ConditionsOperation in experiment
78% In methanol; EXAMPLE 3 Approximately 4 parts of dicobaltoctacarbonyl, 20 parts of 2-pentenenitrile, A 150 parts of tetramethylenesulfone, and 20 parts of methanol were charged to a magnetically stirred stainless steel autoclave. After the charge was complete, the autoclave was sealed, heated with stirring to 160 C. and pressurized to 21 MPa with carbon monoxide. After approximately four hours at these conditions, the autoclave was cooled to ambient temperature and the contents analyzed. It was found that the conversion of pentenenitrile was 78%, and the yield of methyl 5-cyanovalerate was 93%.
 

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