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Chemical Structure| 26117-27-1 Chemical Structure| 26117-27-1

Structure of 26117-27-1

Chemical Structure| 26117-27-1

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Product Details of [ 26117-27-1 ]

CAS No. :26117-27-1
Formula : C6H10N2O4
M.W : 174.15
SMILES Code : O=C(C[C@@H](NC(C)=O)C(O)=O)N
MDL No. :MFCD00038154

Safety of [ 26117-27-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H312-H332
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P330-P363-P501

Application In Synthesis of [ 26117-27-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 26117-27-1 ]

[ 26117-27-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 14464-29-0 ]
  • [ 4474-86-6 ]
  • [ 26117-27-1 ]
YieldReaction ConditionsOperation in experiment
N2-Acetyl-D-asparagine The title compound was prepared by conventional methods of peptide chemistry, at first by esterification of N2-[(benzyloxy)carbonyl]-D-asparagine with (2-trimethylsilyl)ethanol with EDCI/DMAP in DCM, followed by hydrogenolytic detachment of the benzyl ester over 10percent palladium/activated carbon in DCM/methanol 1:1, then by reaction with 1-acetoxypyrrolidine-2,5-dione in the presence of N,N-diisopropylethylamine and finally by detachment of the Teoc protecting group by stirring at 50° C. with 6 equivalents of zinc chloride in trifluoroethanol for 1 h. LC-MS (Method 1): Rt=0.15 min; MS (ESIneg): m/z=173 (M-H)-.
 

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