Alternatived Products of [ 2314-78-5 ]
Product Details of [ 2314-78-5 ]
CAS No. : | 2314-78-5 |
MDL No. : | MFCD00059748 |
Formula : |
C6H9NO2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | GHAZCVNUKKZTLG-UHFFFAOYSA-N |
M.W : |
127.14
|
Pubchem ID : | 16842 |
Synonyms : |
|
Application In Synthesis of [ 2314-78-5 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 2314-78-5 ]
- 1
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[ 2314-78-5 ]
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[ 7335-06-0 ]
- 2
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[ 2314-78-5 ]
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[ 2687-91-4 ]
- 3
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[ 2687-91-4 ]
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[ 2314-78-5 ]
- 4
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[ 2687-91-4 ]
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[ 2314-78-5 ]
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[ 932-17-2 ]
- 5
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[ 2314-78-5 ]
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[ 37637-20-0 ]
- 6
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[ 2314-78-5 ]
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[ 7664-93-9 ]
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[ 7732-18-5 ]
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[ 7335-06-0 ]
- 7
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[ 2314-78-5 ]
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[ 7664-93-9 ]
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[ 7732-18-5 ]
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[ 7335-06-0 ]
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[ 2687-91-4 ]
- 8
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[ 121-44-8 ]
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[ 60-35-5 ]
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[ 2314-78-5 ]
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[ 685-91-6 ]
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[ 625-50-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
With dihydrogen peroxide In water at 160℃; for 120h; Autoclave; |
The gas chromatography-mass spectroscopy (GC-MS) spectrumindicated that there were no detectable organic compoundsin the starting purified triethylamine. In a typical synthesis,0.6 ml (4.3 mmol) purified triethylamine and 10 mL 30% (0.1 mol)hydrogen peroxide solution were mixed with water and then added into each steel alloy (Fe-Cr-Ni alloy, GB-1220-92) autoclavewith a filling capacity of 90% (approx. 1.4 MPa). The autoclaveswere then sealed tightly and placed in the oven with the temperatureranging from 20 to 200 C at the interval of every 20 C. After5 days, the solution in the autoclaves was taken out and analyzed.The final pH of the reaction mixture was 9.7. Gas chromatography-mass spectroscopy (GC-MS) was employed to identify theproducts. It is proved that 120 C is a turning point: when the temperatureis lower than that, the main product is N,N-diethylhydroxylamine(1); on the contrary, the product is more complex andthe main products are amides: N,N-diethylacetamide(2),N-ethylacetamide(3), acetylamine(4), and 1-ethylpyrrolidine-2,5-dione(5), when the mass spectra of the products were comparedto those of standard substances (Figs. S1-S5). The reaction can berepresented as follows: |
Reference:
[1]Bai, Xueyin; Liu, Ziwei; Ye, Kaiqi; Wang, Yu; Zhang, Xianlong; Yue, Huijuan; Tian, Ge; Feng, Shouhua
[Tetrahedron Letters, 2014, vol. 55, # 2, p. 319 - 321]
- 9
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[ 110-15-6 ]
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[ 143314-17-4 ]
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[ 1121-07-9 ]
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[ 2314-78-5 ]
- 10
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[ 848641-69-0 ]
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[ 110-15-6 ]
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[ 1121-07-9 ]
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[ 2314-78-5 ]
Yield | Reaction Conditions | Operation in experiment |
1: 67.9 %Chromat.
2: 8.7 %Chromat. |
With carbon dioxide at 150℃; for 18h; Green chemistry; |
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- 11
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[ 110-15-6 ]
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[ 174899-82-2 ]
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[ 1121-07-9 ]
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[ 2314-78-5 ]
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[ 123-25-1 ]
- 12
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[ 2314-78-5 ]
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[ 16078-30-1 ]
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3-(1-acetylindolin-7-yl)-1-ethylpyrrolidine-2,5-dione
[ No CAS ]