[ CAS No. 160248-28-2 ] {[proInfo.proName]}

Name: 160248-28-2|4,4',4'',4'''-Methanetetrayltetrabenzoic acid|95%
Brand: Ambeed
SKU: A1083829
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Quality Control of [ 160248-28-2 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 160248-28-2 ]

SDS Specification

Alternatived Products of [ 160248-28-2 ]

Product Details of [ 160248-28-2 ]

CAS No. :	160248-28-2	MDL No. :	MFCD28385403
Formula :	C₂₉H₂₀O₈	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	VSFXBCHNPQPWBX-UHFFFAOYSA-N
M.W :	496.46	Pubchem ID :	15501836
Synonyms :

Safety of [ 160248-28-2 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313	UN#:	N/A
Hazard Statements:	H315-H319	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 160248-28-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 160248-28-2 ]

[ 160248-28-2 ] Synthesis Path-Downstream 1~45

1
[ 908094-01-9 ]
[ 160248-28-2 ]
[ 1233-73-4 ]
[ 105309-62-4 ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; diethyl ether Ambient temperature; Yield given. Yields of byproduct given;

Reference： [1]Kirste, Burkhard; Grimm, Michael; Kurreck, Harry [Journal of the American Chemical Society, 1989, vol. 111, # 1, p. 108 - 114]

2
[ 908094-01-9 ]
[ 160248-28-2 ]
[ 105309-62-4 ]

Yield	Reaction Conditions	Operation in experiment
99.6%	In methanol; diethyl ether Ambient temperature;

Reference： [1]Grimm, Michael; Kirste, Burkhard; Kurreck, Harry [Angewandte Chemie, 1986, vol. 98, # 12, p. 1095 - 1099]

3
[ 121706-21-6 ]
[ 160248-28-2 ]

Yield	Reaction Conditions	Operation in experiment
98.8%	With potassium hydroxide In ethylene glycol Heating;
	With potassium hydroxide In ethylene glycol for 19h; Heating;

Reference： [1]Grimm, Michael; Kirste, Burkhard; Kurreck, Harry [Angewandte Chemie, 1986, vol. 98, # 12, p. 1095 - 1099]
[2]Kirste, Burkhard; Grimm, Michael; Kurreck, Harry [Journal of the American Chemical Society, 1989, vol. 111, # 1, p. 108 - 114]

4
[ 117679-69-3 ]
[ 160248-28-2 ]

Yield	Reaction Conditions	Operation in experiment
	With chromium(VI) oxide; sulfuric acid In acetic anhydride; acetic acid at 10℃; for 0.5h; Yield given;

Reference： [1]Kirste, Burkhard; Grimm, Michael; Kurreck, Harry [Journal of the American Chemical Society, 1989, vol. 111, # 1, p. 108 - 114]

5
[ 160248-28-2 ]
[ 356060-69-0 ]

Yield	Reaction Conditions	Operation in experiment
	With oxalyl dichloride; N,N-dimethyl-formamide at 20℃; for 4h;

Reference： [1]Cannon, Amy S.; Jian, Tianying; Wang, Jun; Warner, John C. [Organic Preparations and Procedures International, 2004, vol. 36, # 4, p. 353 - 359]

6
[ 160248-28-2 ]
C₃₇H₄₀N₄O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: oxalyl chloride; N,N-dimethylformamide / 4 h / 20 °C 2: CH₂Cl₂ / cooling

Reference： [1]Cannon, Amy S.; Jian, Tianying; Wang, Jun; Warner, John C. [Organic Preparations and Procedures International, 2004, vol. 36, # 4, p. 353 - 359]

7
[ 160248-28-2 ]
C₄₅H₅₆N₄O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: oxalyl chloride; N,N-dimethylformamide / 4 h / 20 °C 2: 1.083 g / CH₂Cl₂ / cooling

Reference： [1]Cannon, Amy S.; Jian, Tianying; Wang, Jun; Warner, John C. [Organic Preparations and Procedures International, 2004, vol. 36, # 4, p. 353 - 359]

8
[ 971-93-7 ]
[ 160248-28-2 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 11.8 percent / toluene / 48 h 2: CrO₃, H₂SO₄ / acetic acid; acetic anhydride / 0.5 h / 10 °C

Reference： [1]Kirste, Burkhard; Grimm, Michael; Kurreck, Harry [Journal of the American Chemical Society, 1989, vol. 111, # 1, p. 108 - 114]

9
[ 105309-59-9 ]
[ 160248-28-2 ]

Reference： [1]Journal of the American Chemical Society,1989,vol. 111,p. 108 - 114
[2]Angewandte Chemie,1986,vol. 98,p. 1095 - 1099

10
[ 4294-57-9 ]
[ 160248-28-2 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 11.8 percent / toluene / 48 h 2: CrO₃, H₂SO₄ / acetic acid; acetic anhydride / 0.5 h / 10 °C

Reference： [1]Kirste, Burkhard; Grimm, Michael; Kurreck, Harry [Journal of the American Chemical Society, 1989, vol. 111, # 1, p. 108 - 114]

11
[ 76-84-6 ]
[ 160248-28-2 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 4 steps 2: 66 percent / Br₂ / 0.75 h / Ambient temperature 3: 96.5 percent / KI/KOH/Pd(II)-acetate, HMPA 4: 98.8 percent / KOH / ethane-1,2-diol / Heating

Reference： [1]Grimm, Michael; Kirste, Burkhard; Kurreck, Harry [Angewandte Chemie, 1986, vol. 98, # 12, p. 1095 - 1099]

12
[ 630-76-2 ]
[ 160248-28-2 ]

Reference： [1]Angewandte Chemie,1986,vol. 98,p. 1095 - 1099
[2]Zeitschrift fur Anorganische und Allgemeine Chemie,2019,vol. 645,p. 912 - 918

13
[ 62-53-3 ]
[ 160248-28-2 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 4 steps 2: 66 percent / Br₂ / 0.75 h / Ambient temperature 3: 96.5 percent / KI/KOH/Pd(II)-acetate, HMPA 4: 98.8 percent / KOH / ethane-1,2-diol / Heating

Reference： [1]Grimm, Michael; Kirste, Burkhard; Kurreck, Harry [Angewandte Chemie, 1986, vol. 98, # 12, p. 1095 - 1099]

14
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
Cd₄(tetrakis(4-carboxyphenyl)methane^(4-))2(dimethylformamide)4*4(dimethylformamide)*4H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
61%	In N,N-dimethyl-formamide High Pressure; soln. of C(C6H4COOH)4 and Cd(NO3)2*4H2O in DMF heated at 95°C for2 d in a screw-capped vial; crystals collected, washed with DMF, dried under reduced pressure at room temp.; elem. anal.;

Reference： [1]Chun, Hyungphil; Kim, Dongwoo; Dybtsev, Danil N.; Kim, Kimoon [Angewandte Chemie - International Edition, 2004, vol. 43, # 8, p. 971 - 974]

15
zinc(II) nitrate hexahydrate [ No CAS ]
[ 160248-28-2 ]
Zn₂(methane tetrabenzoate)(H₂O)2*(DMF)6(H₂O)5 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
63%	In ethanol; water; N,N-dimethyl-formamide acid, Zn(NO3)2*6H2O, DMF, EtOH, and water were heated to 70°C; react. mixt. was cooled to room temp., crystals were filtered; elem. anal.;

Reference： [1]Kim; Chen; Reineke; Li; Eddaoudi; Moler; O'Keeffe; Yaghi [Journal of the American Chemical Society, 2001, vol. 123, # 34, p. 8239 - 8247]

16
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
Co4(μ-OH2)4(methanetetrabenzoate)2(H2O)4*13DMF*11H2O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In ethanol; water; N,N-dimethyl-formamide High Pressure; Co salt and methanetetrabenzoic acid reacted solvothermally in DMF/EtOH/H2O (3:1:1 v/v/v) at 50°C; XRD;

Reference： [1]Cheon, Young Eun; Suh, Myunghyun Paik [Chemical Communications, 2009, # 17, p. 2296 - 2298]

17
[ 617-84-5 ]
copper nitrate hemi(pentahydrate) [ No CAS ]
[ 7732-18-5 ]
[ 160248-28-2 ]
[Cu₂(methanetetra(p-benzoic acid)(-1H))(H₂O)2]*6(diethylformamide)*2H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
72%	With HCl In water to mixt. of C(C6H4COOH)4 and Cu nitrate in H2O/def, several drops of aq.HCl added, placed in oven at 80°C for 1 d; collected by filtration;

Reference： [1]Ma, Liqing; Jin, Athena; Xie, Zhigang; Lin, Wenbin [Angewandte Chemie - International Edition, 2009, vol. 48, # 52, p. 9905-9908+9768]

18
[ 160248-28-2 ]
Co4(μ-OH2)4(methanetetrabenzoate)2 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: water; N,N-dimethyl-formamide; ethanol 2: neat (no solvent)

Reference： [1]Cheon, Young Eun; Suh, Myunghyun Paik [Chemical Communications, 2009, # 17, p. 2296 - 2298]

19
nickel(II) nitrate hexahydrate [ No CAS ]
[ 7732-18-5 ]
[ 160248-28-2 ]
[ 33513-42-7 ]
[Ni4(μ6-methanetetrabenzoate)2(μ2-H2O)4(H2O)4]·10DMF·11H2O}n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	at 80℃; for 48h;

Reference： [1]Almasi, Miroslav; Zelenak, Vladimir; Opanasenko, Maksym; Cejka, Jiri [Dalton Transactions, 2014, vol. 43, # 9, p. 3730 - 3738]

20
[ 64-18-6 ]
zirconyl chloride octahydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
4HO^(1-)*10C₃H₇NO*12H₂O*4CHO₂^(1-)*2C₂₉H₁₆O₈^(4-)*Zr₆O₄⁽¹⁶⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
55%	at 100℃; for 168h;

Reference： [1]Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao; Jiang, Juncong; Queen, Wendy L.; Hudson, Matthew R.; Yaghi, Omar M. [Journal of the American Chemical Society, 2014, vol. 136, # 11, p. 4369 - 4381]

21
zirconyl chloride octahydrate [ No CAS ]
[ 160248-28-2 ]
4HO^(1-)*2H₂O*3C₂₉H₁₆O₈^(4-)*Zr₆O₄⁽¹⁶⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In formic acid; N,N-dimethyl-formamide at 130℃; for 24h;

22
[ 64-18-6 ]
zirconium oxide chloride octahydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
[Zr₆O₄(OH)₄(C₂₉H₁₆O₈)₂(HCOO)₄(H₂O)₄](C₃H₇NO)₁₀(H₂O)₈ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
55%	at 130℃; for 48h;	Zr₆04(OH)4(MTB)2(HCOO)4(H₂0)4, MOF-841. H4MTB (0.12 g, 0.25 mmol) and ZrOCi2- 8H20 (0.32 g, 1.0 mmol) in a solvent mixture of DMF/formic acid (40 mL/25 mL) were placed in a 125-mL screw-capped glass jar, which was heated at 130 °C for two days. Mother liquor of the reaction mixture was separated and further heated at 130 °C for another two days. Colorless block crystals were collected and washed three times with 5 mL of fresh DMF (Yield: 0.13g, 55 % based on H4MTB). digested solution NMR of as-synthesized sample (400 MHz, DMSO-d6, ppm): 8.1 11 (s, 2H, 2 x HCOOH), 7.929 (s, 5H, 5 x DMF) , 7.883 (d, J= 4.4 Hz, 8H, 1 x MTB), 7.335 (d, J= 4.4 Hz, 8H, 1 x MTB), 2.875 (5s, 15H, 5 x DMF), 2.717 (s, 15H, 5 x DMF). EA of as -synthesized sample: Calcd. for Zr6C92Hl34O54Nl0 = [Zr6O4(OH)4(C29Hl6O8)2 (HCOO)4(H2O)4](C3H7NO)l0(H2O)8: C, (0404) 39.58; H, 4.84; N, 5.02%; Found: C, 39.1 1; H, 4.91 ; N, 5.09%. ATR-FTIR (4000-400 cnr l): 3382 (br), 2930 (vw), 2860 (vw), 1652 (m), 1602 (m), 1583 (m), 1564 (m), 1541 (m), 1407 (s), 1253 (m), 1 191 (m), 1 151 (w), 1096 (w), 1061 (w), 1017 (w), 860 (w), 837 (w), 772 (m), 743 (w), 719 (w), 695 (w), 646 (s), 523 (m), 454 (s).

Reference： [1]Current Patent Assignee: UNIVERSITY OF CALIFORNIA; APPLIANCE INNOVATION INC - WO2015/127033, 2015, A1 Location in patent: Paragraph 00222

23
zirconium oxide chloride octahydrate [ No CAS ]
[ 160248-28-2 ]
Zr6O4(OH)4(4,4',4'',4'''-methanetetrayltetrabenzoate)3(H2O)2 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With formic acid In N,N-dimethyl-formamide at 130℃; for 24h;	Zr604(OH)₄(MTB)3(H₂0)2, MOF-812. Methanetetrabenzoic acid (H4MTB) (0.048 g, 0.1 mmol) and ZrOCi2- 8H20 (0.064 g, 0.2 mmol) were dissolved in a solvent mixture of DMF/formic acid (10 mL/6 mL) in a 20-mL screw-capped glass vial, which was heated at 130 °C for one day.

Reference： [1]Current Patent Assignee: UNIVERSITY OF CALIFORNIA; APPLIANCE INNOVATION INC - WO2015/127033, 2015, A1 Location in patent: Paragraph 00221

24
[ 295-37-4 ]
zinc nitrate tetrahydrate [ No CAS ]
[ 7732-18-5 ]
[ 160248-28-2 ]
[ 33513-42-7 ]
[Zn2(μ4-methanetetracarboxylate)(κ4-1,4,8,11-tetraazacyclotetradecane)2]*2(N,N’-dimethylformamide)*7H2O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%	In ethanol at 89.84℃; for 53h; Autoclave;

Reference： [1]Almáši, Miroslav; Zeleňák, Vladimír; Zukal, ArnoŠt; Kuchár, Juraj; Čejka, Jiří [Dalton Transactions, 2016, vol. 45, # 3, p. 1233 - 1242]

25
[ 119478-59-0 ]
[ 7732-18-5 ]
[ 160248-28-2 ]
[Ni(1,3,6,9,11,14-hexaazatricyclooctadecane)]₂[methanetetrabenzoate]*16H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
57%	With triethylamine In acetonitrile at 20℃; for 504h;

Reference： [1]Jiang, Xiang; Kou, Hui-Zhong [Chemical Communications, 2016, vol. 52, # 14, p. 2952 - 2955]

26
[Ni(1,3,6,10,12,15-hexaazatricycloeicosane)]*(ClO₄)₂ [ No CAS ]
[ 7732-18-5 ]
[ 160248-28-2 ]
[Ni(1,3,6,10,12,15-hexaazatricycloeicosane)]₂[methanetetrabenzoate]*8H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
53%	With triethylamine In acetonitrile at 20℃; for 336h;

Reference： [1]Jiang, Xiang; Kou, Hui-Zhong [Chemical Communications, 2016, vol. 52, # 14, p. 2952 - 2955]

27
uranyl nirate hexahydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
3C₂₉H₁₆O₈^(4-)*4C₂H₈N⁽¹⁺⁾*4O₂U⁽²⁺⁾*8C₃H₇NO*100H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80.1%	With nitric acid at 120℃; for 48h; High pressure; Autoclave;

Reference： [1]Hu, Kong-Qiu; Jiang, Xiang; Wang, Cong-Zhi; Mei, Lei; Xie, Zhen-Ni; Tao, Wu-Qing; Zhang, Xiao-Lin; Chai, Zhi-Fang; Shi, Wei-Qun [Chemistry - A European Journal, 2017, vol. 23, # 3, p. 529 - 532]

28
uranyl nirate hexahydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
6C₂₉H₁₆O₈^(4-)*8C₂H₈N⁽¹⁺⁾*8O₂U⁽²⁺⁾*12C₃H₇NO*64H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
66.5%	With nitric acid In water at 120℃; for 48h; High pressure; Autoclave;

29
lead(II) nitrate [ No CAS ]
[ 7732-18-5 ]
[ 160248-28-2 ]
[ 33513-42-7 ]
[Pb₄(μ₈-methanetetrabenzoate)₂(H₂O)₄]*5(N,N′-dimethylformamide)*H₂O} [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In ethanol at 79.84℃;

Reference： [1]Almáši, Miroslav; Zeleňák, Vladimír; Gyepes, Róbert; Bourrelly, Sandrine; Opanasenko, Maksym V.; Llewellyn, Philip L.; Čejka, Jiří [Inorganic Chemistry, 2018, vol. 57, # 4, p. 1774 - 1786]

30
thorium(IV) nitrate hexahydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
C₂₉H₁₆O₈^(4-)*6H₂O*5.5C₃H₇NO*Th⁽⁴⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
61.4%	With nitric acid at 90℃; for 72h; Sealed tube;

Reference： [1]Wang, Yanlong; Liu, Wei; Bai, Zhuanling; Zheng, Tao; Silver, Mark A.; Li, Yuxiang; Wang, Yaxing; Wang, Xia; Diwu, Juan; Chai, Zhifang; Wang, Shuao [Angewandte Chemie - International Edition, 2018, vol. 57, # 20, p. 5783 - 5787][Angew. Chem., 2018, vol. 130, p. 5885 - 5889,5]

31
[ 160248-28-2 ]
trans-1,4-diaminocyclohexane dihydrochloride [ No CAS ]
C₂₉H₂₀O₈*2C₆H₁₄N₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	With sodium hydroxide In methanol; water at 20℃;

Reference： [1]Xing, Guolong; Yan, Tingting; Das, Saikat; Ben, Teng; Qiu, Shilun [Angewandte Chemie - International Edition, 2018, vol. 57, # 19, p. 5345 - 5349][Angew. Chem., 2018, vol. 130, p. 5443 - 5447,5]

32
[ 124-38-9 ]
[ 105309-59-9 ]
[ 160248-28-2 ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2019,vol. 645,p. 912 - 918
[2]Journal of Materials Chemistry A,2018,vol. 6,p. 14231 - 14239

33
tetracosa-9,11-diyn-1-amine [ No CAS ]
[ 160248-28-2 ]
C₁₂₅H₁₈₄N₄O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; triethylamine

Reference： [1]Jeong, Woomin; Khazi, Mohammed Iqbal; Lee, Dong Geol; Kim, Jong-Man [Macromolecules, 2018, vol. 51, # 24, p. 10312 - 10322]

34
[ 366-18-7 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
2C₂₉H₁₆O₈^(4-)*4Cd⁽²⁺⁾*7C₃H₇NO*4C₁₀H₈N₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	at 70℃;

Reference： [1]Harms, Sven; Köferstein, Roberto; Görls, Helmar; Robl, Christian [Zeitschrift fur Anorganische und Allgemeine Chemie, 2019, vol. 645, # 14, p. 912 - 918]

35
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 160248-28-2 ]
[ 33513-42-7 ]
C₂₉H₁₆O₈^(4-)*2Cd⁽²⁺⁾*3H₂O*C₃H₇NO [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In water at 50℃;

Reference： [1]Harms, Sven; Köferstein, Roberto; Görls, Helmar; Robl, Christian [Zeitschrift fur Anorganische und Allgemeine Chemie, 2019, vol. 645, # 14, p. 912 - 918]

36
[ 160248-28-2 ]
C₂₉H₂₀O₈*2C₈H₁₀N₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: methanol; water / 1 h / 20 °C 2: ethanol; water / 168 h

Reference： [1]Boer, Stephanie A.; Morshedi, Mahbod; Tarzia, Andrew; Doonan, Christian J.; White, Nicholas G. [Chemistry - A European Journal, 2019, vol. 25, # 42, p. 10006 - 10012]

37
[ 160248-28-2 ]
C₂₉H₂₀O₈*C₂₉H₂₈N₈ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: methanol; water / 1 h / 20 °C 2: water / 168 h

Reference： [1]Boer, Stephanie A.; Morshedi, Mahbod; Tarzia, Andrew; Doonan, Christian J.; White, Nicholas G. [Chemistry - A European Journal, 2019, vol. 25, # 42, p. 10006 - 10012]

38
[ 2052-49-5 ]
[ 160248-28-2 ]
4C₁₆H₃₆N⁽¹⁺⁾*C₂₉H₁₆O₈^(4-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
94%	In methanol; water at 20℃; for 1h;

Reference： [1]Boer, Stephanie A.; Morshedi, Mahbod; Tarzia, Andrew; Doonan, Christian J.; White, Nicholas G. [Chemistry - A European Journal, 2019, vol. 25, # 42, p. 10006 - 10012]

39
tetrakis(4-amidiniumphenyl)methane tetrachloride [ No CAS ]
[ 160248-28-2 ]
biocompatible hydrogen-bonded organic framework-1 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With ammonium hydroxide In water at 20℃; for 1h; Darkness;

Reference： [1]Liang, Weibin; Carraro, Francesco; Solomon, Marcello B.; Bell, Stephen G.; Amenitsch, Heinz; Sumby, Christopher J.; White, Nicholas G.; Falcaro, Paolo; Doonan, Christian J. [Journal of the American Chemical Society, 2019, vol. 141, # 36, p. 14298 - 14305]

40
[ 64-17-5 ]
[ 160248-28-2 ]
[ 33513-42-7 ]
2C₂H₇N*2H⁽¹⁺⁾*4Ca⁽²⁺⁾*2C₂H₆O*2C₂₉H₁₆O₈^(4-)*O^(2-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
50%	With calcium(II) nitrate tetrahydrate at 80℃; for 120h;

Reference： [1]Di, Zhengyi; Hu, Falu; Li, Jing; Wu, Mingyan [Dalton Transactions, 2020, vol. 49, # 26, p. 8836 - 8840]

41
[ 7732-18-5 ]
[ CAS Unavailable ]
[ 160248-28-2 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
64 %	With nitric acid at 120℃; Sealed tube;

Reference： [1]Gómez-Oliveira, Eloy P.; Reinares-Fisac, Daniel; Aguirre-Díaz, Lina M.; Esteban-Betegón, Fátima; Pintado-Sierra, Mercedes; Gutiérrez-Puebla, Enrique; Iglesias, Marta; Ángeles Monge; Gándara, Felipe [Angewandte Chemie - International Edition, 2022, vol. 61, # 37][Angew. Chem., 2022, vol. 134, # 37]

42
[ CAS Unavailable ]
[ 7732-18-5 ]
[ 160248-28-2 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
40 mg	With nitric acid at 90℃; Sealed tube;

43
[ CAS Unavailable ]
[ 160248-28-2 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
61 %	In ethanol; water at 90℃; Sealed tube;

44
[ CAS Unavailable ]
[ 160248-28-2 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
70 %	at 120℃; Autoclave;	Synthesis of [Eu4(MTB)3(DMF)6].2DMF ( 1 ) 1 was synthesized as following: EuCl 3 .6H 2 O (0.147 g, 0.40 mmol) was added into DMF (3 mL) to form the clear solution in a 25 mL Teflon cell, the ligand H 4 MTB (0.149 g, 0.30 mmol) was dissolved in DMF (5 mL) and added to the above solution. After the mixed solution was stirred for 10 mins, the Teflon cell was sealed in the autoclave and then placed in an oven, the temper- ature of the oven was keeped at 120 °C and the heating time was 24 hours. After we slowly cooled the product to environment tem- perature, the colourless single-crystals was harvested. Yield: 70% based on EuCl 3 .6H 2 O. Anal. Calcd for C 111 H 104 Eu 4 N 8 O 32 : C, 49.93; H, 3.93; N, 4.20. Found: C, 50.11; H, 4.06; N, 4.38%. IR (KBr pellets, cm -1 ): 3423(s), 2930(w), 1656(s), 1602(s), 1534(s), 1413(s), 1108(s), 1016(w), 848(m), 777(s), 724(w), 670(w), 546(m).

Reference： [1]Luo, Jun; Liu, Bao-Shu; Zhang, Yun-Chang; Wang, Bing-Kai; Guo, Bei-Bei; She, Lan; Chen, Tian-Heng [Journal of Molecular Structure, 2023, vol. 1274]

45
[ 64-18-6 ]
[ 34754-42-2 ]
[ 160248-28-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	In N,N-dimethyl-formamide at 120℃;

Reference： [1]Hanna, Sylvia L.; Debela, Tekalign T.; Mroz, Austin M.; Syed, Zoha H.; Kirlikovali, Kent O.; Hendon, Christopher H.; Farha, Omar K. [Chemical Science, 2022, vol. 13, # 44, p. 13032 - 13039]

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H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
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H204	Fire or projection hazard
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H222	Extremely flammable aerosol
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H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
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Health hazards
Code	Phrase
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H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
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Code	Phrase
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H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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[ 160248-28-2 ] Synthesis Path-Downstream 1~45

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