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Chemical Structure| 1596367-33-7 Chemical Structure| 1596367-33-7

Structure of 1596367-33-7

Chemical Structure| 1596367-33-7

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Product Details of [ 1596367-33-7 ]

CAS No. :1596367-33-7
Formula : C13H20BNO3
M.W : 249.11
SMILES Code : O=C1C=C(B2OC(C)(C)C(C)(C)O2)C=CN1CC

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Application In Synthesis of [ 1596367-33-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1596367-33-7 ]

[ 1596367-33-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 832735-58-7 ]
  • [ 73183-34-3 ]
  • [ 1596367-33-7 ]
YieldReaction ConditionsOperation in experiment
With tris-(dibenzylideneacetone)dipalladium(0); potassium acetate; catacxium A; In N,N-dimethyl acetamide; at 90℃;Inert atmosphere; A solution of compound (150a) (202 mg, 1.0 mmol), bis pinacol diboron (381 mg, 1.5 mmol) and potassium acetate (294 mg, 3 mmol) in N,N'-dimethylacetamide (0.7 mL) was degassed with argon for 10 minutes and tris(dibenzylideneacetone)dipalladium(0) (Pd2dba3, 9 mg, 0.01 mmol) and Di(1-adamantyl)-n-butylphosphine (11mg, 0.03 mmol) were then added. The mixture was heated at 90C overnight and then concentrated. The residue was diluted with ethyl acetate. The organic layer was washed with saturated solution of sodium bicarbonate, brine, dried over sodium sulfate, filtered and concentrated under reduced pressure to give crude compound (150b) (800 mg) which was used in the next step without further purification. MS m/z ([M+H]+) 250.
 

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