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CAS No. : | 14680-77-4 | MDL No. : | MFCD00043105 |
Formula : | C24H16BCl4K | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 496.11 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P264-P271-P261-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In ethanol; water |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | In methanol; water for 0.5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
63% | In acetonitrile byproducts: C6H3Me3; pptn. on Et2O addn.; elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
metathesis reaction; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In ethanol; water pptn. on mixing ethanolic K-salt soln. and 100 fold aq. K-salt soln.; recrystn. from acetone; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
65% | In not given under Ar; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzonitrile K compd. added to soln. of Cu porphyrin at room temp.; not isolated; monitored by UV-vis spectra; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzonitrile K compd. added to soln. of VO porphyrin at room temp.; not isolated; monitored by UV-vis spectra; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzonitrile K compd. added to soln. of Ni porphyrin at room temp.; not isolated; monitored by UV-vis spectra; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzonitrile K compd. added to soln. of Pd porphyrin at room temp.; not isolated; monitored by UV-vis spectra; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzonitrile K compd. added to soln. of Ag porphyrin at room temp.; not isolated; monitored by UV-vis spectra; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzonitrile K compd. added to soln. of Co porphyrin at room temp.; not isolated; monitored by UV-vis spectra; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzonitrile K compd. added to soln. of Zn porphyrin at room temp.; not isolated; monitored by UV-vis spectra; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 4-morpholinoethanesulfonate In water; chlorobenzene byproducts: KOH; two-phase reaction of chlorobenzene soln. of In-tetraphenylporphyrinato complex with potassium tetrakis(p-chlorophenyl)borate at pH 6.0 bufferedby 4-morpholinoethanesulfonate soln.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzonitrile identified by UV spectroscopy; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | With 18-crown-6 ether; acetylacetonato(1,5-cyclooctadiene)rhodium(I); 6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(di-benzo[d,f][1,3,2]dioxaphosphepin) In water; toluene at 100℃; for 20h; Inert atmosphere; regioselective reaction; | |
56% | With acetylacetonato(1,5-cyclooctadiene)rhodium(I); 18-crown-6 ether; 6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(di-benzo[d,f][1,3,2]dioxaphosphepin) In water; toluene at 100℃; for 20h; Inert atmosphere; | 8 General Procedure for the Isomerization-Conjugate Addition Reaction of Arylborates General procedure: An oven-dried 20 mL crimp top vial was charged with acetylacetonato(1,5-cyclooctadiene)rhodium(I) (1.5 mol %), Biphephos (1.5 mol %), arylborate salt (2.0 equiv.) and stir bar, sealed with a Teflon septum and evacuated-purged with argon three times. Subsequently, toluene (3 mL/mmol ester), olefinic ester 1 (0.5-1.0 mmol) and water (150 μL/mmol ester) were added via hypodermic syringe, and the reaction mixture was stirred for 20 h at 100° C. After cooling to r.t. (=21° C.), the solvent was removed in vacuo and ester 3 was obtained after flash column chromatography (SiO2, ethyl acetate-hexane or diethyl ether-hexane). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
61% | With [Fe(Cp)2][BF4] |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | With hydrogenchloride In methanol; water at 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
50% | Stage #1: C30H16ClF4IrN4; water With hydrogenchloride In methanol for 0.5h; Stage #2: potassium tetrakis(4-chlorophenyl)borate In water |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
57% | Stage #1: C30H16ClF4IrN4; water With hydrogenchloride In methanol; water for 0.5h; Stage #2: potassium tetrakis(4-chlorophenyl)borate In methanol |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
67% | Stage #1: [Ir(biqb)(ppy)(CN)]*0.5H2O With hydrogenchloride In methanol; water for 0.5h; Stage #2: diethyl ether; potassium tetrakis(4-chlorophenyl)borate In methanol; water |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
46% | Stage #1: C30H20ClIrN4 With hydrogenchloride In methanol; water for 0.5h; Stage #2: dichloromethane; potassium tetrakis(4-chlorophenyl)borate In methanol; water |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
66% | Stage #1: C41H31IrN3P With hydrogenchloride In methanol; water for 0.5h; Stage #2: dichloromethane; potassium tetrakis(4-chlorophenyl)borate In methanol; water |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In acetonitrile at 24.84℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In acetonitrile at 24.84℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In [D3]acetonitrile at 24.84℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
55% | With 2,2,3,3,3-pentafluoropropanoic anhydride Schlenk technique; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | With 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate In acetonitrile at 60℃; for 18h; | |
68% | With 6C50H46N6O4*4Zn(2+)*8C2F6NO4S2(1-); chloranil; fullerene-C<SUB>6</SUB><SUB>0</SUB> In acetonitrile at 90℃; for 40h; Inert atmosphere; Schlenk technique; Glovebox; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With bis((1,1,1-trifluoro-N-(trifluoromethyl)sulfonyl)methylsulfonamido)zinc; C38H40N4O4 In acetonitrile at 90℃; for 40h; Inert atmosphere; Schlenk technique; Glovebox; |