Home Cart Sign in  
Chemical Structure| 1415387-40-4 Chemical Structure| 1415387-40-4

Structure of 1415387-40-4

Chemical Structure| 1415387-40-4

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 1415387-40-4 ]

CAS No. :1415387-40-4
Formula : C6H7N3O4S
M.W : 217.20
SMILES Code : NC1=CC(S(=O)(C)=O)=NC=C1[N+]([O-])=O
MDL No. :MFCD23703288

Safety of [ 1415387-40-4 ]

Application In Synthesis of [ 1415387-40-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1415387-40-4 ]

[ 1415387-40-4 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 2604-39-9 ]
  • [ 1415387-40-4 ]
  • 2
  • [ 2604-39-9 ]
  • [ 5188-07-8 ]
  • [ 1415387-40-4 ]
YieldReaction ConditionsOperation in experiment
89% The compound <strong>[2604-39-9]2-chloro-5-nitropyridin-4-amine</strong> 34a (500 mg, 2.88 mmol), sodium methanethiolate (2.02 g, 28.8 mmol) and methanol (15 ml) were mixed at room temperature. After stirring for 15 hours, The solvent was removed under reduced pressure, the residue was dissolved in ethyl acetate (100ml) and washed with water (50ml). The separated aqueous phase was extracted with additional ethyl acetate (100 mL). The organic phases were combined, dried over anhydrous sodium sulfate. After filtration, the filtrate solvent was removed under reduced pressure to give a yellow solid. The yellow solid was dissolved in tetrahydrofuran (120 mL).Then trifluoroacetic acid (16 ml) and m-chloroperoxybenzoic acid (5.56 g, 32.32 mmol) were added carefully.After stirring at room temperature for 20 minutes, most of the solvent was removed under reduced pressure. The residue was diluted with ethyl acetate (400ml), and washed sequentially with saturated sodium bicarbonate solution (200ml) and saturated sodium chloride solution (200ml) and washed. The organic phase was dried over anhydrous sodium sulfate and filtered, and the filtrate solvent was removed under reduced pressure, To give the desired product 2-methanesulfonyl-5-nitro-4-amine 34b (2.08g, yellow solid), yield: 89%
 

Historical Records

Technical Information

Categories