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Chemical Structure| 1396165-20-0 Chemical Structure| 1396165-20-0

Structure of 1396165-20-0

Chemical Structure| 1396165-20-0

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Product Details of [ 1396165-20-0 ]

CAS No. :1396165-20-0
Formula : C52H56N2O2S
M.W : 773.08
SMILES Code : O=S(C1=CC=C(N2C3=C(C4=C2C=CC(C(C)(C)C)=C4)C=C(C(C)(C)C)C=C3)C=C1)(C5=CC=C(N6C7=C(C8=C6C=CC(C(C)(C)C)=C8)C=C(C(C)(C)C)C=C7)C=C5)=O
MDL No. :N/A

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Application In Synthesis of [ 1396165-20-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1396165-20-0 ]

[ 1396165-20-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 37500-95-1 ]
  • [ 2050-48-8 ]
  • [ 1396165-20-0 ]
YieldReaction ConditionsOperation in experiment
58.21% To a solution of 3b (0.376g, 1.0mmol), 18-crown-6 (0.027g, 0.1mmol) and 3,6-di(tert-butyl)carbazole (0.68g, 2.4mmol) in DMPU (5mL) was added K2CO3 (0.55g, 4.0mmol). The reaction mixture was then purged with nitrogen for ten minutes before adding CuI (0.020g, 0.1mmol). The following procedure was similar to that used for 1a. Yield: 58.21%. M.p.:367-370C. 1H NMR (300MHz, CDCl3): delta (ppm) 8.26-8.23 (d, J=8.4Hz, 4H), 8.13 (s, 4H), 7.83-7.80 (d, J=8.4Hz, 2H), 7.50-7.43 (m, 8H), 1.46 (s, 36H). 13C NMR (75MHz, CDCl3): delta (ppm) 143.7, 142.8, 138.4, 137.9, 129.2, 126.2, 123.7, 123.6, 116.1, 108.8, 34.4, 31.6. MS (MALDI-TOF) [m/z]: calcd for C52H56N2O2S, 772.41; found, 772.5745. Anal. Calcd. for C52H56N2O2S (%): C, 80.79; H, 7.30; N 3.62; S, 4.15.found:C, 80.62; H, 7.38; N 3.67; S, 4.17.
 

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