[ CAS No. 1361119-48-3 ] {[proInfo.proName]}

Name: 1361119-48-3|4,4'-(Anthracene-9,10-diylbis(ethyne-2,1-diyl))dibenzaldehyde|98%
Brand: Ambeed
SKU: A1271741
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Structure of 1361119-48-3 * Storage: {[proInfo.prStorage]}

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Quality Control of [ 1361119-48-3 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 1361119-48-3 ]

Product Details of [ 1361119-48-3 ]

CAS No. :	1361119-48-3	MDL No. :
Formula :	C₃₂H₁₈O₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	XTERTOOUIOHMBT-UHFFFAOYSA-N
M.W :	434.48	Pubchem ID :	59053323
Synonyms :

Safety of [ 1361119-48-3 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1361119-48-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1361119-48-3 ]

[ 1361119-48-3 ] Synthesis Path-Downstream 1~10

1
[ 1361119-48-3 ]
[ 1361119-51-8 ]

Yield	Reaction Conditions	Operation in experiment
50%	With oxygen In dichloromethane at -20℃; for 48h; Irradiation;

Reference： [1]Fudickar, Werner; Linker, Torsten [Chemistry - A European Journal, 2011, vol. 17, # 49, p. 13661 - 13664]

2
[ 523-27-3 ]
[ 1361119-48-3 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: copper(l) iodide; bis(triphenylphosphine)palladium(II) chloride; diisopropylamine / tetrahydrofuran / 8 h / Reflux 2: copper(l) iodide; bis(triphenylphosphine)palladium(II) chloride; potassium hydroxide / tetrahydrofuran; N,N-dimethyl-formamide / 5 h / 80 °C
	Multi-step reaction with 2 steps 1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine / tetrahydrofuran / 8 h / Reflux 2: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium hydroxide / tetrahydrofuran; N,N-dimethyl-formamide / 5 h
	Multi-step reaction with 3 steps 1: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / 3 h / 60 °C / Inert atmosphere 2: potassium hydroxide / tetrahydrofuran; methanol / 25 °C 3: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / Inert atmosphere

Reference： [1]Fudickar, Werner; Linker, Torsten [Chemistry - A European Journal, 2011, vol. 17, # 49, p. 13661 - 13664]
[2]Fudickar, Werner; Linker, Torsten [Journal of the American Chemical Society, 2012, vol. 134, # 36, p. 15071 - 15082]
[3]Tarkuç, Simge; Eelkema, Rienk; Grozema, Ferdinand C. [Tetrahedron, 2017, vol. 73, # 33, p. 4994 - 5004]

3
[ 18750-95-3 ]
[ 1122-91-4 ]
[ 1361119-48-3 ]

Yield	Reaction Conditions	Operation in experiment
55%	With copper(l) iodide; bis(triphenylphosphine)palladium(II) chloride; potassium hydroxide In tetrahydrofuran; N,N-dimethyl-formamide at 80℃; for 5h;
55%	With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium hydroxide In tetrahydrofuran; N,N-dimethyl-formamide for 5h;

4
[ 1361119-48-3 ]
[ 95-54-5 ]
[ 1380209-60-8 ]

Yield	Reaction Conditions	Operation in experiment
61%	With iodine In tetrahydrofuran; water for 48h; Darkness; Inert atmosphere;

Reference： [1]Location in patent: experimental part Lee, I-Lin; Li, Sie-Rong; Chen, Kuan-Fu; Ku, Po-Jen; Singh, Ashutosh S.; Kuo, Hui-Tung; Wen, Yuh-Sheng; Chu, Chi-Wei; Sun, Shih-Sheng [European Journal of Organic Chemistry, 2012, # 15, p. 2906 - 2915]

5
[ 523-27-3 ]
[ 63697-96-1 ]
[ 1361119-48-3 ]

Yield	Reaction Conditions	Operation in experiment
51%	With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; diisopropylamine In tetrahydrofuran at 80℃; for 14h; Inert atmosphere;

6
[ 1361119-48-3 ]
9,10-bis(4-formylphenylethynyl)-9,10-dihydro-9,10-epidioxyanthracene [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
50%	With oxygen; methylene blue In chloroform at -20℃; for 18h; Irradiation;

Reference： [1]Fudickar, Werner; Linker, Torsten [Journal of the American Chemical Society, 2012, vol. 134, # 36, p. 15071 - 15082]

7
[ 1361119-48-3 ]
[ 109-77-3 ]
C₃₈H₁₈N₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With triethylamine In chloroform Reflux;	2.4. General procedure for the synthesis of DCV-end capped chromophores. The dicyanovinyl derivatives were synthesized via a Knoevenagel condensation reaction of the previously prepared carboxyaldehyde (2-6). Bisaldehydes (0.251 mmol), malononitrile (0.627 mmol) and 0.5 mL of TEA were stirred in chloroform (30 mL) at reflux temperature until aldehyde was digested. Solvent was removed under reduced pressure. The residue was purified by column chromatography on silica gel to obtain the desired product.

Reference： [1]Tarkuç, Simge; Eelkema, Rienk; Grozema, Ferdinand C. [Tetrahedron, 2017, vol. 73, # 33, p. 4994 - 5004]

8
[ 18512-55-5 ]
[ 1122-91-4 ]
[ 1361119-48-3 ]

Yield	Reaction Conditions	Operation in experiment
65%	With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran Inert atmosphere;	2.3.General procedure for the synthesis of 9,10-bis(ethnylarylaldehyde)anthracene (6-8). General procedure: 9,10-bis(ethynyl)anthracene (5) was freshly prepared prior to subsequent coupling reaction using a previously published procedure.S4 Diterminal alkyne (5) was coupled with the brominated aromatic aldehydes under Sonogashira coupling conditions. THF (30mL), brominated aromatic aldehydes (3.049 mmol), CuI (0.148 mmol) and Pd(PPh3)2Cl2 (0.152 mmol)were placed in a flask, degassed and backfilled with argon. To this solution was subsequently added a solution of 9,10-bis(ethynyl)anthracene (1.016 mmol) in THF (10 mL). Then 12 mL of TEA was added and the reaction mixture was refluxed for 12 hours. After removal of the solvent, the residue was dissolved in dichloromethane, washed with water and dried over MgSO4. After solvent removal, the residue was purified by column chromatography.

Reference： [1]Tarkuç, Simge; Eelkema, Rienk; Grozema, Ferdinand C. [Tetrahedron, 2017, vol. 73, # 33, p. 4994 - 5004]

9
[ 120-12-7 ]
[ 1361119-48-3 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 4 steps 1: bromine; acetic acid 2: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / 3 h / 60 °C / Inert atmosphere 3: potassium hydroxide / tetrahydrofuran; methanol / 25 °C 4: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / Inert atmosphere

Reference： [1]Tarkuç, Simge; Eelkema, Rienk; Grozema, Ferdinand C. [Tetrahedron, 2017, vol. 73, # 33, p. 4994 - 5004]

10
[ 18750-95-3 ]
[ 1361119-48-3 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: potassium hydroxide / tetrahydrofuran; methanol / 25 °C 2: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / Inert atmosphere

Reference： [1]Tarkuç, Simge; Eelkema, Rienk; Grozema, Ferdinand C. [Tetrahedron, 2017, vol. 73, # 33, p. 4994 - 5004]

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P233	Keep container tightly closed.
P234	Keep only in original container.
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P321
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P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
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P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
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P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
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H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
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H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
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H311	Toxic in contact with skin
H312	Harmful in contact with skin
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H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
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H319	Causes serious eye irritation
H320	Causes eye irritation
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H331	Toxic if inhaled
H332	Harmful if inhaled
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H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 1361119-48-3 ] {[proInfo.proName]}

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Application In Synthesis of [ 1361119-48-3 ]

[ 1361119-48-3 ] Synthesis Path-Downstream 1~10

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