Alternatived Products of [ 1361119-48-3 ]
Product Details of [ 1361119-48-3 ]
CAS No. : | 1361119-48-3 |
MDL No. : | |
Formula : |
C32H18O2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | XTERTOOUIOHMBT-UHFFFAOYSA-N |
M.W : |
434.48
|
Pubchem ID : | 59053323 |
Synonyms : |
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Safety of [ 1361119-48-3 ]
Application In Synthesis of [ 1361119-48-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1361119-48-3 ]
- 1
-
[ 1361119-48-3 ]
-
[ 1361119-51-8 ]
Yield | Reaction Conditions | Operation in experiment |
50% |
With oxygen In dichloromethane at -20℃; for 48h; Irradiation; |
|
- 2
-
[ 523-27-3 ]
-
[ 1361119-48-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1: copper(l) iodide; bis(triphenylphosphine)palladium(II) chloride; diisopropylamine / tetrahydrofuran / 8 h / Reflux
2: copper(l) iodide; bis(triphenylphosphine)palladium(II) chloride; potassium hydroxide / tetrahydrofuran; N,N-dimethyl-formamide / 5 h / 80 °C |
|
|
Multi-step reaction with 2 steps
1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine / tetrahydrofuran / 8 h / Reflux
2: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium hydroxide / tetrahydrofuran; N,N-dimethyl-formamide / 5 h |
|
|
Multi-step reaction with 3 steps
1: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / 3 h / 60 °C / Inert atmosphere
2: potassium hydroxide / tetrahydrofuran; methanol / 25 °C
3: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / Inert atmosphere |
|
Reference:
[1]Fudickar, Werner; Linker, Torsten
[Chemistry - A European Journal, 2011, vol. 17, # 49, p. 13661 - 13664]
[2]Fudickar, Werner; Linker, Torsten
[Journal of the American Chemical Society, 2012, vol. 134, # 36, p. 15071 - 15082]
[3]Tarkuç, Simge; Eelkema, Rienk; Grozema, Ferdinand C.
[Tetrahedron, 2017, vol. 73, # 33, p. 4994 - 5004]
- 3
-
[ 18750-95-3 ]
-
[ 1122-91-4 ]
-
[ 1361119-48-3 ]
Yield | Reaction Conditions | Operation in experiment |
55% |
With copper(l) iodide; bis(triphenylphosphine)palladium(II) chloride; potassium hydroxide In tetrahydrofuran; N,N-dimethyl-formamide at 80℃; for 5h; |
|
55% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium hydroxide In tetrahydrofuran; N,N-dimethyl-formamide for 5h; |
|
Reference:
[1]Fudickar, Werner; Linker, Torsten
[Chemistry - A European Journal, 2011, vol. 17, # 49, p. 13661 - 13664]
[2]Fudickar, Werner; Linker, Torsten
[Journal of the American Chemical Society, 2012, vol. 134, # 36, p. 15071 - 15082]
- 4
-
[ 1361119-48-3 ]
-
[ 95-54-5 ]
-
[ 1380209-60-8 ]
Yield | Reaction Conditions | Operation in experiment |
61% |
With iodine In tetrahydrofuran; water for 48h; Darkness; Inert atmosphere; |
|
Reference:
[1]Location in patent: experimental part
Lee, I-Lin; Li, Sie-Rong; Chen, Kuan-Fu; Ku, Po-Jen; Singh, Ashutosh S.; Kuo, Hui-Tung; Wen, Yuh-Sheng; Chu, Chi-Wei; Sun, Shih-Sheng
[European Journal of Organic Chemistry, 2012, # 15, p. 2906 - 2915]
- 5
-
[ 523-27-3 ]
-
[ 63697-96-1 ]
-
[ 1361119-48-3 ]
Yield | Reaction Conditions | Operation in experiment |
51% |
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diisopropylamine In tetrahydrofuran at 80℃; for 14h; Inert atmosphere; |
|
Reference:
[1]Location in patent: experimental part
Lee, I-Lin; Li, Sie-Rong; Chen, Kuan-Fu; Ku, Po-Jen; Singh, Ashutosh S.; Kuo, Hui-Tung; Wen, Yuh-Sheng; Chu, Chi-Wei; Sun, Shih-Sheng
[European Journal of Organic Chemistry, 2012, # 15, p. 2906 - 2915]
- 6
-
[ 1361119-48-3 ]
-
9,10-bis(4-formylphenylethynyl)-9,10-dihydro-9,10-epidioxyanthracene
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
50% |
With oxygen; methylene blue In chloroform at -20℃; for 18h; Irradiation; |
|
- 7
-
[ 1361119-48-3 ]
-
[ 109-77-3 ]
-
C38H18N4
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
With triethylamine In chloroform Reflux; |
2.4. General procedure for the synthesis of DCV-end capped chromophores.
The dicyanovinyl derivatives were synthesized via a Knoevenagel condensation reaction of the previously prepared carboxyaldehyde (2-6). Bisaldehydes (0.251 mmol), malononitrile (0.627 mmol) and 0.5 mL of TEA were stirred in chloroform (30 mL) at reflux temperature until aldehyde was digested. Solvent was removed under reduced pressure. The residue was purified by column chromatography on silica gel to obtain the desired product. |
- 8
-
[ 18512-55-5 ]
-
[ 1122-91-4 ]
-
[ 1361119-48-3 ]
Yield | Reaction Conditions | Operation in experiment |
65% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran Inert atmosphere; |
2.3.General procedure for the synthesis of 9,10-bis(ethnylarylaldehyde)anthracene (6-8).
General procedure: 9,10-bis(ethynyl)anthracene (5) was freshly prepared prior to subsequent coupling reaction using a previously published procedure.S4 Diterminal alkyne (5) was coupled with the brominated aromatic aldehydes under Sonogashira coupling conditions. THF (30mL), brominated aromatic aldehydes (3.049 mmol), CuI (0.148 mmol) and Pd(PPh3)2Cl2 (0.152 mmol)were placed in a flask, degassed and backfilled with argon. To this solution was subsequently added a solution of 9,10-bis(ethynyl)anthracene (1.016 mmol) in THF (10 mL). Then 12 mL of TEA was added and the reaction mixture was refluxed for 12 hours. After removal of the solvent, the residue was dissolved in dichloromethane, washed with water and dried over MgSO4. After solvent removal, the residue was purified by column chromatography. |
- 9
-
[ 120-12-7 ]
-
[ 1361119-48-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 4 steps
1: bromine; acetic acid
2: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / 3 h / 60 °C / Inert atmosphere
3: potassium hydroxide / tetrahydrofuran; methanol / 25 °C
4: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / Inert atmosphere |
|
- 10
-
[ 18750-95-3 ]
-
[ 1361119-48-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1: potassium hydroxide / tetrahydrofuran; methanol / 25 °C
2: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / Inert atmosphere |
|