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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
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Chemical Structure| 1187-82-2 Chemical Structure| 1187-82-2

Structure of 1187-82-2

Chemical Structure| 1187-82-2

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Product Details of [ 1187-82-2 ]

CAS No. :1187-82-2
Formula : C6H12O2
M.W : 116.16
SMILES Code : CCC[C@H](C)C(O)=O
MDL No. :MFCD08277250

Safety of [ 1187-82-2 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H227-H302+H312-H314
Precautionary Statements:P210-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338+P310-P312-P363-P370+P378-P403+P235-P405-P501
Class:8
UN#:3265
Packing Group:

Application In Synthesis of [ 1187-82-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1187-82-2 ]

[ 1187-82-2 ] Synthesis Path-Downstream   1~4

  • 2
  • [ 16957-70-3 ]
  • [ 1187-82-2 ]
YieldReaction ConditionsOperation in experiment
89% In methanol; EXAMPLE 2 Asymmetric hydrogenation of <strong>[16957-70-3]trans-2-methyl-2-pentenoic acid</strong> In an atmosphere of argon, 14.3 mg (16.8*10-3 mmol) of Ru(OAc)2 [(S)-(-)-OcH-binap] complex and 409 mg (3.58 mmol) of <strong>[16957-70-3]trans-2-methyl-2-pentenoic acid</strong> were dissolved in 18 ml of methanol, and the resulting solution was put into a 100 ml capacity autoclave and stirred at 25° C. for 24 hours under a hydrogen pressure of 1.5 atm. The reaction solution was concentrated under a reduced pressure and then subjected to distillation under a reduced pressure to obtain 370 mg of (S)-2-methylpentanoic acid with a yield of 89percent.
  • 3
  • [ 623-36-9 ]
  • [ 16957-70-3 ]
  • [ 123-15-9 ]
  • [ 1187-82-2 ]
  • 4
  • [ 623-36-9 ]
  • [ 16957-70-3 ]
  • [ 1187-82-2 ]
 

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