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[ CAS No. 1111637-72-9 ] (6-Acetamido-4-methylpyridin-3-yl)boronic acid

Cat. No.: A486329
Chemical Structure| 1111637-72-9
Chemical Structure| 1111637-72-9
Structure of 1111637-72-9
Purity Size Price USA Stock *0-1 Day Global Stock *5-7 Days Quantity
98% 100mg $221.00 Inquiry Inquiry
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98% 10g $4940.00 Inquiry Inquiry

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Product Details of [ 1111637-72-9 ]

CAS No. :1111637-72-9 MDL No. :MFCD12964547
Formula : C8H11BN2O3 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 194.00 Pubchem ID :-
Synonyms :

Safety of [ 1111637-72-9 ]

Signal Word:Warning Class:
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330 UN#:
Hazard Statements:H302-H315-H319 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1111637-72-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1111637-72-9 ]

[ 1111637-72-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 142404-82-8 ]
  • [ 1111637-72-9 ]
YieldReaction ConditionsOperation in experiment
Preparation of 6-acetamido-4-methylpyridin-3-ylboronic acid (73)To a stirred solution of the 2-acetylamino-5-bromo-4-methylpyridine (1.858g, 8.11 mmol) and boron isopropoxide (7.5ml, 32.4mmol) in THF cooled to -780C was added n-butyl lithium (4.1 ml, 41mmol of 10 M soln in hexanes). After 1 hour at -780C, the reaction was quenched with water and warmed to room temperature. THF was removed under reduced pressure. Added 2N HCI until a precipitate developed. Filtered and washed with a minimal amount of water and dried under vacuum. 1 H NMR (400 MHz, DMSO-d6) d ppm 2.07 (s, 3 H) 2.39 (s, 3 H) 7.84 (s, 1 H) 8.09 (s, 2 H) 8.33 (s, 1 H) 10.36 (s, 1 H).
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