Home Cart Sign in  
Chemical Structure| 105125-00-6 Chemical Structure| 105125-00-6

Structure of 105125-00-6

Chemical Structure| 105125-00-6

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 105125-00-6 ]

CAS No. :105125-00-6
Formula : C12H7BrS3
M.W : 327.28
SMILES Code : BrC1=C(C2=CC=CS2)SC(C3=CC=CS3)=C1
MDL No. :MFCD27976807

Safety of [ 105125-00-6 ]

Application In Synthesis of [ 105125-00-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 105125-00-6 ]

[ 105125-00-6 ] Synthesis Path-Downstream   1~7

  • 2
  • [ 188290-36-0 ]
  • [ 3141-24-0 ]
  • [ 1006384-44-6 ]
  • [ 492-97-7 ]
  • [ 105125-00-6 ]
  • 3
  • [ 3141-24-0 ]
  • [ 5713-61-1 ]
  • [ 3140-92-9 ]
  • [ 1006384-44-6 ]
  • [ 492-97-7 ]
  • [ 105125-00-6 ]
  • 4
  • [ 3141-24-0 ]
  • [ 6165-68-0 ]
  • [ 1006384-44-6 ]
  • [ 105125-00-6 ]
  • 6
  • [ 872-31-1 ]
  • [ 3141-24-0 ]
  • [ 105125-00-6 ]
  • 7
  • [ 3141-24-0 ]
  • [ 54663-78-4 ]
  • [ 105125-00-6 ]
YieldReaction ConditionsOperation in experiment
69% With tetrakis(triphenylphosphine) palladium(0); In N,N-dimethyl-formamide; at 80℃; for 40h;Inert atmosphere; In a 100-mL round-bottom flask were added <strong>[3141-24-0]2,3,5-tribromothiophene</strong>(1) (3.2 mL, 25 mmol), 2-(tributylstannyl)thiophene (17.5mL, 55 mmol), Pd(PPh3)4, and DMF (50 mL). The mixturewas stirred at 80 C for 40 h under nitrogen atmosphere. Afterthe mixture was cooled to room temperature, it was dilutedwith diethyl ether (200 mL), washed with HCl (10 mL, 2.0M) and then brine, and dried over anhydrous MgSO4. Theorganic layer was dried and the solvent evaporated. The result-ing crude product was purified by silica gel flash chromatog-raphy using hexane as the eluent. The solvent was evaporatedand the product was dried in vacuo to give 5.6 g (69%) of alight yellow oil. 1H NMR (300 MHz, CDCl3) delta: 7.43 (dd,1H, J = 1.2, 3.6 Hz), 7.36 (dd, 1H, J = 1.2, 5.1Hz), 7.27 (dd,1H, J = 1.2, 5.1 Hz), 7.19 (dd, 1H, J = 1.2, 3.6Hz), 7.09 (dd,1H, J = 3.6, 5.1 Hz), 7.08 (s), 7.04 (dd, 1H, J = 3.6, 5.1 Hz);13C NMR (75 MHz, CDCl3) delta: 135.7, 135.6, 134.1, 130.7,128.0, 127.6, 127.2, 126.5, 126.1, 125.3, 124.3, 107.8.
 

Historical Records

Technical Information

Categories