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Chemical Structure| 1009799-44-3 Chemical Structure| 1009799-44-3

Structure of 1009799-44-3

Chemical Structure| 1009799-44-3

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Product Details of [ 1009799-44-3 ]

CAS No. :1009799-44-3
Formula : C8H17N3O3
M.W : 203.24
SMILES Code : O=C(OC(C)(C)C)N(C/C(N)=N/O)C
MDL No. :MFCD16829774

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Application In Synthesis of [ 1009799-44-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1009799-44-3 ]

[ 1009799-44-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 180976-09-4 ]
  • [ 1009799-44-3 ]
YieldReaction ConditionsOperation in experiment
96% With hydroxylamine; In ethanol; water; for 1h;Heating / reflux; A solution of <strong>[180976-09-4]cyanomethyl-methyl-carbamic acid tert-butyl ester</strong> (6.01 g, 35.3 mmol) and hydroxylamine (5.13 g, 77.6 mmol, 50percent solution in water) in ethanol (30 mL) was <n="118"/>heated at reflux for 1 h. The reaction mixture was cooled to room temperature and concentrated in vacuo. The residue was azeotroped twice with ethanol, then once with isopropyl alcohol to afford a white solid. This was triturated with ether and collected by filtration, then dried under vacuum at room temperature to afford the title compound (5.27 g) as a white solid. A further crop could be obtained from the mother liquors by the same work-up procedure. Total yield 6.93 g (96percent). 1H NMR (CDCI3): 1.48 (S, 9 H), 2.87 (s, 3 H), 3.84 (s, 2 H), 4.73 (brs., 1 H), 5.09 (bra., 2 H).
 

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