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CAS No. : | 100516-61-8 | MDL No. : | N/A |
Formula : | C18H6 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 222.24 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P264-P272-P273-P280-P302+P352-P305+P351+P338-P333+P313-P337+P313-P501 | UN#: | N/A |
Hazard Statements: | H317-H320-H402 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
99% | With potassium fluoride In 1,2-dimethoxyethane at 0℃; for 2.5h; | |
62% | With N,N,N-tributylbutan-1-aminium fluoride In tetrahydrofuran at 0℃; for 0.166667h; | |
With potassium fluoride; 18-crown-6 ether In 1,2-dimethoxyethane at 23℃; |
With potassium fluoride; 18-crown-6 ether In 1,2-dimethoxyethane at 23℃; for 0.5h; | ||
With methanol; potassium carbonate In tetrahydrofuran at 20℃; for 0.5h; | ||
With potassium carbonate In tetrahydrofuran; methanol at 20℃; for 1.66667h; | ||
With potassium carbonate In tetrahydrofuran; methanol at 20℃; for 2h; | ||
With methanol; potassium carbonate In tetrahydrofuran at 20℃; for 0.5h; | ||
With N,N,N-tributylbutan-1-aminium fluoride In tetrahydrofuran at 8℃; for 0.166667h; | ||
With N,N,N-tributylbutan-1-aminium fluoride | ||
With N,N,N-tributylbutan-1-aminium fluoride | ||
With N,N,N-tributylbutan-1-aminium fluoride In tetrahydrofuran at 8℃; for 0.166667h; | ||
With N,N,N-tributylbutan-1-aminium fluoride In tetrahydrofuran at 8℃; for 0.166667h; | ||
With N,N,N-tributylbutan-1-aminium fluoride In tetrahydrofuran at 20℃; for 0.25h; Inert atmosphere; | ||
With potassium fluoride; 18-crown-6 ether In 1,2-dimethoxyethane at 20℃; for 3h; | 3 Dissolve 1,2,3,4,5,6-hexatrimethylsilylethynylbenzene (100mg, 0.15mmol) in 20mL of ethylene glycol dimethyl ether, add potassium fluoride (350mg, 6.02mmol) and 18 -Crown ether-6 (20mg, 0.0757mmol) mixed uniformly, detrimethylsilane reaction at room temperature for 3h, after the reaction is completed, washed with saturated brine (30mL×3) and extracted with dichloromethane 3 times in sequence (30mL×3), dry with anhydrous magnesium sulfate, filter to remove magnesium sulfate and concentrate to obtain 1,2,3,4,5,6-hexaethynylbenzene | |
With potassium carbonate In tetrahydrofuran; methanol | ||
With N,N,N-tributylbutan-1-aminium fluoride In tetrahydrofuran at 8℃; for 0.166667h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With potassium fluoride; copper(l) iodide; triethylamine 1.) 100 deg C, 72 h; 2.) glyme, 10 min; Yield given. Multistep reaction; |