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Chemical Structure| 7646-67-5 Chemical Structure| 7646-67-5

Structure of N-(2-Hydroxyethyl)acrylamide
CAS No.: 7646-67-5

Chemical Structure| 7646-67-5

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Zehuan Huang ; Xiaoyi Chen ; Stephen J. K. O’Neill ; Guanglu Wu ; Daniel J. Whitaker ; Jiaxuan Li , et al.

Abstract: Supramolecular polymer networks are non-covalently crosslinked soft materials that exhibit unique mechanical features such as self-healing, high toughness and stretchability. Previous studies have focused on optimizing such properties using fast-dissociative crosslinks (that is, for an aqueous system, dissociation rate constant kd > 10 s−1). Herein, we describe non-covalent crosslinkers with slow, tuneable dissociation kinetics (kd < 1 s−1) that enable high compressibility to supramolecular polymer networks. The resultant glass-like supramolecular networks have compressive strengths up to 100 MPa with no fracture, even when compressed at 93% strain over 12 cycles of compression and relaxation. Notably, these networks show a fast, room-temperature self-recovery (< 120 s), which may be useful for the design of high-performance soft materials. Retarding the dissociation kinetics of non-covalent crosslinks through structural control enables access of such glass-like supramolecular materials, holding substantial promise in applications including soft robotics, tissue engineering and wearable bioelectronics.

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Product Details of [ 7646-67-5 ]

CAS No. :7646-67-5
Formula : C5H9NO2
M.W : 115.13
SMILES Code : C=CC(NCCO)=O
MDL No. :MFCD11110645
InChI Key :UUORTJUPDJJXST-UHFFFAOYSA-N
Pubchem ID :193628

Safety of [ 7646-67-5 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
 

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