Home Chemistry Organic Building Blocks Aliphatic Cyclic Hydrocarbons Bicyclo[2.2.1]Hept-2-Ene
Addition Reactions: Like other alkenes, bicyclo[2.2.1]hept-2-ene can undergo addition reactions with electrophiles, such as hydrogen halides (HCl, HBr, HI), halogens (Br2, Cl2), and other reagents like water (H2O) or ozone (O3). These reactions involve breaking the π bond and forming new sigma (σ) bonds.
Cycloaddition Reactions: Bicyclo[2.2.1]hept-2-ene can participate in cycloaddition reactions, such as Diels-Alder reactions, which are commonly used to construct ring systems. In a Diels-Alder reaction, a diene (like bicyclo[2.2.1]hept-2-ene) reacts with a dienophile to form a cycloadduct.
Oxidation Reactions: Bicyclo[2.2.1]hept-2-ene can undergo oxidation reactions when treated with oxidizing agents like potassium permanganate (KMnO4) or osmium tetroxide (OsO4). These reactions can lead to the formation of diols or other oxygen-containing functional groups.
Reduction Reactions: Reduction of bicyclo[2.2.1]hept-2-ene can be accomplished using reducing agents like hydrogen gas (H2) in the presence of a catalyst (e.g., Pt, Pd, or Ni). This can convert the double bond into a single bond.
Polymerization Reactions: Bicyclo[2.2.1]hept-2-ene can be polymerized to form a polymer, either through radical polymerization or other polymerization methods. In this process, the double bond serves as a site for chain propagation.
Functional Group Transformations: Bicyclo[2.2.1]hept-2-ene can also be subjected to various functional group transformations, such as alkylation, acylation, and substitution reactions, which can modify the molecule's structure and properties.
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Methyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
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3-(Methoxycarbonyl)bicyclo[2.2.1]hept-5-ene-2-carboxylic acid
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Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid
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1-(Bicyclo[2.2.1]hept-5-en-2-yl)-1-oxo-5,8,11,14-tetraoxa-2-azaheptadecan-17-oic acid
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Ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate
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Bicyclo[2.2.1]hept-5-en-2-yltriethoxysilane
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