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Chemical Structure| 112052-11-6 Chemical Structure| 112052-11-6
Chemical Structure| 112052-11-6

*Storage: Sealed in dry,Store in freezer, under -20°C.

(S)-Tetrahydrofuran-3-yl 4-methylbenzenesulfonate

CAS No.: 112052-11-6

4.5 *For Research Use Only !

Cat. No.: A112139 Purity: 98%

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Product Details of [ 112052-11-6 ]

CAS No. :112052-11-6
Formula : C11H14O4S
M.W : 242.29
SMILES Code : O=S(C1=CC=C(C)C=C1)(O[C@@H]2COCC2)=O
MDL No. :MFCD08704351
InChI Key :WWCNXHYRAKUQDB-JTQLQIEISA-N
Pubchem ID :13837326

Safety of [ 112052-11-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis [ 112052-11-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 112052-11-6 ]

[ 112052-11-6 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 85290-78-4 ]
  • [ 112052-11-6 ]
  • [ 1589005-17-3 ]
  • [ 1589005-15-1 ]
YieldReaction ConditionsOperation in experiment
With caesium carbonate; In N,N-dimethyl-formamide; at 80℃; for 14h; To a mixture of reagent 2 (2.77 g, 1 1.4 mmol) and Cs2C03 (3.1 1 g, 9.5 mmol) in DMF (30 mL) was added 3-methyl-1 H-pyrazole-4-carboxylic acid ethyl ester (1 .47 mL, 9.5 mol). The mix- ture was kept at 80C for 14 h. The mixture was concentrated and the residue was extracted with EtOAc (50 mL). The combined organic layers were washed with water. The organic layer was dried over Na2S04 and evaporated to dryness. Flash chromatography (silica, petroleum ether : EtOAc 3:1 ) gave a mixture of reagents 3 and 4 as a solid (1 .58 g, 62%).
 

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