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Catalysts Ligands
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3,3'-diphenyl-1,1'-binaphthalene
(S)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-[1,1'-binaphthalene]-2,2'-diol
Catalysts Ligands
Chemistry
Chiral oxygen ligands
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BINOLs
3,3'-diphenyl-1,1'-binaphthalene

[ CAS No. 849939-13-5 ] {[proInfo.proName]}

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Cat. No.: {[proInfo.prAm]}
Chemical Structure| 849939-13-5
Chemical Structure| 849939-13-5
Structure of 849939-13-5 * Storage: {[proInfo.prStorage]}
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Quality Control of [ 849939-13-5 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification
Alternatived Products of [ 849939-13-5 ]

Product Details of [ 849939-13-5 ]

CAS No. :849939-13-5 MDL No. :MFCD08689862
Formula : C36H18F12O2 Boiling Point : -
Linear Structure Formula :- InChI Key :PGXMYJSTCAQJBY-UHFFFAOYSA-N
M.W : 710.51 Pubchem ID :11664821
Synonyms :

Safety of [ 849939-13-5 ]

Signal Word:Warning Class:
Precautionary Statements:P305+P351+P338 UN#:
Hazard Statements:H319 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 849939-13-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 849939-13-5 ]

[ 849939-13-5 ] Synthesis Path-Downstream   1~8

  • 1
  • Mo(2,5-dimethylpyrrolide)2(CHCMe2Ph)(N(2,6-Me2C6H3)) [ No CAS ]
  • [ 849939-13-5 ]
  • (R)-Mo(N-2,6-Me2C6H3)(CHCMe2Ph)(3,3'-bis(3,5-bis(trifluoromethyl)phenyl)binaphtholato) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzene-d6 (N2); ligand added to a soln. of Mo complex, reacted for 15 min; not isolated, detected by NMR;
Reference： [1]Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.; Mueller, Peter; Hoveyda, Amir H. [Organometallics, 2007, vol. 26, # 10, p. 2528 - 2539]
  • 2
  • Mo(2,5-dimethylpyrrolide)2(CHCMe2Ph)(N(2,6-Me2C6H3)) [ No CAS ]
  • [ 849939-13-5 ]
  • (R)-Mo(N-2,6-Me2C6H3)(CHCMe2Ph)(3,3'-bis(3,5-bis(trifluoromethyl)phenyl)binaphtholato)(THF) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In tetrahydrofuran (N2); not isolated, detected by NMR;
Reference： [1]Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.; Mueller, Peter; Hoveyda, Amir H. [Organometallics, 2007, vol. 26, # 10, p. 2528 - 2539]
  • 3
  • Mo(N(2,6-iPr<SUB>2</SUB>C<SUB>6</SUB>H<SUB>3</SUB>))(CHCMe<SUB>2</SUB>Ph)(NC<SUB>4</SUB>H<SUB>2</SUB>Me<SUB>2</SUB>)<SUB>2</SUB> [ No CAS ]
  • [ 849939-13-5 ]
  • (R)-Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(3,3'-bis(3,5-bis(trifluoromethyl)phenyl)binaphtholato) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzene-d6 (N2); ligand added to a soln. of Mo complex, reacted for 15 min; not isolated, detected by NMR;
Reference： [1]Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.; Mueller, Peter; Hoveyda, Amir H. [Organometallics, 2007, vol. 26, # 10, p. 2528 - 2539]
  • 4
  • Mo(N(2,6-iPr<SUB>2</SUB>C<SUB>6</SUB>H<SUB>3</SUB>))(CHCMe<SUB>2</SUB>Ph)(NC<SUB>4</SUB>H<SUB>2</SUB>Me<SUB>2</SUB>)<SUB>2</SUB> [ No CAS ]
  • [ 849939-13-5 ]
  • (R)-Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(3,3'-bis(3,5-bis(trifluoromethyl)phenyl)binaphtholato)(THF) [ No CAS ]
YieldReaction ConditionsOperation in experiment
37% In tetrahydrofuran (N2); a soln. of ligand added to a soln. of Mo complex, stirred at room temp. for 1 h; evapd. (vac.), dissolved in pentane, pptd. at -30°C; elem. anal.;
Reference： [1]Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.; Mueller, Peter; Hoveyda, Amir H. [Organometallics, 2007, vol. 26, # 10, p. 2528 - 2539]
  • 5
  • Mo(N-2-(CF3)C6H4)(CHCMe2Ph)(2,5-dimethylpyrrolide)2 [ No CAS ]
  • [ 849939-13-5 ]
  • (R)-Mo(N-2-(CF3)C6H4)(CHCMe2Ph)(3,3'-bis(3,5-bis(trifluoromethyl)phenyl)binaphtholato) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzene-d6 (N2); ligand added to a soln. of Mo complex, reacted for 1 h; not isolated, detected by NMR;
Reference： [1]Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.; Mueller, Peter; Hoveyda, Amir H. [Organometallics, 2007, vol. 26, # 10, p. 2528 - 2539]
  • 6
  • Mo(N-2-(CF3)C6H4)(CHCMe2Ph)(2,5-dimethylpyrrolide)2 [ No CAS ]
  • [ 849939-13-5 ]
  • (R)-Mo(N-2-(CF3)C6H4)(CHCMe2Ph)(3,3'-bis(3,5-bis(trifluoromethyl)phenyl)binaphtholato)(THF) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In tetrahydrofuran (N2); not isolated, detected by NMR;
Reference： [1]Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.; Mueller, Peter; Hoveyda, Amir H. [Organometallics, 2007, vol. 26, # 10, p. 2528 - 2539]
  • 7
  • Mo(1-adamantylimido)(CHCMe2Ph)(2,5-dimethylpyrrolide)2 [ No CAS ]
  • [ 849939-13-5 ]
  • (R)-Mo(N-1-adamantyl)(CHCMe2Ph)(3,3'-bis(3,5-bis(trifluoromethyl)phenyl)binaphtholato) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzene-d6 (N2); ligand added to a soln. of Mo complex; not isolated, detected by NMR;
Reference： [1]Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.; Mueller, Peter; Hoveyda, Amir H. [Organometallics, 2007, vol. 26, # 10, p. 2528 - 2539]
  • 8
  • Mo(1-adamantylimido)(CHCMe2Ph)(2,5-dimethylpyrrolide)2 [ No CAS ]
  • [ 849939-13-5 ]
  • (R)-Mo(N-1-adamantyl)(CHCMe2Ph)(3,3'-bis(3,5-bis(trifluoromethyl)phenyl)binaphtholato)(THF) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In tetrahydrofuran (N2); not isolated, detected by NMR;
Reference： [1]Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.; Mueller, Peter; Hoveyda, Amir H. [Organometallics, 2007, vol. 26, # 10, p. 2528 - 2539]

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3,3'-diphenyl-1,1'-binaphthalene
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Similar Product of
[ 849939-13-5 ]

Chemical Structure| 756491-54-0

A822395[ 756491-54-0 ]

(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-[1,1'-binaphthalene]-2,2'-diol

Reason: Optical isomers