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[ CAS No. 83536-16-7 ] {[proInfo.proName]}

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Chemical Structure| 83536-16-7
Chemical Structure| 83536-16-7
Structure of 83536-16-7 * Storage: {[proInfo.prStorage]}
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Product Details of [ 83536-16-7 ]

CAS No. :83536-16-7 MDL No. :MFCD32667015
Formula : C48H30O12 Boiling Point : -
Linear Structure Formula :- InChI Key :LUIFAWBWDOLINT-UHFFFAOYSA-N
M.W : 798.74 Pubchem ID :15471410
Synonyms :

Safety of [ 83536-16-7 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:
Hazard Statements:H302-H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 83536-16-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 83536-16-7 ]

[ 83536-16-7 ] Synthesis Path-Downstream   1~23

  • 1
  • [ 83536-14-5 ]
  • [ 83536-16-7 ]
YieldReaction ConditionsOperation in experiment
98% With potassium hydroxide In tetrahydrofuran; methanol at 60℃;
  • 2
  • [ 83536-16-7 ]
  • [ 83525-37-5 ]
YieldReaction ConditionsOperation in experiment
With thionyl chloride; N-benzyl-N,N,N-triethylammonium chloride In 1,2-dichloro-ethane at 85℃; for 24h;
  • 3
  • [ 83536-16-7 ]
  • [ 507272-77-7 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: thionyl chloride; benzyltriethylammonium chloride / 1,2-dichloro-ethane / 24 h / 85 °C 2: 280 mg / 4-(dimethylamino)pyridine; NH3 gas / 1,2-dichloro-ethane / -40 - 20 °C
  • 4
  • [ 83536-13-4 ]
  • hexakis(4-carboxyphenyl)benzene [ No CAS ]
  • 5
  • [ CAS Unavailable ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
In water; N,N-dimethyl-formamide at 150℃; for 48h;
  • 6
  • [ 617-84-5 ]
  • [ CAS Unavailable ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
In water at 85℃; for 16h;
  • 7
  • [ CAS Unavailable ]
  • [ 68-12-2 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
In water at 100℃; for 18h;
  • 8
  • [ 617-84-5 ]
  • [ CAS Unavailable ]
  • [ 64-17-5 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
In water at 120℃; for 24h;
  • 11
  • [ CAS Unavailable ]
  • [ 68-12-2 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
In water; acetic acid at 120℃; for 72h;
  • 13
  • [ CAS Unavailable ]
  • [ 64-19-7 ]
  • [ 68-12-2 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
Stage #1: Iron(III) nitrate nonahydrate; N,N-dimethyl-formamide; hexakis(4-carboxyphenyl)benzene With triethylamine for 24h; Stage #2: acetic acid at 150℃; for 120h;
  • 14
  • [ CAS Unavailable ]
  • [ 121-44-8 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
Stage #1: Iron(III) nitrate nonahydrate; triethylamine; hexakis(4-carboxyphenyl)benzene In N,N-dimethyl-formamide for 24h; Stage #2: With formic acid In N,N-dimethyl-formamide at 150℃; for 120h;
  • 15
  • [ CAS Unavailable ]
  • [ 64-19-7 ]
  • [ 68-12-2 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With triethylamine at 120℃; for 72h;
  • 16
  • [ CAS Unavailable ]
  • [ 68-12-2 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With 1,2-bis(5-methylisoxazol-3-yl)hydrazine In acetic acid at 120℃; for 72h;
  • 18
  • [ 5096-11-7 ]
  • hexakis(4-carboxyphenyl)benzene [ No CAS ]
  • C90H72N6O12 [ No CAS ]
  • 19
  • [ 7606-26-0 ]
  • [ 83536-16-7 ]
  • [ 2484953-05-9 ]
YieldReaction ConditionsOperation in experiment
15% With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 50℃; for 24h; Darkness; Inert atmosphere;
  • 20
  • [ CAS Unavailable ]
  • [ 68-12-2 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
80% Stage #1: N,N-dimethyl-formamide; hexakis(4-carboxyphenyl)benzene at 120℃; Stage #2: lanthanum(III) nitrate hexahydrate In glacial acetic acid at 150℃; for 168h;
  • 21
  • [ 95-54-5 ]
  • [ 83536-16-7 ]
  • [ 2492439-99-1 ]
YieldReaction ConditionsOperation in experiment
80% With oxygen at 150 - 190℃; for 48h; 7 Example 7
The Synthesis of 2,2'-(3',4',5',6'-tetrakis(4-(1H-benzo[d]imidazol-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diyl)bis(1H-benzol[d]imidazole) (6) Teflon capped pressure tube (10 ml) filled with argon, was charged with 25 mg (31.3 μmol) of Hexakis(4-carboxyphenyl)benzene, 20.6 mg of o-phenylenediamine (190.9 μmol) in the presence of 3 mL of PPA as solvent, catalyst. The reaction was heated at 150° C. for 24 h and then stirred at 190° C. for 24 h under oxygen. After the pH of the resulting mixture was adjusted to 8-9 with saturated sodium hydrogen carbonate (NaHCO3), product was precipitated. Thus obtained crude product was then further purified by recrystallization with methanol to give 2,2'-(3',4',5',6'-tetrakis(4-(1H-benzo[d]imidazol-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diyl)bis(1H-benzo[d]imidazole), as a pale yellow solid, 31 mg, Yield: 80%. MALDI-TOF MS: m/z calculated for C68H43N8 [M+1]+: 1231.47, found: 1231.2944. C84H55N12Na+[M+1+Na]+: 1254.45 found: 1254.2770. FT-IR (KBr): 3100-3400, 1635, 1395, 1123, 850, 742.
7 Example 7 Example 7 The Synthesis of 2,2'-(3',4',5',6'-tetrakis(4-(1H-benzo[d]imidazol-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diyl)bis(1H-benzol[d]imidazole) (6) Teflon capped pressure tube (10 ml) filled with argon, was charged with 25 mg (31.3 μmol) of Hexakis(4-carboxyphenyl)benzene, 20.6 mg of o-phenylenediamine (190.9 μmol) in the presence of 3 mL of PPA as solvent, catalyst. The reaction was heated at 150° C. for 24 h and then stirred at 190° C. for 24 h under oxygen. After the pH of the resulting mixture was adjusted to 8-9 with saturated sodium hydrogen carbonate (NaHCO3), product was precipitated. Thus obtained crude product was then further purified by recrystallization with methanol to give 2,2'-(3',4',5',6'-tetrakis(4-(1H-benzo[d]imidazol-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diyl)bis(1H-benzo[d]imidazole), as a pale yellow solid, 31 mg, Yield: 80%. MALDI-TOF MS: m/z calculated for C68H43N8 [M+1]+: 1231.47, found: 1231.2944. C84H55N12Na+[M+1+Na]+: 1254.45 found: 1254.2770. FT-IR (KBr): 3100-3400, 1635, 1395, 1123, 850, 742.
  • 22
  • [ CAS Unavailable ]
  • [ 68-12-2 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With acetic acid at 120℃; Sealed tube;
  • 23
  • [ CAS Unavailable ]
  • [ 7732-18-5 ]
  • [ 64-19-7 ]
  • [ 83536-16-7 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
Stage #1: iron(III)-acetylacetonate; water; acetic acid; hexakis(4-carboxyphenyl)benzene In N,N-dimethyl-formamide Sealed tube; Sonication; Stage #2: In N,N-dimethyl-formamide at 150℃; Sealed tube;
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