Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
{[ item.p_purity ]} | {[ item.pr_size ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]} | {[ item.pr_usastock ]} | Inquiry - | {[ item.pr_chinastock ]} | Inquiry - |
* Storage: {[proInfo.prStorage]}
CAS No. : | 83536-16-7 | MDL No. : | MFCD32667015 |
Formula : | C48H30O12 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | LUIFAWBWDOLINT-UHFFFAOYSA-N |
M.W : | 798.74 | Pubchem ID : | 15471410 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P280-P301+P312-P302+P352-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
98% | With potassium hydroxide In tetrahydrofuran; methanol at 60℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With thionyl chloride; N-benzyl-N,N,N-triethylammonium chloride In 1,2-dichloro-ethane at 85℃; for 24h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: thionyl chloride; benzyltriethylammonium chloride / 1,2-dichloro-ethane / 24 h / 85 °C 2: 280 mg / 4-(dimethylamino)pyridine; NH3 gas / 1,2-dichloro-ethane / -40 - 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In water; N,N-dimethyl-formamide at 150℃; for 48h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In water at 85℃; for 16h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In water at 100℃; for 18h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In water at 120℃; for 24h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
98% | With sodium hydroxide In tetrahydrofuran; methanol at 80℃; for 24h; | |
With sodium hydroxide In tetrahydrofuran; methanol |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
at 120℃; for 72h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In water; acetic acid at 120℃; for 72h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
at 100℃; for 72h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Stage #1: Iron(III) nitrate nonahydrate; N,N-dimethyl-formamide; hexakis(4-carboxyphenyl)benzene With triethylamine for 24h; Stage #2: acetic acid at 150℃; for 120h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Stage #1: Iron(III) nitrate nonahydrate; triethylamine; hexakis(4-carboxyphenyl)benzene In N,N-dimethyl-formamide for 24h; Stage #2: With formic acid In N,N-dimethyl-formamide at 150℃; for 120h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With triethylamine at 120℃; for 72h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1,2-bis(5-methylisoxazol-3-yl)hydrazine In acetic acid at 120℃; for 72h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In acetic acid at 150℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
15% | With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 50℃; for 24h; Darkness; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | Stage #1: N,N-dimethyl-formamide; hexakis(4-carboxyphenyl)benzene at 120℃; Stage #2: lanthanum(III) nitrate hexahydrate In glacial acetic acid at 150℃; for 168h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | With oxygen at 150 - 190℃; for 48h; | 7 Example 7 The Synthesis of 2,2'-(3',4',5',6'-tetrakis(4-(1H-benzo[d]imidazol-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diyl)bis(1H-benzol[d]imidazole) (6) Teflon capped pressure tube (10 ml) filled with argon, was charged with 25 mg (31.3 μmol) of Hexakis(4-carboxyphenyl)benzene, 20.6 mg of o-phenylenediamine (190.9 μmol) in the presence of 3 mL of PPA as solvent, catalyst. The reaction was heated at 150° C. for 24 h and then stirred at 190° C. for 24 h under oxygen. After the pH of the resulting mixture was adjusted to 8-9 with saturated sodium hydrogen carbonate (NaHCO3), product was precipitated. Thus obtained crude product was then further purified by recrystallization with methanol to give 2,2'-(3',4',5',6'-tetrakis(4-(1H-benzo[d]imidazol-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diyl)bis(1H-benzo[d]imidazole), as a pale yellow solid, 31 mg, Yield: 80%. MALDI-TOF MS: m/z calculated for C68H43N8 [M+1]+: 1231.47, found: 1231.2944. C84H55N12Na+[M+1+Na]+: 1254.45 found: 1254.2770. FT-IR (KBr): 3100-3400, 1635, 1395, 1123, 850, 742. |
7 Example 7 Example 7 The Synthesis of 2,2'-(3',4',5',6'-tetrakis(4-(1H-benzo[d]imidazol-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diyl)bis(1H-benzol[d]imidazole) (6) Teflon capped pressure tube (10 ml) filled with argon, was charged with 25 mg (31.3 μmol) of Hexakis(4-carboxyphenyl)benzene, 20.6 mg of o-phenylenediamine (190.9 μmol) in the presence of 3 mL of PPA as solvent, catalyst. The reaction was heated at 150° C. for 24 h and then stirred at 190° C. for 24 h under oxygen. After the pH of the resulting mixture was adjusted to 8-9 with saturated sodium hydrogen carbonate (NaHCO3), product was precipitated. Thus obtained crude product was then further purified by recrystallization with methanol to give 2,2'-(3',4',5',6'-tetrakis(4-(1H-benzo[d]imidazol-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diyl)bis(1H-benzo[d]imidazole), as a pale yellow solid, 31 mg, Yield: 80%. MALDI-TOF MS: m/z calculated for C68H43N8 [M+1]+: 1231.47, found: 1231.2944. C84H55N12Na+[M+1+Na]+: 1254.45 found: 1254.2770. FT-IR (KBr): 3100-3400, 1635, 1395, 1123, 850, 742. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With acetic acid at 120℃; Sealed tube; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Stage #1: iron(III)-acetylacetonate; water; acetic acid; hexakis(4-carboxyphenyl)benzene In N,N-dimethyl-formamide Sealed tube; Sonication; Stage #2: In N,N-dimethyl-formamide at 150℃; Sealed tube; |