[ CAS No. 704860-92-4 ] {[proInfo.proName]}

Name: 704860-92-4|2,7-Di-tert-butylpyrene-4,5-dione|98%
Brand: Ambeed
SKU: A1271720
Rating: 92 (22 reviews)

,{[proInfo.pro_purity]}

Cat. No.: {[proInfo.prAm]}

2D 3D

Structure of 704860-92-4 * Storage: {[proInfo.prStorage]}

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

For Research Only 110K+ Compounds Competitive Price 1-2 Day Shipping

Quality Control of [ 704860-92-4 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 704860-92-4 ]

SDS Specification

Alternatived Products of [ 704860-92-4 ]

Product Details of [ 704860-92-4 ]

CAS No. :	704860-92-4	MDL No. :	N/A
Formula :	C₂₄H₂₄O₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	BCVLJPPUHAYYTD-UHFFFAOYSA-N
M.W :	344.45	Pubchem ID :	11187008
Synonyms :

Safety of [ 704860-92-4 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313	UN#:	N/A
Hazard Statements:	H315-H319	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 704860-92-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 704860-92-4 ]

[ 704860-92-4 ] Synthesis Path-Downstream 1~61

1
[ 24300-91-2 ]
[ 704860-92-4 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium periodate; ruthenium trichloride hexahydrate; In dichloromethane; water; acetonitrile; at 20℃; for 18h;	2,7-di-tert-butylhydrazine (3.93 g, 12.5 mmol) was dissolved in a 500 ml round bottom flask with dichloromethane (50 ml) in acetonitrile (50 ml) and then mechanically stirred.Then sodium periodate (12.15 g, 60 mmol) was added in sequence.Lanthanum trichloride monohydrate (0.25 g) and water (60 ml) were reacted at room temperature for 18 h. The solvent was evaporated to dryness with a rotary evaporator, and the product was extracted with dichloromethane.The crude product is obtained by column chromatography using petroleum ether/dichloromethane (1:1) and then recrystallized from chlorobenzene and petroleum ether to give the final product. Traits: orange-red solid.

Reference： [1]Journal of Organic Chemistry,2005,vol. 70,p. 707 - 708
[2]European Journal of Organic Chemistry,2016,vol. 2016,p. 5933 - 5936
[3]Journal of Materials Chemistry C,2016,vol. 4,p. 3809 - 3814
[4]Journal of the American Chemical Society,2004,vol. 126,p. 7794 - 7795
[5]Chemical Communications,2015,vol. 51,p. 10142 - 10145
[6]Patent: CN109942585,2019,A .Location in patent: Paragraph 0098; 0105-0108

2
[ 64321-35-3 ]
[ 704860-92-4 ]
2,7-di-tert-butyl-9,11-bis(4-(tert-butyl)phenyl)-10H-cyclopenta[e]pyren-10-one [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2004,vol. 126,p. 7794 - 7795
[2]Journal of the American Chemical Society,2007,vol. 129,p. 11743 - 11749
[3]Angewandte Chemie - International Edition,2016,vol. 55,p. 15594 - 15598
Angew. Chem.,2016,vol. 128,p. 15823 - 15827

3
[ 704860-92-4 ]
[ 190843-93-7 ]

Reference： [1]Green Chemistry,2020,vol. 22,p. 5966 - 5971
[2]Journal of Organic Chemistry,2005,vol. 70,p. 707 - 708

4
[ 704860-92-4 ]
[ 737756-10-4 ]

Reference： [1]Journal of the American Chemical Society,2004,vol. 126,p. 7794 - 7795

5
[ 24300-91-2 ]
[ 190843-93-7 ]
[ 704860-92-4 ]

Reference： [1]Tetrahedron,2010,vol. 66,p. 2944 - 2952
[2]Supramolecular Chemistry,2014,vol. 26,p. 15 - 24

6
[ 23680-12-8 ]
[ 704860-92-4 ]
[ 1226759-40-5 ]

Reference： [1]Tetrahedron,2010,vol. 66,p. 2944 - 2952

7
[ 1435751-25-9 ]
[ 704860-92-4 ]
[ 1435751-46-4 ]

Reference： [1]Journal of Organic Chemistry,2013,vol. 78,p. 5544 - 5549

8
2,3,7,8-phenazine tetramine sesquihydrochloride [ No CAS ]
[ 704860-92-4 ]
24,27,30,33-tetra-tert-butyl-6,8,10,17,19,21-hexaaza-1.22,4.5,11.12,15.16-tetrabenzono nonaacene [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
23%	With pyridine; for 48h;Reflux;	2,3,7,8-Phenazinetetramine hydrochloride (150 mg, 0.5mmol) and 2,7-Di-t-butylpyrene-9,10-diketone(385mg, 1.1 mmol) were dissolved into 20 mL pyridine. The solution was refluxedfor 48 hours. After cooling to room temperature, 35mL methanol was added, theprecipitate was filtered and washed successively with 30mL chloroform,30mL THF,20mL HCl (6M), 50mL ethanol, yielded compound 1 (100mg, 23%) as a brown-black solid.1H NMR (400 MHz,TFA-d, δppm) 9.28 (s, 4H), 8.68 (s, 4H), 8.16 (s, 4H), 7.98 (s, 4H), 1.69 (s, 36H). FT-IR(KBr, cm-1): 2954, 1470. MS-HRMS: Calcd for C60H53N6, 857.4332 (M+ + H); found 857.4489 (M+ + H).

Reference： [1]Tetrahedron Letters,2014,vol. 55,p. 282 - 285

9
dibenzo[1,4]dioxine-2,3,7,8-tetramine tetrakishydrochloride [ No CAS ]
[ 704860-92-4 ]
24,27,30,33-tetra-tert-butyl-6,10,17,21-tetraaza-8,19-benzodioxin-1.22,4.5,11.12,15.16-tetrabenzono nonaacene [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
24%	With pyridine; for 48h;Reflux;	2,3,7,8-tetraaminodibenzo-1,4-dioxintetrahydrochloride (100 mg, 0.25 mmol) and 2,7-Di-t-butylpyrene-9,10-diketone(220mg, 0.63 mmol) were dissolved into 20 mL pyridine. Thesolution was refluxed for 48 hours. After cooling to room temperature, 50 mLmethanol was added, the precipitate was filtered and washed successively with50mL chloroform,60mL THF, 30mL HCl (6M), 50mL, boiled ethanol, yielded compound2 (53 mg, 24%) as a brown-yellowsolid.1H NMR (400 MHz, TFA-d,δppm) 9.41 (s, 4H), 8.54 (s, 4H), 8.22(s, 4H), 8.01 (s, 4H), 1.70 (s, 36H). FT-IR(KBr, cm-1): 1464. MS-HRMS: Calcd for C60H53N4O2, 861.4169 (M+ + H);found 861.4404 (M+ + H).

Reference： [1]Tetrahedron Letters,2014,vol. 55,p. 282 - 285

10
[ 1517464-96-8 ]
[ 704860-92-4 ]
[ 1517464-98-0 ]

Reference： [1]Journal of the American Chemical Society,2014,vol. 136,p. 28 - 31

11
[ 160621-41-0 ]
[ 704860-92-4 ]
[ 1312364-64-9 ]

Yield	Reaction Conditions	Operation in experiment
60%	In methanol; for 48h;Reflux;	2,3-Dinitro-benzo-18-crown-6 (11b) (0.50 g, 1.68 mmol) was added to a solution of 2,7-di-tert-butylpyrene-4,5dione (7) (0.50 g, 1.45 mmol) in 250 ml of methanol, and the reaction mixture was refluxed for 48 h. The final yellow product was filtered and washed with copious amount of methanol to afford 2 (1.20 g, 60 %). 1H NMR (300 MHz, CDCl3): δ 1.69 (18H, s), 3.74 (4H, s), 3.77 (4H, t, J = 3.9 Hz), 3.86 (4H, t, J = 3.1 Hz), 4.093 (4H, t, J = 3.9 Hz), 4.42 (4H, t, J = 3.6 Hz), 7.34 (2H, s), 8.00 (2H, s), 8.25 (2H, d, J = 1.8 Hz), 9.60 (2H, s). 13C NMR (75 MHz, CDCl3): δ 31.59, 35.53, 69.00, 69.14, 70.50, 70.77, 71.02, 107.11, 120.46, 123.75, 124.93, 127.26, 129.21, 131.08, 139.79, 141.44, 149.43, 152.77. HRMS-MALDI(m/z): [M + H]+: calculated for C40H47N2O6, 651.3429; Found, 651.3411.

Reference： [1]Supramolecular Chemistry,2014,vol. 26,p. 15 - 24

12
[ 129-00-0 ]
[ 704860-92-4 ]

Reference： [1]Supramolecular Chemistry,2014,vol. 26,p. 15 - 24
[2]Chemical Communications,2015,vol. 51,p. 10142 - 10145
[3]Journal of Materials Chemistry C,2016,vol. 4,p. 3809 - 3814
[4]Patent: CN109942585,2019,A
[5]Chemistry - A European Journal,2022,vol. 28

13
[ 102818-74-6 ]
[ 704860-92-4 ]
[ 1470026-64-2 ]

Yield	Reaction Conditions	Operation in experiment
60%	In methanol; for 48h;Reflux;	1,2-Diamino-benzo-15-crown-5(11a) (1.00 g, 3.35 mmol) was added to a solution of <strong>[704860-92-4]2,7-di-tert-butylpyrene-4,5-dione</strong> (7) (1.15 g, 3.35 mmol) in 300 ml of methanol, and the reaction mixture was refluxed for 48 h. The final yellow product was filtered and washed with copious amount of methanol to afford 1 (1.20 g, 60 %). 1H NMR (300 MHz, CDCl3): δ 1.66 (18H, s), 3.85 (8H, s), 4.07 (4H, t, J = 3.9 Hz), 4.44 (4H, t, J = 2.4 Hz), 7.62 (2H, s), 8.00 (2H,s), 8.25 (2H,d, J = 1.8 Hz), 9.60 (2H,d, J = 1.8 Hz). 13C NMR (75 MHz, CDCl3): δ 31.93, 35.53, 68.43, 69.04, 70.12, 71.25, 107.13, 120.46, 123.76, 124.92, 127.26, 129.21, 131.09, 139.87, 141.41, 149.43, 152.84. HRMS-MALDI(m/z): [M + H]+: calculated for C38H43N2O5, 607.3166; Found, 607.3212.

Reference： [1]Supramolecular Chemistry,2014,vol. 26,p. 15 - 24

14
[ 50-00-0 ]
[ 704860-92-4 ]
2,7-tert-butylpyrene-4,5-imidazole [ No CAS ]

Reference： [1]ACS Catalysis,2014,vol. 4,p. 2811 - 2817

15
[ 704860-92-4 ]
C₃₄H₃₀N₄O₄ [ No CAS ]

Reference： [1]Organic Letters,2014,vol. 16,p. 6096 - 6099

16
[ 704860-92-4 ]
2,7-di-tert-butyl-10,11-dihydro-8b,12a-(epoxyethanooxy)pyreno[4,5-b][1,4]dioxine-4,5-dione [ No CAS ]

Reference： [1]Organic Letters,2014,vol. 16,p. 6096 - 6099
[2]Chemical Communications,2015,vol. 51,p. 8037 - 8040

17
[ 109-77-3 ]
[ 704860-92-4 ]
C₃₀H₂₄N₄ [ No CAS ]

Reference： [1]Organic Letters,2014,vol. 16,p. 6096 - 6099

18
[ 107-21-1 ]
[ 704860-92-4 ]
C₂₈H₃₂O₄ [ No CAS ]

Reference： [1]Organic Letters,2014,vol. 16,p. 6096 - 6099
[2]Chemical Communications,2015,vol. 51,p. 8037 - 8040

19
1,3-dibutyl-5,6-diaminobenzimidazolium iodide [ No CAS ]
[ 704860-92-4 ]
C₃₁H₂₉N₄⁽¹⁺⁾*I^(1-) [ No CAS ]

Reference： [1]Inorganic Chemistry,2015,vol. 54,p. 3654 - 3659

20
2,3,8,9-tetraphenylpyrazino[2,3-f ]quinoxaline-5,6-diamine [ No CAS ]
[ 704860-92-4 ]
C₅₈H₄₄N₆ [ No CAS ]

Reference： [1]New Journal of Chemistry,2015,vol. 39,p. 2429 - 2432

21
[ 704860-92-4 ]
C₃₄H₃₀N₆O₄ [ No CAS ]

Reference： [1]Chemical Communications,2015,vol. 51,p. 8037 - 8040

22
[ 704860-92-4 ]
C₃₂H₃₀N₄O₄ [ No CAS ]

Reference： [1]Chemical Communications,2015,vol. 51,p. 8037 - 8040

23
[ 36023-58-2 ]
[ 704860-92-4 ]
C₃₀H₂₄N₆ [ No CAS ]

Reference： [1]Chemical Communications,2015,vol. 51,p. 8037 - 8040

24
[ 1187-42-4 ]
[ 704860-92-4 ]
2,7-di-tert-butylpyrene[4,5]-(2,3-pyrazine-5,6-dinitrile) [ No CAS ]

Reference： [1]Chemical Communications,2015,vol. 51,p. 8037 - 8040

25
[ 18514-52-8 ]
[ 704860-92-4 ]
2,7-di-tert-butylpyrene[4,5]-(2,3-pyrazine-5,6-dinitrile) [ No CAS ]

Reference： [1]Chemistry - A European Journal,2015,vol. 21,p. 3168 - 3173

26
C₃₆H₃₀N₆O₂ [ No CAS ]
[ 704860-92-4 ]
C₈₄H₇₀N₆O₂ [ No CAS ]

Reference： [1]Journal of Organic Chemistry,2015,vol. 80,p. 8390 - 8397

27
[ 95-54-5 ]
[ 704860-92-4 ]
2,7-di(tert-butyl)phenanthro[4,5-abc]phenazine [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2016,vol. 2016,p. 1283 - 1291
[2]Green Chemistry,2020,vol. 22,p. 5966 - 5971

28
[ 771-97-1 ]
[ 704860-92-4 ]
2,7-di-tert-butylbenzo[i]phenanthro[4,5-abc]phenazine [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2016,vol. 2016,p. 1283 - 1291

29
[ 3171-45-7 ]
[ 704860-92-4 ]
2,7-di-tert-butyl-11,12-dimethylphenanthro[4,5-abc]phenazine [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2016,vol. 2016,p. 1283 - 1291

30
[ 619-05-6 ]
[ 704860-92-4 ]
2,7-di-tert-butylphenanthro[4,5-abc]phenazine-11-carboxylic acid [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2016,vol. 2016,p. 1283 - 1291

31
[ 5348-42-5 ]
[ 704860-92-4 ]
2,7-di-tert-butyl-11,12-dichlorophenanthro[4,5-abc]phenazine [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2016,vol. 2016,p. 1283 - 1291

32
[ 165190-74-9 ]
[ 704860-92-4 ]
2,7-di-tert-butyl-10,14-di(thiophen-2-yl)phenanthro[4,5-abc][1,2,5]thiadiazolo[3,4-i]phenazine [ No CAS ]

Reference： [1]Chemical Science,2016,vol. 7,p. 3851 - 3856

33
4,7-bis(5-(2-ethylhexyl)thiophene-2-yl)benzo[c][1,2,5]thiadiazole-5,6-diamine [ No CAS ]
[ 704860-92-4 ]
2,7-di-tert-butyl-10,14-bis(5-(2-ethylhexyl)thiophen-2-yl)phenanthro[4,5-abc][1,2,5]thiadiazolo[3,4-i]phenazine [ No CAS ]

Reference： [1]Chemistry - A European Journal,2018,vol. 24,p. 7845 - 7851
[2]Journal of Materials Chemistry C,2016,vol. 4,p. 3809 - 3814

34
3-phenyl-1-(1H-pyrazol-1-yl)but-3-en-1-one [ No CAS ]
[ 704860-92-4 ]
(R)-2′,7′-di-tert-butyl-4-phenyl-5′H-spiro[pyran-2,4′-pyrene]-5′,6(3H)-dione [ No CAS ]
(S)-2′,7′-di-tert-butyl-4-phenyl-5′H-spiro[pyran-2,4′-pyrene]-5′,6(3H)-dione [ No CAS ]

Reference： [1]Organic and Biomolecular Chemistry,2016,vol. 14,p. 6435 - 6441

35
C₂₆H₁₈N₆O₆Si⁽²⁺⁾*2F₆P^(1-) [ No CAS ]
[ 704860-92-4 ]
C₅₀H₄₂N₆O₂Si⁽²⁺⁾*2F₆P^(1-) [ No CAS ]

Reference： [1]European Journal of Inorganic Chemistry,2016,vol. 2016,p. 5161 - 5170

36
[ 87837-08-9 ]
[ 704860-92-4 ]
C₆₂H₅₀N₄ [ No CAS ]

Reference： [1]Organic Letters,2017,vol. 19,p. 1718 - 1721

37
2,3,9,10,16,17-hexakis-(2,6-dimethylphenoxy)-23,24-diaminophthalocyaninato zinc(II) [ No CAS ]
[ 704860-92-4 ]
C₁₀₄H₈₈N₁₀O₆Zn [ No CAS ]

Reference： [1]Chemistry - A European Journal,2017,vol. 23,p. 8644 - 8651

38
[ 64321-35-3 ]
[ 704860-92-4 ]
(2,7-di-tert-butylpyrene-4,5-diyl)bis((4-(tert-butyl)phenyl)methanone) [ No CAS ]