[ CAS No. 64385-02-0 ] {[proInfo.proName]}

Name: 64385-02-0|2,3,4,5,6-Pentaiodobenzoic acid|98%
Brand: Ambeed
SKU: A1179866
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2D 3D

Structure of 64385-02-0 * Storage: {[proInfo.prStorage]}

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Quality Control of [ 64385-02-0 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 64385-02-0 ]

Product Details of [ 64385-02-0 ]

CAS No. :	64385-02-0	MDL No. :	MFCD30533929
Formula :	C₇HI₅O₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	LNLWJOZRHQPFML-UHFFFAOYSA-N
M.W :	751.60	Pubchem ID :	12256098
Synonyms :

Safety of [ 64385-02-0 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313	UN#:
Hazard Statements:	H315-H319	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 64385-02-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 64385-02-0 ]

[ 64385-02-0 ] Synthesis Path-Downstream 1~9

1
[ 64385-02-0 ]
[ 536-74-3 ]
[ 123568-37-6 ]

Yield	Reaction Conditions	Operation in experiment
32%	With copper(l) iodide; triethylamine at 50℃; for 12h;

Reference： [1]Tao, Weijin; Nesbitt, Stephanie; Heck, Richard F. [Journal of Organic Chemistry, 1990, vol. 55, # 1, p. 63 - 69]

2
[ 65-85-0 ]
[ 64385-02-0 ]

Yield	Reaction Conditions	Operation in experiment
49%	With iodine; periodic acid In sulfuric acid 1.) room temperature, 1 d, 2.) 95 deg C, 1 d;

Reference： [1]Mattern, Daniell Lewis [Journal of Organic Chemistry, 1984, vol. 49, # 17, p. 3051 - 3053]

3
[ 64349-92-4 ]
[ 64385-02-0 ]

Yield	Reaction Conditions	Operation in experiment
	With water

Reference： [1]Deacon,G.B.; Farquharson,G.J. [Australian Journal of Chemistry, 1977, vol. 30, p. 1701 - 1713]

Yield	Reaction Conditions	Operation in experiment
	entspr. Saeure 4, KI;

5
[ 109-06-8 ]
[ 64385-02-0 ]
C₇HI₅O₂*C₆H₇N [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
79%	In diethyl ether; N,N-dimethyl-formamide at 20℃; for 48h;	Preparation of 1 PIBA (80 mg, 0.09 mmol) was dissolved in 3 mL of DMF, after which 2-methylpyridine (10 μL, 0.11 mmol) was added. Slow diffusion of diethyl ether vapor at room temperature for 2 days results in the formation of pale yellowcrystals of 1 with a yield of ≈79%.

Reference： [1]Bondarenko; Novikov; Chernova; Sokolov; Adonin [Journal of Structural Chemistry, 2021, vol. 62, # 8, p. 1237 - 1242][Zh. Strukt. Kim., 2021, vol. 62, # 8, p. 1325 - 1330]

6
[ 108-89-4 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 64385-02-0 ]
[ 33513-42-7 ]
Cu⁽²⁺⁾*2C₇I₅O₂^(1-)*C₆H₇N*3.5C₃H₇NO*0.5H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
81%	In diethyl ether Sealed tube;	2.1 Preparation of 1-4 General procedure: In all cases, PIBA was dissolved in DMF, followed by addition of corresponding pyridine and, after that, solution of Cu(NO3)2·3H2O in DMF (see Table 1 for details). After that, the mixture was placed into bigger vial containing diethyl ether and closed. Slow diffusion of Et2O results in formation of crystalline samples of 1-4 (all brownish-green) suitable for XRD (within 1-5days). Yields: 79% (1), 83% (2), 87% (3), 81% (4).

Reference： [1]Abramov, Pavel A.; Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S.; Sokolov, Maxim N. [Polyhedron, 2022, vol. 214]

7
[ 110-86-1 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 64385-02-0 ]
C₂₄H₁₀CuI₁₀N₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
79%	In diethyl ether; N,N-dimethyl-formamide Sealed tube;	2.1 Preparation of 1-4 General procedure: In all cases, PIBA was dissolved in DMF, followed by addition of corresponding pyridine and, after that, solution of Cu(NO3)2·3H2O in DMF (see Table 1 for details). After that, the mixture was placed into bigger vial containing diethyl ether and closed. Slow diffusion of Et2O results in formation of crystalline samples of 1-4 (all brownish-green) suitable for XRD (within 1-5days). Yields: 79% (1), 83% (2), 87% (3), 81% (4).

Reference： [1]Abramov, Pavel A.; Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S.; Sokolov, Maxim N. [Polyhedron, 2022, vol. 214]

8
[ 591-22-0 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 64385-02-0 ]
C₂₈H₁₈CuI₁₀N₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%	In diethyl ether; N,N-dimethyl-formamide Sealed tube;	2.1 Preparation of 1-4 General procedure: In all cases, PIBA was dissolved in DMF, followed by addition of corresponding pyridine and, after that, solution of Cu(NO3)2·3H2O in DMF (see Table 1 for details). After that, the mixture was placed into bigger vial containing diethyl ether and closed. Slow diffusion of Et2O results in formation of crystalline samples of 1-4 (all brownish-green) suitable for XRD (within 1-5days). Yields: 79% (1), 83% (2), 87% (3), 81% (4).

Reference： [1]Abramov, Pavel A.; Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S.; Sokolov, Maxim N. [Polyhedron, 2022, vol. 214]

9
[ 108-48-5 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 64385-02-0 ]
C₂₈H₁₈CuI₁₀N₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
87%	In diethyl ether; N,N-dimethyl-formamide Sealed tube;	2.1 Preparation of 1-4 General procedure: In all cases, PIBA was dissolved in DMF, followed by addition of corresponding pyridine and, after that, solution of Cu(NO3)2·3H2O in DMF (see Table 1 for details). After that, the mixture was placed into bigger vial containing diethyl ether and closed. Slow diffusion of Et2O results in formation of crystalline samples of 1-4 (all brownish-green) suitable for XRD (within 1-5days). Yields: 79% (1), 83% (2), 87% (3), 81% (4).

Reference： [1]Abramov, Pavel A.; Adonin, Sergey A.; Bondarenko, Mikhail A.; Novikov, Alexander S.; Sokolov, Maxim N. [Polyhedron, 2022, vol. 214]

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P342	If experiencing respiratory symptoms:
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P353	Rinse skin with water/shower.
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P378
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P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
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P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
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P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
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H242	Heating may cause a fire
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H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
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H301	Toxic if swallowed
H302	Harmful if swallowed
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H311	Toxic in contact with skin
H312	Harmful in contact with skin
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H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
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H401	Toxic to aquatic life
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H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 64385-02-0 ] {[proInfo.proName]}

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Application In Synthesis of [ 64385-02-0 ]

[ 64385-02-0 ] Synthesis Path-Downstream 1~9

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