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[ CAS No. 60836-10-4 ] {[proInfo.proName]}

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Cat. No.: {[proInfo.prAm]}
Chemical Structure| 60836-10-4
Chemical Structure| 60836-10-4
Structure of 60836-10-4 * Storage: {[proInfo.prStorage]}
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Product Details of [ 60836-10-4 ]

CAS No. :60836-10-4 MDL No. :
Formula : C11H18OSi2 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 222.43 Pubchem ID :-
Synonyms :

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Application In Synthesis of [ 60836-10-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 60836-10-4 ]

[ 60836-10-4 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 60836-10-4 ]
  • [ 4756-25-6 ]
  • [ 170649-54-4 ]
YieldReaction ConditionsOperation in experiment
35% In tetrahydrofuran; diethyl ether; toluene at 54℃; for 8h;
  • 2
  • [ 60836-10-4 ]
  • [ 27329-60-8 ]
  • [ 681164-27-2 ]
  • 3
  • [ 14243-64-2 ]
  • [ 60836-10-4 ]
  • [ 1338228-66-2 ]
  • 4
  • [ 60836-10-4 ]
  • [ 513-81-5 ]
  • C17H28OSi2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
88% With dimethylaluminum chloride In hexane; dichloromethane at -78℃; Inert atmosphere; Compound 508 To a solution of 200a (93 mg, 0.42 mmol) in CH2C12 (4 mL) at -78 °C under N2 was added dimethylaluminum chloride (0.50 mL, 0.50 mmol, 1.0 M in hexanes) followed by 2,3-dimethyl- 1,3-butadiene (287 mg, 3.35 mmol). The reaction was stirred until complete by TLC (1-1.5 hours). The reaction was quenched at -78 °C with saturated aqueous NaHC03 and extracted with Et20. The layers were separated, the organic phase washed with H2O, brine, and dried over Na2S04. The mixture was filtered through a silica gel plug and the solvent was removed in vacuo to yield crude 508 (112 mg, 88%) as a colorless oil and was not further purified: R/= 0.7 (EtOAc:hexanes, 1: 10); NMR (500 MHz, C6D6): (5 = 3.11 (t, J = 8.0 Hz, 2H), 2.78 (t, .7 = 8.1 Hz, 2H), 1.54 (s, 3H), 1.47 (s,3H), 0.31 (s, 9H). 0.05 (s, 9H); 13C NMR (125 MHz, C6D6): δ = 179.1, 152.8, 142.0, 122.4, 122.4, 103.5, 99.5, 39.9, 35.6, 18.4, 17.9, -0.2, -0.8; IR (film): 2920, 1644 cm-1 ; HRMS (ESI-TOF) mlz calcd for [Ci7H28Si20+H]+ 305.1751 ; found 305.1753.
With dimethylaluminum chloride In hexane; dichloromethane at -78℃; Inert atmosphere;
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