[ CAS No. 586372-53-4 ] {[proInfo.proName]}

Name: 586372-53-4|(Benzene-1,3,5-triyltris(methylene))tris(phosphonic acid)|98%
Brand: Ambeed
SKU: A1156859
Rating: 93 (22 reviews)

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Quality Control of [ 586372-53-4 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

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Product Details of [ 586372-53-4 ]

CAS No. :	586372-53-4	MDL No. :	MFCD34165581
Formula :	C₉H₁₅O₉P₃	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	QNXIXVZKHKBGHY-UHFFFAOYSA-N
M.W :	360.13	Pubchem ID :	13669035
Synonyms :

Safety of [ 586372-53-4 ]

Signal Word:	Danger	Class:	8
Precautionary Statements:	P501-P260-P234-P264-P280-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405	UN#:	3261
Hazard Statements:	H314-H290	Packing Group:	Ⅲ
GHS Pictogram:

Application In Synthesis of [ 586372-53-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 586372-53-4 ]

[ 586372-53-4 ] Synthesis Path-Downstream 1~34

1
[ 6566-57-0 ]
[ 586372-53-4 ]

Yield	Reaction Conditions	Operation in experiment
92%	With hydrogenchloride; water for 24h; Heating;
92%	In hydrogenchloride for 24h; Heating;
92%	With hydrogenchloride In water for 20h; Reflux;

80.3 %

With hydrogenchloride In water at 110℃;

1.S3-3.S3 S3: Synthesis of 1,3,5-benzenetrimethylphosphonic acid At room temperature, the intermediate II (7.0 g, 13.25 mmol) prepared in the previous step and 130 mL of concentrated hydrochloric acid were successively added to a 250 mL reaction flask, and the reaction was refluxed at 110° C. for 20 h, monitored by TLC [V (dichloromethane): V (methanol )=8:1] After the reaction was completed, cooling and decompression removed excess water and HCl to obtain 4.68g white solid, which was recrystallized with methanol/water (volume ratio 7:1) mixed solution to obtain a large amount of white crystal block III, which was vacuum-dried (dried at 50-55°C for 8-10h) to obtain 3.83g of white crystals with a yield of 80.3%.

Reference： [1]Jaffres, Paul-Alain; Villemin, Didier; Montouillout, Valerie; Fernandez, Christian; Chardon, Josiane; Santos, Jana Sopkova-De Oliveira [Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 2002, vol. 389, # PART I, p. 87 - 95]
[2]Sopkova-De Oliveira Santos, Jana; Montouillout, Valerie; Fayon, Franck; Fernandez, Christian; Delain-Bioton, Lise; Villemin, Didier; Jaffres, Paul-Alain [New Journal of Chemistry, 2004, vol. 28, # 10, p. 1244 - 1249]
[3]Location in patent: experimental part Vilela, Sergio M. F.; Ananias, Duarte; Gomes, Ana C.; Valente, Anabela A.; Carlos, Luis D.; Cavaleiro, Jose A. S.; Rocha, Joao; Tome, Joao P. C.; Almeida Paz, Filipe A. [Journal of Materials Chemistry, 2012, vol. 22, # 35, p. 18354 - 18371]
[4]Current Patent Assignee: JIANGSU SANJILI CHEMICAL - CN115651013, 2023, A Location in patent: Paragraph 0038-0039; 0044-0045; 0050; 0055-0056; 0059; ...

2
[ CAS Unavailable ]
[ 586372-53-4 ]
[ 796871-89-1 ]

Yield	Reaction Conditions	Operation in experiment
280 mg	In methanol; water at 18℃;

Reference： [1]Sopkova-De Oliveira Santos, Jana; Montouillout, Valerie; Fayon, Franck; Fernandez, Christian; Delain-Bioton, Lise; Villemin, Didier; Jaffres, Paul-Alain [New Journal of Chemistry, 2004, vol. 28, # 10, p. 1244 - 1249]

3
[ 553-26-4 ]
[ CAS Unavailable ]
[ 586372-53-4 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
33%	In ethanol; water addn. of bipyridine to soln. of phosphonic acid deriv. in aq. ethanol, mixing with aq. soln. of copper compd., heating at 95-100°C for 3 d; isolation of crystals, X-ray anal.;

Reference： [1]Zon, Jerzy; Kong, Deyuan; Gagnon, Kevin; Perry, Houston; Holliness, Leanthony; Clearfield, Abraham [Dalton Transactions, 2010, vol. 39, # 45, p. 11008 - 11018]

4
[ CAS Unavailable ]
[ 7732-18-5 ]
[ 586372-53-4 ]
[ CAS Unavailable ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	at 20℃; Microwave irradiation;

Reference： [1]Vilela, Sergio M. F.; Firmino, Ana D. G.; Mendes, Ricardo F.; Fernandes, Jose A.; Ananias, Duarte; Valente, Anabela A.; Ott, Holger; Carlos, Luis D.; Rocha, Joao; Tome, Joao P. C.; Almeida Paz, Filipe A. [Chemical Communications, 2013, vol. 49, # 57, p. 6400 - 6402]

5
[ CAS Unavailable ]
[ CAS Unavailable ]
[ 7732-18-5 ]
[ 586372-53-4 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	at 60℃; for 0.0833333h; Microwave irradiation;

6
[ CAS Unavailable ]
[ CAS Unavailable ]
[ 7732-18-5 ]
[ 586372-53-4 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	at 60℃; for 0.0833333h; Microwave irradiation;

7
[ 7732-18-5 ]
[ CAS Unavailable ]
[ 586372-53-4 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
86%	at 140℃; for 96h; Autoclave;	H6L1 (0.25 mmol, 0.090 g), Pb(ac)2·3H2O (0.375 mmol, 0.1422 g), and 10 mL of water were mixed and stirred in a Teflon-lined autoclave. Afterward, it was sealed and heated at 140 °C for 4 days and allowed to cool to room temperature in a time period of 24 hours. Colorless plate crystals of 1 (0.1455 g) were collected and washed with deionized water in satisfying yield (86 %, based on metal). Elemental analysis (%) calcd for C18H26O19P6Pb3 (1353.78): C 15.97, H 1.94; found: C 15.90, H 2.03. IR(KBr, cm-1): 3423 (b, m), 2895 (w), 1637 (w), 1599 (m), 1454 (w), 1416 (w), 1227 (m), 1125 (s), 1049 (vs), 938 (s), 909 (m), 875 (m), 741 (m), 706 (m), 631 (w), 509 (m), 488 (w) (see Figure S6).

Reference： [1]Tang, Si-Fu; Lv, Xiao-Xia; Li, Liang-Jun; Wang, Chao; Zhao, Xue-Bo [Inorganic Chemistry Communications, 2014, vol. 39, p. 51 - 55]

8
[ CAS Unavailable ]
[ 7732-18-5 ]
[ 586372-53-4 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	at 180℃; for 72h; High pressure;