[ CAS No. 58139-59-6 ] {[proInfo.proName]}

Name: 58139-59-6|[4,4'-Bithiazole]-2,2'-diamine|98%
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Quality Control of [ 58139-59-6 ]

COA NMR CNMR HPLC LC-MS

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Product Details of [ 58139-59-6 ]

CAS No. :	58139-59-6	MDL No. :	MFCD01740587
Formula :	C₆H₆N₄S₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	MRFMTBTUKQIBDI-UHFFFAOYSA-N
M.W :	198.27	Pubchem ID :	42654
Synonyms :

Safety of [ 58139-59-6 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313	UN#:
Hazard Statements:	H315-H319	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 58139-59-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 58139-59-6 ]

[ 58139-59-6 ] Synthesis Path-Downstream 1~61

1
[ 58139-59-6 ]
[ 14352-51-3 ]
3,3'-[4,4']bithiazolyl-2,2'-diyldiamino-bis-isoindol-1-one [ No CAS ]

Reference： [1]Patent: US2692267,1952,A

2
[ 17356-08-0 ]
[ 6305-43-7 ]
[ 58139-59-6 ]

Reference： [1]Tetrahedron Letters,2000,vol. 41,p. 3883 - 3886
[2]Heterocycles,2014,vol. 89,p. 693 - 708
[3]Russian Journal of Organic Chemistry,2005,vol. 41,p. 623 - 624
[4]Helvetica Chimica Acta,1948,vol. 31,p. 2065,2071

3
[ 58139-59-6 ]
[ 108-24-7 ]
2,2'-diacetylamino-(4,4')bithiazole [ No CAS ]

Reference： [1]Journal of the Indian Chemical Society,1984,vol. 61,p. 151 - 153

4
[ 58139-59-6 ]
2,2'-diamino-5,5'-dinitro-(4,4')bithiazole [ No CAS ]

Reference： [1]Journal of the Indian Chemical Society,1984,vol. 61,p. 151 - 153

5
[ 58139-59-6 ]
2,2'-diamino-5,5'-dibromo-4,4'-bithiazole [ No CAS ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

6
[ 58139-59-6 ]
[ 259542-06-8 ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

7
[ 553-26-4 ]
[ 58139-59-6 ]
2,2'-diamino-4,4'-bis(1,3-thiazole) 4,4'-bipyridine [ No CAS ]

Reference： [1]Journal of Molecular Structure,2007,vol. 826,p. 29 - 35

8
[ 58139-59-6 ]
[ 13362-78-2 ]
2,2'-diamino-4.4'-bis(1,3-thiazole) 1,2-bis(4-pyridyl)ethylene [ No CAS ]

Reference： [1]Journal of Molecular Structure,2007,vol. 826,p. 29 - 35

9
[ 17252-51-6 ]
[ 58139-59-6 ]
2,2'-diamino-4.4'-bis(1,3-thiazole) 1,3-bis(4-pyridyl)propane [ No CAS ]

Reference： [1]Journal of Molecular Structure,2007,vol. 826,p. 29 - 35

10
[ 58139-59-6 ]
2,2'-diethynyl-4,4'-bithiazole [ No CAS ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

11
[ 58139-59-6 ]
[ 259542-07-9 ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

12
[ 58139-59-6 ]
2,2'-bis(3-hydroxyprop-1-ynyl)-4,4'-bithiazole [ No CAS ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

13
[ 58139-59-6 ]
2,2',5,5'-tetraethynyl-4,4'-bithiazole [ No CAS ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

14
[ 58139-59-6 ]
2,2'-bis(phenylethynyl)-4,4'-bithiazole [ No CAS ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

15
[ 58139-59-6 ]
[ 259542-15-9 ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

16
[ 58139-59-6 ]
2,2',5,5'-tetrakis(phenylethynyl)-4,4'-bithiazole [ No CAS ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

17
[ 58139-59-6 ]
[ 259542-16-0 ]

Reference： [1]Heterocycles,2000,vol. 52,p. 349 - 364

18
[ 58139-59-6 ]
2,2'-diacetylamino-5,5'-dinitro-(4,4')bithiazole [ No CAS ]

Reference： [1]Journal of the Indian Chemical Society,1984,vol. 61,p. 151 - 153

19
[ 58139-59-6 ]
copper(II) choride dihydrate [ No CAS ]
[ 318489-74-6 ]

Reference： [1]Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,2000,vol. 30,p. 1653 - 1666

20
copper(II) nitrate trihydrate [ No CAS ]
[ 58139-59-6 ]
[ 318489-76-8 ]

Reference： [1]Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,2000,vol. 30,p. 1653 - 1666

21
copper(ll) sulfate pentahydrate [ No CAS ]
[ 58139-59-6 ]
[ 318489-77-9 ]

Reference： [1]Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,2000,vol. 30,p. 1653 - 1666

22
[ 58139-59-6 ]
[ 7789-45-9 ]
[ 318489-75-7 ]

Reference： [1]Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,2000,vol. 30,p. 1653 - 1666

23
[ 58139-59-6 ]
copper(II) choride dihydrate [ No CAS ]
[ 318489-74-6 ]

Reference： [1]Acta Crystallographica, Section C: Crystal Structure Communications,2001,vol. 57,p. 354 - 355

24
[ 58139-59-6 ]
nickel(II) chloride hexahydrate [ No CAS ]
[ 178558-82-2 ]

Reference： [1]Polyhedron,1996,vol. 15,p. 2771 - 2776

25
[ 58139-59-6 ]
copper(II) choride dihydrate [ No CAS ]
oxydiacetic acid hydrate [ No CAS ]
[ 620126-08-1 ]

Reference： [1]Acta Crystallographica, Section C: Crystal Structure Communications,2003,vol. 59,p. m307-m309

26
[ 10196-18-6 ]
[ 58139-59-6 ]
sodium perchlorate [ No CAS ]
[Zn(2,2'-diamino-4,4'-bithiazole)2](ClO₄)2 [ No CAS ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2003,vol. 629,p. 1627 - 1631

27
[ 58139-59-6 ]
[ 10108-64-2 ]
[ 577705-24-9 ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2003,vol. 629,p. 1627 - 1631

28
[ 58139-59-6 ]
[ 592-85-8 ]
[ 651714-38-4 ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2003,vol. 629,p. 1627 - 1631

29
[ 58139-59-6 ]
cobalt(II) chloride hexahydrate [ No CAS ]
[ 178558-80-0 ]

Reference： [1]Polyhedron,1996,vol. 15,p. 2771 - 2776

30
[ 58139-59-6 ]
chromium chloride hexahydrate [ No CAS ]
[ 142-73-4 ]
[ 709037-47-8 ]

Reference： [1]Acta Crystallographica, Section C: Crystal Structure Communications,2004,vol. 60,p. m137-m139

31
oxovanadium(IV) sulfate [ No CAS ]
[ 58139-59-6 ]
[ 7732-18-5 ]
diaqua(2,2'-diamino-4,4'-bi-1,3-thiazole)oxosulfatovanadium(IV) tetrahydrate [ No CAS ]

Reference： [1]Acta Crystallographica, Section C: Crystal Structure Communications,2005,vol. 61,p. m463-m465

32
[ 58139-59-6 ]
[ 557-34-6 ]
sodium perchlorate [ No CAS ]
[Zn(2,2'-diamino-4,4'-bithiazole)2(CH₃COO]ClO₄*2H₂O [ No CAS ]

Reference： [1]Zeitschrift fur Naturforschung, B: Chemical Sciences,2005,vol. 60,p. 951 - 954

33
[ 58139-59-6 ]
sodium perchlorate [ No CAS ]
[ 543-90-8 ]
[Cd(2,2'-diamino-4,4'-bithiazole)2(CH₃COO]ClO₄*2H₂O [ No CAS ]

Reference： [1]Zeitschrift fur Naturforschung, B: Chemical Sciences,2005,vol. 60,p. 951 - 954

34
[ 110-99-6 ]
[ 58139-59-6 ]
cobalt(II) chloride hexahydrate [ No CAS ]
aqua(2,2'-diamino-4,4'-bi-1,3-thiazole-.kappa(2)N,N')(oxydiacetato-κ(3)O,O',O'')cobalt(II) trihydrate [ No CAS ]

Reference： [1]Acta Crystallographica, Section C: Crystal Structure Communications,2007,vol. 63,p. m177-m180

35
[ 58139-59-6 ]
Cu(pic)₂⋅6H₂O [ No CAS ]
[ 639462-01-4 ]
[μ3-cis-N-(2-aminoethyl)-N'-(2-carboxylatophenyl)oxamidato(3-)]bis(2,2'-diamino-4,4'-bi-1,3-thiazole)tetracopper(II) bis(2,4,6-trinitrophenolate) [ No CAS ]

Reference： [1]Acta Crystallographica, Section C: Crystal Structure Communications,2010,vol. 66,p. m218-m221

36
copper(II) nitrate trihydrate [ No CAS ]
[ 58139-59-6 ]
[ 1037416-00-4 ]
catena-poly[[(2,2'-diamino-4,4'-bithiazole)(μ3-cis-N-(2-carboxylatophenyl)-N'-[3-(dimethylamino)propyl]oxamidato(3-))dicopper(II)] nitrate 0.6-hydrate] [ No CAS ]

Reference： [1]Acta Crystallographica, Section C: Crystal Structure Communications,2010,vol. 66,p. m323-m326

37
[ 58139-59-6 ]
[ 3189-97-7 ]
C₆H₆N₄S₂*C₁₄H₁₄N₄ [ No CAS ]

Reference： [1]Journal of Chemical Crystallography,2010,vol. 40,p. 1180 - 1187

38
[ 58139-59-6 ]
2,5-bis-(4-pyridyl)-3,4-diaza-2,4-hexadiene [ No CAS ]
[(DABTZ)(4-bpdh)] [ No CAS ]

Reference： [1]Journal of Chemical Crystallography,2010,vol. 40,p. 1180 - 1187

39
[ 67-56-1 ]
copper(II) perchlorate hexahydrate [ No CAS ]
[ 58139-59-6 ]
[ 7732-18-5 ]
[Cu₂(N-(5-chloro-2-hydroxyphenyl)-N'-[3-(dimethylamino)propyl]oxamido-3H)(CH₃OH)(2,2'-diamino-4,4'-bithiazole)](ClO₄)*1.5H₂O [ No CAS ]

Reference： [1]Inorganica Chimica Acta,2012,vol. 390,p. 190 - 198

40
[ 58139-59-6 ]
[ 1402392-63-5 ]
2ClO₄^(1-)*C₃₈H₃₈Cu₄N₁₄O₁₀S₄⁽²⁺⁾ [ No CAS ]

Reference： [1]Transition Metal Chemistry,2012,vol. 37,p. 569 - 577

41
copper(II) perchlorate hexahydrate [ No CAS ]
[ 58139-59-6 ]
[ 1416180-15-8 ]
[Cu₄(bhpox)₂(dabt)₂](ClO₄)₂ [ No CAS ]

Reference： [1]New Journal of Chemistry,2012,vol. 36,p. 2472 - 2483

42
copper(II) perchlorate hexahydrate [ No CAS ]
[ 58139-59-6 ]
[ 1219579-29-9 ]
[Cu₄(N-(5-chloro-2-hydroxy-phenyl)-N'-[3-(methylamino)propyl]oxamido)₂(2,2'-diamino-4,4'-bithiazole)₂](ClO₄)₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
68%		To a stirred methanol solution (5 mL) containing Cu(ClO4)2·6H2O (0.0371 g, 0.1 mmol) was added dropwise a methanol solution (10 mL) of H3chmpoxd (0.0143 g, 0.05 mmol) and piperidine (0.0128 g, 0.15 mmol) at room temperature. After stirring for 30 min, a methanol solution (5 mL) of <strong>[58139-59-6]dabt</strong> (0.0099 g, 0.05 mmol) was added dropwise. The mixture was stirred quickly at 333 K for 6 h, the resulting dark brown solution was filtered and brown cube crystals of the complex suitable for X-ray analysis were obtained by slow evaporation. Yield: 0.0477 g (68%). Anal. Calc. for Cu4C36H60N14O14Cl4S4: C, 30.09; H, 4.21; N, 13.64. Found: C, 30.10; H, 4.24; N, 13.60%.

Reference： [1]Journal of Molecular Structure,2013,vol. 1039,p. 28 - 36

43
[ 58139-59-6 ]
Cu(pic)₂⋅6H₂O [ No CAS ]
[ 75-05-8 ]
[Cu₂H(DABTA)₂](pic)⋅6H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
81%	In methanol; at 21.84 - 59.84℃; for 6h;	To a stirred acetonitrile solution (12 mL) containing DABT (0.0199 g, 0.1 mmol), a methanol solution (15 mL) of Cu(pic)2⋅6H2O (0.0627 g, 0.1 mmol) was added dropwise at room temperature. After stirring continuously at 333 K for 6 h, the resulting brown solution was filtered and the filtrate was allowed to stand at room temperature for 10 days to give well shaped dark brown crystals suitable for X-ray analysis. Yield, 42 mg (81%). Analysis calculation for Cu2C26H35N15O13S4: C, 30.59%; H, 3.46%; N, 20.58%. Found: C, 30.61%; H, 3.41%; N, 20.54%.

Reference： [1]Journal of Molecular Structure,2013,vol. 1037,p. 15 - 22

44
[ 58139-59-6 ]
[ 59661-86-8 ]
N,N'-([4,4'-bithiazole]-2,2'-diyl)bis-2-phenylquinoline-4-carboxamide [ No CAS ]

Reference： [1]Heterocycles,2014,vol. 89,p. 693 - 708

45
[ 58139-59-6 ]
6-chloro-2-phenyl-quinoline-4-carbonyl chloride [ No CAS ]
N,N'-([4,4'-bithiazole]-2,2'-diyl)bis-6-chloro-2-phenylquinoline-4-carboxamide [ No CAS ]

Reference： [1]Heterocycles,2014,vol. 89,p. 693 - 708

46
[ 58139-59-6 ]
6-iodo-2-phenyl-quinoline-4-carbonyl chloride [ No CAS ]
N,N'-([4,4,-bithiazole]-2,2'-diyl)bis-6-iodo-2-phenylquinoline-4-carboxamide [ No CAS ]

Reference： [1]Heterocycles,2014,vol. 89,p. 693 - 708

47
[ 67-56-1 ]
[ 58139-59-6 ]
copper(II) choride dihydrate [ No CAS ]
[ 1190284-42-4 ]
[ 1615720-56-3 ]

Reference： [1]New Journal of Chemistry,2014,vol. 38,p. 2964 - 2978

48
[ 366-18-7 ]
[ 58139-59-6 ]
[([4,4'-bithiazole]-2,2'-diamine)₂(2,2'-bipyridine)] [ No CAS ]

Reference： [1]Helvetica Chimica Acta,2014,vol. 97,p. 701 - 707

49
[ 67-56-1 ]
[ 58139-59-6 ]
[ 14098-24-9 ]
[([4,4'-bithiazole]-2,2'-diamine)₂(benzo-18-crown-6)(MeOH)] [ No CAS ]

Reference： [1]Helvetica Chimica Acta,2014,vol. 97,p. 701 - 707

50
[ 37366-09-9 ]
sodium hexafluoroantimonate [ No CAS ]
[ 58139-59-6 ]
[(η⁶-C₆H₆)Ru(2,2'-diamino-4,4'-bithiazole)Cl]*SbF₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
78%		A mixture of the starting metal precursors [(g6-arene)Ru(l-Cl)Cl]2 (0.1 mmol) and ligand (0.2 mmol) was dissolved inmethanol (20 ml) and stirred for 1 h. NaSbF6 (2.5 equivalents)added to the reaction mixture after one hour of the reaction. Thereaction mixture was stirred at room temperature for 8 h. A yellowprecipitate was formed, washed with cold methanol (10 ml) anddiethyl ether (3 10 ml) and dried in vacuum.

Reference： [1]Inorganica Chimica Acta,2014,vol. 421,p. 349 - 358

51
sodium hexafluoroantimonate [ No CAS ]
[ 58139-59-6 ]
[ 52462-29-0 ]
[(η⁶-C₆H₆)Ru(2,2'-diamino-4,4'-bithiazole)Cl]*SbF₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
82%		A mixture of the starting metal precursors [(g6-arene)Ru(l-Cl)Cl]2 (0.1 mmol) and ligand (0.2 mmol) was dissolved inmethanol (20 ml) and stirred for 1 h. NaSbF6 (2.5 equivalents)added to the reaction mixture after one hour of the reaction. Thereaction mixture was stirred at room temperature for 8 h. A yellowprecipitate was formed, washed with cold methanol (10 ml) anddiethyl ether (3 10 ml) and dried in vacuum.2.4.1. [(g6-C6H6)Ru(dm4bt)Cl]SbF6 (1)Yield 105 mg (74%). 1H NMR (400 MHz, Acetone-d6) d = 8.27 (s,2H, tz-H), 6.26 (s, 6H, C6H6), 3.26 (s, 6H, tz-CH3); IR (KBr cm1): 3104(m), 2919(m), 1639(m), 1533(m), 1440(vs), 1374(m),1308(m), 1215(m), 1165(m), 850(m), 658(vs); ESI-MS: 410.9 [M+]peak; UV-Vis {Acetonitrile, kmax nm (e/104 M1 cm1)}: 285(0.84), 410 (0.08); Anal. Calc. for C14H14N2S2RuClSbF6 (646.7): C,40.92; H, 3.43; N, 6.82. Found: C, 40.98; H, 3.52; N, 6.91%.

Reference： [1]Inorganica Chimica Acta,2014,vol. 421,p. 349 - 358

52
sodium hexafluoroantimonate [ No CAS ]
[RuCl₂(hexamethylbenzene)]2 [ No CAS ]
[ 58139-59-6 ]
[(η⁶-C_6Me6)Ru(2,2'-diamino-4,4'-bithiazole)Cl]*SbF₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
82%		A mixture of the starting metal precursors [(g6-arene)Ru(l-Cl)Cl]2 (0.1 mmol) and ligand (0.2 mmol) was dissolved inmethanol (20 ml) and stirred for 1 h. NaSbF6 (2.5 equivalents)added to the reaction mixture after one hour of the reaction. Thereaction mixture was stirred at room temperature for 8 h. A yellowprecipitate was formed, washed with cold methanol (10 ml) anddiethyl ether (3 10 ml) and dried in vacuum.2.4.1. [(g6-C6H6)Ru(dm4bt)Cl]SbF6 (1)Yield 105 mg (74%). 1H NMR (400 MHz, Acetone-d6) d = 8.27 (s,2H, tz-H), 6.26 (s, 6H, C6H6), 3.26 (s, 6H, tz-CH3); IR (KBr cm1): 3104(m), 2919(m), 1639(m), 1533(m), 1440(vs), 1374(m),1308(m), 1215(m), 1165(m), 850(m), 658(vs); ESI-MS: 410.9 [M+]peak; UV-Vis {Acetonitrile, kmax nm (e/104 M1 cm1)}: 285(0.84), 410 (0.08); Anal. Calc. for C14H14N2S2RuClSbF6 (646.7): C,40.92; H, 3.43; N, 6.82. Found: C, 40.98; H, 3.52; N, 6.91%.

Reference： [1]Inorganica Chimica Acta,2014,vol. 421,p. 349 - 358

53
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] [ No CAS ]
sodium hexafluoroantimonate [ No CAS ]
[ 58139-59-6 ]
[Cp*Ir(2,2'-diamino-4,4'-bithiazole)Cl]*SbF₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%		General procedure: A mixture of the starting metal precursors [CpM(l-Cl)Cl]2(0.1 mmol) and ligand (0.2 mmol) was dissolved in methanol(20 ml) and refluxed for 1 h. NaSbF6 (2.5 equivalents) was addedto reaction mixture after one hour of the reaction. The reactionmixture was refluxed for 8 h. A yellow precipitate was formed upon evaporation of methanol solvent by rotary evaporator. Thiswas washed with cold methanol and diethyl ether (3 10 ml)and dried in vacuum.

Reference： [1]Inorganica Chimica Acta,2014,vol. 421,p. 349 - 358

54
sodium hexafluoroantimonate [ No CAS ]
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer [ No CAS ]
[ 58139-59-6 ]
[Cp*Rh(2,2'-diamino-4,4'-bithiazole)Cl]*SbF₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%		General procedure: A mixture of the starting metal precursors [CpM(l-Cl)Cl]2(0.1 mmol) and ligand (0.2 mmol) was dissolved in methanol(20 ml) and refluxed for 1 h. NaSbF6 (2.5 equivalents) was addedto reaction mixture after one hour of the reaction. The reactionmixture was refluxed for 8 h. A yellow precipitate was formed upon evaporation of methanol solvent by rotary evaporator. Thiswas washed with cold methanol and diethyl ether (3 10 ml)and dried in vacuum.

Reference： [1]Inorganica Chimica Acta,2014,vol. 421,p. 349 - 358

55
copper(II) nitrate trihydrate [ No CAS ]
[ 58139-59-6 ]
C₁₆H₂₃N₃O₄ [ No CAS ]
[Cu₂(N-benzoate-N'-[3-(diethylamino)propyl]oxamide)(2,2'-diamino-4,4'-bithiazole)](NO₃)*H₂O}_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
82%		To a stirred ethanol solution (10 mL) of H3bdpox (0.0151 g, 0.05 mM) and piperidine (0.0128 g, 0.15 mM), an ethanol solution (5 mL) containing Cu(NO3)23H2O (0.0242 g,0.1 mM) was added dropwise at room temperature. The mixture was stirred quickly for 30 min and an ethanol solution (5 mL) of <strong>[58139-59-6]dabt</strong> (0.0099 g, 0.05 mM) was added. The reaction solution was heated at 333 K with stirring for 6 h and then cooled to room temperature. The resulting dark green solution was filtered and dark brown cube crystals of the polymeric copper(II) complex suitable for X-ray analysis were obtained by slow evaporation at room temperature after 15 days. Yield: 0.0296 g (82%). Anal. Calcd for Cu2C22H28N8O8S2 (%): C, 36.51; H, 3.90; N, 15.48. Found (%): C, 36.62; H, 3.97; N,15.32. ΛM (DMF solution): 78 Scm2 M-1.

Reference： [1]Journal of Coordination Chemistry,2015,vol. 68,p. 928 - 948

56
[ 58139-59-6 ]
[ 15420-02-7 ]
C₆H₆N₄S₂*C₁₂H₈N₄O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
78%	In methanol; at 20℃; for 1h;	This compound was prepared by adding 10 mL solution of2,5-bis(4-pyridyl)-1,3,4-oxadiazole (bpo) (0.244 g, 1mmol) in MeOH to 10 mL methanolic solution of [4,4-bithiazole]-2,2-diamine (0.198 g, 1 mmol) and stirredfor 1 h at room temperature. The prepared solution wasallowed to evaporate slowly for 10 days at room temperature(ca. 25C). Yellowish crystals of the desiredproduct precipitated, washed by acetone and dried inair (M.p. 60C). IR (KBr, cm-1): 545w, 686w, 816w,1040m, 1247w, 1327w, 1400w, 1523s, 1585m, 1628m,3095sand 3255m. 1H-NMR ([D6]-DMSO): 6.6 (s, 2H);7.7 (d, 4H); 7.2 (d, 4H); 8.5 (s, 4H) ppm. 13C{1H}NMR ([D6]-DMSO): 170.7; 150.2, 142.7; 137.9, 124.7,120.9, 102.6ppm. Yield: 0.3 g, 78%. C18H14N8OS2:calc. (%) C 51.2, H 3.32, N 26.50; found (%): C 50.8,H 3.10, N 26.4.

Reference： [1]Journal of Chemical Sciences,2015,vol. 127,p. 2015 - 2021

57
[ 4916-57-8 ]
[ 58139-59-6 ]
C₆H₆N₄S₂*C₁₂H₁₂N₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
82%	In methanol; at 20℃; for 1h;	This compound was prepared by dissolving 2,2-diamino-4,4-bis(1,3-thiazole) (0.198 g, 1 mmol) in MeOH (10mL) and adding to a MeOH solution of 1,3-bis(4-pyridyl)ethane (0.184 g, 1 mmol). The resulting solutionwas stirred for 1 h at room temperature and allowedto stand for 5 days at room temperature (ca. 25C).Yellowish precipitated crystals were filtered off anddried in air (M.p. 75C). IR (KBr, cm-1): 490w, 553w,707m, 1246m, 1330m, 1338m, 1405m, 1523s, 1584w,1606m, 3088s, 3268w. 1H-NMR ([D6]-DMSO): 1.8(t ,4H); 6.6 (s, 2H); 6.8 (d, 4H); 7.3 (d, 4H) and 7.9 (s, 4H)ppm. 13C {1H} NMR ([D6]-DMSO): 23.0, 102.0, 121.7,147.8, 151.1, 169.5 ppm. Yield: 0.3 g, 82%. C9H9N3S4:calc (%) C 28.27, H 2.35, N 10.99; found (%): C 28.15,H 2.30, N 11.20.

Reference： [1]Journal of Chemical Sciences,2015,vol. 127,p. 2015 - 2021

58
[ 58139-59-6 ]
Cu(pic)₂⋅6H₂O [ No CAS ]
Cu(2,2′-diamino-4,4′-bithiazole)(picrate)₂ [ No CAS ]

Reference： [1]Applied Organometallic Chemistry,2016,vol. 30,p. 730 - 739

59
[ 58139-59-6 ]
[ 109-77-3 ]
C₁₂H₄N₁₀S₂ [ No CAS ]

Reference： [1]Patent: CN109134454,2019,A .Location in patent: Paragraph 0012; 0036; 0040; 0041

60
[ 57-13-6 ]
[ 6305-43-7 ]
[ 58139-59-6 ]

Yield	Reaction Conditions	Operation in experiment
5.9 g	In ethanol; for 2h;Reflux;	In a three-necked flask equipped with a reflux condenser and a stirring device,9.0 g (0.036 mol) of 1,4-dibromobutanedione were added in sequence,5.4g (0.072mol) thioureaAnd 200mL of absolute ethanol, refluxed under stirring for 2h,The reaction mixture is then poured into 100 mL of hot water (45-50 C).Concentrated aqueous ammonia (22-25%) was added to the mixture under stirring to pH 8-9, and a pale yellow precipitate was allowed to stand, which was filtered to give a crude product.The crude product was recrystallized from a mixed solvent of ethanol/water (3:1 by volume) and dried to give the product 2,2'-diamino-4,4'-bithiazole 5.9 g.

Reference： [1]Patent: CN109134454,2019,A .Location in patent: Paragraph 0012; 0036; 0038; 0039

61
[ 58139-59-6 ]
[ 4755-77-5 ]
N,N′-2,2′-(4,4′-bithiazole)-bis(oxamate) [ No CAS ]

Reference： [1]Crystal Growth and Design,2019,vol. 19,p. 3905 - 3912

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[ 58139-59-6 ]

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[ CAS No. 58139-59-6 ] {[proInfo.proName]}

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[ 58139-59-6 ] Synthesis Path-Downstream 1~61

Related Functional Groups of [ 58139-59-6 ]

Amines

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Thiazoles

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[ 58139-59-6 ]

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[ 58139-59-6 ]